全文获取类型
收费全文 | 4547篇 |
免费 | 693篇 |
国内免费 | 389篇 |
专业分类
化学 | 1307篇 |
晶体学 | 59篇 |
力学 | 420篇 |
综合类 | 26篇 |
数学 | 213篇 |
物理学 | 1919篇 |
无线电 | 1685篇 |
出版年
2024年 | 9篇 |
2023年 | 59篇 |
2022年 | 106篇 |
2021年 | 84篇 |
2020年 | 123篇 |
2019年 | 106篇 |
2018年 | 106篇 |
2017年 | 146篇 |
2016年 | 216篇 |
2015年 | 225篇 |
2014年 | 297篇 |
2013年 | 346篇 |
2012年 | 312篇 |
2011年 | 349篇 |
2010年 | 256篇 |
2009年 | 306篇 |
2008年 | 291篇 |
2007年 | 320篇 |
2006年 | 305篇 |
2005年 | 217篇 |
2004年 | 207篇 |
2003年 | 180篇 |
2002年 | 149篇 |
2001年 | 129篇 |
2000年 | 132篇 |
1999年 | 108篇 |
1998年 | 101篇 |
1997年 | 68篇 |
1996年 | 63篇 |
1995年 | 65篇 |
1994年 | 51篇 |
1993年 | 36篇 |
1992年 | 38篇 |
1991年 | 22篇 |
1990年 | 17篇 |
1989年 | 13篇 |
1988年 | 13篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1985年 | 12篇 |
1984年 | 9篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 8篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有5629条查询结果,搜索用时 15 毫秒
61.
62.
为了研究CuO的不同掺杂浓度对表面等离子共振角的影响,提出一种新型的棱镜耦合法Ag-SnO2(掺杂CuO)复合膜表面等离子共振光学传感器结构.采用射频反应溅射法在清洗处理后的金红石棱镜上依次制备Ag膜(50nm),SnO2膜(50nm),CuO和SnO2膜(50nm)4层膜结构,CuO的厚度依其不同的掺杂体积分数的不同而不同,经过退火实现SnO2薄膜的掺杂得到复合膜.以He-Ne激光62.8nm为入射激励光源,通过采用表面等离子共振实验方法,CuO的掺杂体积分数分别为0,0.01和0.05时,得到共振角分别为59.61°,60.52°和61.3°的结果.结果表明,CuO掺杂的体积分数越大,表面等离子共振的共振角越大. 相似文献
63.
以聚对磺酸钠苯乙烯(PSS)为聚阴离子、聚烯丙基氯化氨(PAH)为聚阳离子交替沉积制备了多层聚合物纳米复合膜,用热分析仪考察了这两种体相聚合物的热稳定性,采用紫外-可见光谱仪、椭圆偏振光测厚仪、接触角测量仪等分析了复合膜的性能,用DF-PM型动静摩擦系数精密测定装置考察了其摩擦学性能.结果发现,所制备的聚合物复合膜具有一定的减摩作用,原因是单晶硅表面沉积聚合物超薄膜可以降低表面的粘着力,对硅表面具有微观修饰作用,从而降低其同钢对摩时的摩擦系数;单晶硅表面分子沉积聚合物纳米复合膜的摩擦学特性同超薄膜的层数相关,沉积层数较多的超薄膜的耐磨寿命较长,并因加热处理而得到明显改善. 相似文献
64.
为了揭示地形变化对连续档输电线动态特性的影响,本文提出了基于任意高差角的动刚度理论.首先将单档导线视为连续档导线的子结构,构建了两悬挂点不等高的单档导线振动方程,并在该理论方程中引入了二次项,能够考虑重力沿弦向分量的影响,推导出绝缘子串绕其悬挂点转动的动刚度计算方法,通过动刚度理论研究连续档导线横向振动模态和频率,并应用有限元软件ABAQUS 验证理论模态和频率公式的准确性.所得结果表明,动刚度的计算方法具有较高的精度,理论模态与有限元输出结果吻合较好,同时获得的频率和模态可为山地高压输电线路防舞技术的研究提供依据. 相似文献
65.
66.
67.
Alexandre P. Felgueiras Fbio M. S. Rodrigues Rui M. B. Carrilho Pedro F. Cruz Vitor H. Rodrigues Tams Kgl Lszl Kollr Mariette M. Pereira 《Molecules (Basel, Switzerland)》2022,27(6)
Four stereoisomeric monoether derivatives, based on axially chiral (R)- or (S)-BINOL bearing a chiral (+)- or (−)-neomenthyloxy group were synthesised and fully characterised by NMR spectroscopy and X-ray crystallography. The respective tris-monophosphites were thereof prepared and fully characterised. The coordination ability of the new bulky phosphites with Rh(CO)2(acac), was attested by 31P NMR, which presented a doublet in the range of δ = 120 ppm, with a 1J(103Rh-31P) coupling constant of 290 Hz. The new tris-binaphthyl phosphite ligands were further characterised by DFT computational methods, which allowed us to calculate an electronic (CEP) parameter of 2083.2 cm−1 and an extremely large cone angle of 345°, decreasing to 265° upon coordination with a metal atom. Furthermore, the monophosphites were applied as ligands in rhodium-catalysed hydroformylation of styrene, leading to complete conversions in 4 h, 100% chemoselectivity for aldehydes and up to 98% iso-regioselectivity. The Rh(I)/phosphite catalytic system was also highly active and selective in the hydroformylation of disubstituted olefins, including (E)-prop-1-en-1-ylbenzene and prop-1-en-2-ylbenzene. 相似文献
68.
69.
Angel H. Romero 《Molecular physics》2017,115(20):2528-2546
The influence of ring puckering angle on the multipole moments of sixteen four-membered heterocycles (1-16) was theoretically estimated using MP2 and different DFTs in combination with the 6-31+G(d,p) basis set. To obtain an accurate evaluation, CCSD/cc-pVDZ level and, the MP2 and PBE1PBE methods in combination with the aug-cc-pVDZ and aug-cc-pVTZ basis sets were performed on the planar geometries of 1-16. In general, the DFT and MP2 approaches provided an identical dependence of the electrical properties with the puckering angle for 1-16. Quantitatively, the quality of the level of theory and basis sets affects significant the predictions of the multipole moments, in particular for the heterocycles containing C=O and C=S bonds. Convergence basis sets within the MP2 and PBE1PBE approximations are reached in the dipole moment calculations when the aug-cc-pVTZ basis set is used, while the quadrupole and octupole moment computations require a larger basis set than aug-cc-pVTZ. On the other hand, the multipole moments showed a strong dependence with the molecular geometry and the nature of the carbon-heteroatom bonds. Specifically, the C-X bond determines the behavior of the μ(?), θ(?) and ?(?) functions, while the C=Y bond plays an important role in the magnitude of the studied properties. 相似文献
70.
Samuel BeckfordNicholas Langston Min Zou Ronghua Wei 《Applied Surface Science》2011,257(13):5688-5693
Low surface energy polymer thin-films can be applied to surfaces to increase hydrophobicity and reduce friction for a variety of applications. However, wear of these thin films, resulting from repetitive rubbing against another surface, is of great concern. In this study, we show that highly hydrophobic surfaces with persistent abrasion resistance can be fabricated by depositing fluorinated carbon thin films on sandblasted glass surfaces. In our study, fluorinated carbon thin films were deposited on sandblasted and as-received smooth glass using deep reactive ion etching equipment by only activating the passivation step. The surfaces of the samples were then rubbed with FibrMet abrasive papers in a reciprocating motion using an automatic friction abrasion analyzer. During the rubbing, the static and kinetic friction forces were also measured. The surface wetting properties were then characterized using a video-based contact angle measuring system to determine the changes in water contact angle as a result of rubbing. Assessment of the wear properties of the thin films was based on the changes in the water contact angles of the coated surfaces after repetitive rubbing. It was found that, for sandblasted glass coated with fluorinated carbon film, the water contact angle remained constant throughout the entire rubbing process, contrary to the smooth glass coated with fluorinated carbon film which showed a drastic decrease in water contact angle with the increasing number of rubbing cycles. In addition, the static and kinetic friction coefficients of the sandblasted glass were also much lower than those of the smooth glass. 相似文献