Electron density distribution in potassium bis -(carbonato)cuprate(II)

The electron density distribution in potassiumbis-(carbonato)cuprate(II) has been analyzed using x-ray diffraction data from an earlier structure determination. While the copper-ligand geometry is close to square planar the deformation density near the metal is strongly asymmetric. There are local maxima near the copper atom along the line of the Cu-K vectors. These resemble features found in corresponding regions in normal length metal-metal bonds. The observation is consistent with the long range nature of the Coulomb potential associated with the potassium ion.     

Bedeutung der GC-Detektoreigenschaften

Ohne Zusammenfassung

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Electrochemical response of ascorbic acid at conducting and electrogenerated polymer modified electrodes for electroanalytical applications: a review

The present short review deals with electroanalytical aspects of electrochemical response of ascorbic acid (Vitamin C) at conducting and electrogenerated polymer modified electrodes. Two main topics are considered: (i) electrocatalytic oxidation of ascorbate at conducting polymer modified electrodes, leading to electroanalytical techniques for ascorbate assay, and (ii) retardation of ascorbate penetration through a layer of electrogenerated polymers, leading to permselective coatings and their diverse uses, especially for biosensing devices.     

Characterization of the organization in shear layers via the Proper Orthogonal Decomposition

Experiments are performed in an incompressible plane turbulent mixing layer, using various hot wire rake configurations. From these experiments, the Proper Orthogonal Decomposition is applied for kernels where the space-time correlation tensor is evaluated over different spatial meshes and velocity components configurations. The resulting decompositions are then discussed in terms of characterization of the organization of the flow for various scalar or vectorial approaches of the POD. An incrtial range law is evidenced. The instantaneous contribution of the first modes of the POD to the organization of the flow is analyzed. A dynamical behavior for the organization of the flow is observed from the correlation between the first two modes contribution.     

On three conjectures by K. E. Shuler

Some fifteen years ago, Shuler formulated three conjectures relating to the large-time asymptotic properties of a nearest-neighbor random walk on ² that is allowed to make horizontal steps everywhere but vertical steps only on a random fraction of the columns. We give a proof of his conjectures for the situation where the column distribution is stationary and satisfies a certain mixing codition. We also prove a strong form of scaling to anisotropic Brownian motion as well as a local limit theorem. The main ingredient of the proofs is a large-deviation estimate for the number of visits to a random set made by a simple random walk on . We briefly discuss extensions to higher dimension and to other types of random walk.Dedicated to Prof. K. E. Shuler on the occasion of his 70th birthday, celebrated at a Symposium in his honor on July 13, 1992, at the University of California at San Diego, La Jolla, California.     

基于时间域读出的大动态范围CMOS图像传感器

设计了一款基于时间域读出的大动态范围CMOS图像传感器。传感器基于一种新型的结构,其可在时间域下探测高输入光强,在模拟域下探测低输入光强。该设计在传统电容反馈式跨阻放大器(CTIA)的基础上,新增了时间域测量电路,在不改变原有积分过程的同时可实现连续的大动态范围。基于0.35μm,5V-CMOS工艺进行了256×1线列CMOS图像传感器流片,光电二极管面积为22.5μm×22.5μm,并对器件的光电特性进行了后仿真验证。仿真测试结果表明,基于时间域读出的图像传感器可实现96dB的大动态范围,且时间域和模拟域的两路输出信号可同步输出,功耗为7.98mW。     

基于Zadoff-Chu序列的频控阵稳健波束成形方法

不同于传统相控阵,频控阵（Frequency Diverse Array,FDA）在所有阵元间引入频率偏差,可以生成具有精准指向特性的点状辐射方向图,有效克服传统相控阵方位角相关性导致的接收方向射频信号安全性下降的问题。作为与传统相控阵的本质区别,FDA阵元频偏设置直接影响FDA辐射方向图的形状。为了生成理想的点状方向图,提出了一种Zadoff-Chu FDA（ZC-FDA）稳健波束成形方案,利用Zadoff-Chu序列调整阵元频偏,消除FDA辐射方向图周期性,抑制距离-方位角耦合性。与现有FDA系统相比,ZC-FDA方案在理想点状辐射方向图生成和波束旁瓣水平抑制方面具有明显优势。     

中短波红外图像传感器读出电路研究进展

随着红外技术和探测器性能的进步,中波和短波红外技术在恶劣天气中具有更优秀的成像性能,在民用、军事和航空航天等领域中得到了越来越广泛的应用。读出电路作为连接探测器阵列与后级图像处理电路的关键模块,其性能对中短波红外相机系统性能具有重要影响,决定了最终的成像质量。文章综述了中短波红外图像传感器读出电路的发展现状,分析了读出电路中噪声、动态范围、帧频等问题,重点探讨了针对以上问题的解决方案。最后对读出电路未来设计的改进方向进行了讨论。     

Short packet communication in underlay cognitive network assisted by an intelligent reflecting surface

We propose short packet communication in an underlay cognitive radio network assisted by an intelligent reflecting surface (IRS) composed of multiple reconfigurable reflectors. This scheme, called the IRS protocol, operates in only one time slot (TS) using the IRS. The IRS adjusts its phases to give zero received cumulative phase at the secondary destination, thereby enhancing the end-to-end signal-to-noise ratio. The transmitting power of the secondary source is optimized to simultaneously satisfy the multi-interference constraints, hardware limitations, and performance improvement. Simulation and analysis results of the average block error rates (BLERs) show that the performance can be enhanced by installing more reconfigurable reflectors, increasing the blocklength, lowering the number of required primary receivers, or sending fewer information bits. Moreover, the proposed IRS protocol always outperforms underlay relaying protocols using two TSs for data transmission, and achieves the best average BLER at identical transmission distances between the secondary source and secondary destination. The theoretical analyses are confirmed by Monte Carlo simulations.     

DRBR-HDR: Dual-Branch recursive band reconstruction network for HDR with large motions

Ghosting artifacts due to misaligned imaging and missing content of the moving regions are major challenges of synthesizing high dynamic range (HDR) images from multiple low-dynamic range (LDR) with different exposures in dynamic scenes. Therefore, it hopes the HDR reconstruction model can align the LDRs’ features and restore the missing content without artifacts. In the paper, a new dual-branch recursive band reconstruction network for high dynamic range (DRBR-HDR) is proposed to generate credible result in missing content regions, which not only uses global features as supplementary information to help local features from different receptive fields for efficient feature alignment but also designs a series of coarse-to-fine band representation to better repair missing areas in the process of recursion. In addition, we introduce an interactive attention mechanism for local branches to alleviate ghosting artifacts. The experimental results demonstrate that DRBR-HDR achieves state-of-the-art performance compared with that of the prevailing HDR reconstruction methods in various challenging scenes.Index Terms—inverse tone mapping, band reconstruction, global features, high dynamic range images.