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971.
Maria Regina Alcantara Maria Veronica Marques Correia De Melo Vera Regina Paoli JosÉ Atilio Vanin 《Molecular Crystals and Liquid Crystals》2013,570(3-4):335-347
Lyotropic liquid crystals are prepared from racemic and optically active di-sodium N-lauroyl aspartate (SNLA). The optically active levo enantiomer is a suitable amphiphile for obtaining cholesteric lyotropic mesophases. In the present work, different types of mesophases, including cholesteric and nematic, were prepared and their type I or II magnetic behavior characterized by deuterium and 23Na NMR. The polarizing microscope textures were investigated, particularly with regards to magnetic field effects upon the samples. The usual chevron pattern was obtained for particular sample orientations and several characteristic effects were observed for the type I cholesteric lyomesophase in the first few minutes following removal of the sample from the magnetic field. Although the head group of di-sodium N-lauroyl aspartate possesses two negative charges, compositions are not too different from those reported for other amphiphile lyotropic systems. 相似文献
972.
Hongxin Wang Yoshitaka Yoda Weibing Dong Songping D. Huang 《Journal of synchrotron radiation》2013,20(5):683-690
The conventional energy calibration for nuclear resonant vibrational spectroscopy (NRVS) is usually long. Meanwhile, taking NRVS samples out of the cryostat increases the chance of sample damage, which makes it impossible to carry out an energy calibration during one NRVS measurement. In this study, by manipulating the 14.4 keV beam through the main measurement chamber without moving out the NRVS sample, two alternative calibration procedures have been proposed and established: (i) an in situ calibration procedure, which measures the main NRVS sample at stage A and the calibration sample at stage B simultaneously, and calibrates the energies for observing extremely small spectral shifts; for example, the 0.3 meV energy shift between the 100%‐57Fe‐enriched [Fe4S4Cl4]= and 10%‐57Fe and 90%‐54Fe labeled [Fe4S4Cl4]= has been well resolved; (ii) a quick‐switching energy calibration procedure, which reduces each calibration time from 3–4 h to about 30 min. Although the quick‐switching calibration is not in situ, it is suitable for normal NRVS measurements. 相似文献
973.
基于多组态Dirac-Fock 方法和密度矩阵理论,本文详细计算了高电荷态类锂离子(26 ≤ Z ≤ 92)KLL 双电子复合过程中,自由电子被共振俘获到中间双激发态1s2s22p3/2J = 1 的磁子能级截面以及该双激发态的取向参数,进而得到了此激发态向基态电偶极辐射跃迁1s2s22p3/2J = 1→1s22s2J = 0 所发出光子的角分布和极化度,重点讨论了Breit 相互作用对相关物理量的影响. 研究表明,Breit 相互作用极大地改变了中间双激发态1s2s22p3/2J = 1 不同磁子能级的截面,从而导致了随后退激发放出光子的角分布和极化特性的显著变化.
关键词:
角分布和极化特性
多组态Dirac-Fock方法
密度矩阵理论 相似文献
974.
Yan Yan Hong-Ru Liu Zhu-Ying Sheng Peng-Fei Cui Jie Yu Shuo Chai 《International journal of quantum chemistry》2024,124(3):e27357
Regulation of photodissociation dynamics of oriented LiH molecules in different dissociation channels is proposed based on time dependent quantum wave packet theory. The enhancement of molecular orientation on the photodissociation of LiH is obvious with our theoretical scheme. The results show that the molecular orientation in the ground state has a great effect on the angular distributions of wave packets. By using the proper laser pulses and controlling the polarization direction of the laser pulses, the enhancement of the photodissociation could be realized. After the molecular orientation, an optimal dissociation channel is observed with an improved dissociation probability. Compared with the results without molecular orientation, the maximal dissociation probability is increased by 8.1% in the indirect dissociation channel and 30.7% in the direct dissociation channel. The enhancement effect is more obvious in the direct dissociation channel, which provides a possible method to manipulate the dissociation of LiH molecules experimentally. Additionally, the photodissociation process of LiH also relies on the electric intensity and delay time of two pump pulses. 相似文献
975.
主动雷达导引头具有较高的抗干扰性能,以PD体制导引头为例,分析了导引头单脉冲角跟踪的工作原理,在此基础上分析了同步闪烁干扰和交叉眼干扰这两种能够有效进行角度欺骗的干扰手段,并对干扰性能做出了仿真。 相似文献
976.
Tin‐Yu Wu Yan‐Bo Wang Wei‐Tsong Lee 《Wireless Communications and Mobile Computing》2012,12(4):367-378
In recent years, thanks to the development and popularization of wireless network technologies, the issue of vehicular ad hoc network (VANET) has received great attention, and more and more VANET‐related researches have been brought up. Generally speaking, the biggest difference between VANET and traditional ad hoc network is the velocity of carriers because in VANET, the velocity of vehicles, the carriers, is much higher than those in traditional ad hoc. Therefore, it would be a great challenge to forward data efficiently in VANETs and many researches proposed have focused on the development of routing protocols. The current proposed routing protocols are all assumed to simulate in a distributed and ideal environment. As for the complex geographic environments, such as urban scenarios, extra amendments must be needed to improve the efficiency of the routing protocols. Thus, the main purpose of this paper is to design a suitable routing protocol for urban scenarios with better performance and adaptability. For this reason, greedy on straight roads and predictive at the intersections (GSPI) routing protocol is proposed to use greedy mode on straight roads and to use predictive mode at the intersections. In greedy mode, we choose the next hop according to the weight value that combines the distances and multi‐rate. In predictive mode, we predict the directions of the vehicles to determine the next hop. The simulation results reveal that our proposed algorithm indeed proves its feasibility. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
977.
978.
979.
980.
受光阑限制的部分相干光通过湍流大气传输的方向性 总被引:1,自引:0,他引:1
基于广义惠更斯菲涅耳原理,并利用Rytov相位结构函数二次近似的方法,推导出了受光阑限制的高斯谢尔模型(GSM)光束通过湍流大气传输的二阶矩宽度及扩展角解析表达式。以未受光阑限制的GSM光束为参照光束,分别利用扩展角和归一化远场平均光强分布研究了受光阑限制的GSM光通过湍流大气传输的方向性。研究表明,若以扩展角表征光束的方向性,则在一定条件下,截断参数δ不同的受光阑限制的GSM光束能够与相应的未受光阑限制的GSM光束在自由空间及湍流大气中具有相同的方向性;若以归一化远场平均光强分布表征光束的方向性,则即使扩展角一致,δ不同的受光阑限制的GSM光束与相应的未受光阑限制的GSM光束在自由空间中的方向性也并不相同,但在湍流中则一致。 相似文献