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21.
Carbon nanomaterials such as carbon nanotubes (CNTs), graphene and their hybrid have been studied extensively. Despite having excellent properties of CNTs and graphene have not yet been fully realized in the polymer composites. During fabrication agglomeration of CNTs and restacking of graphene is a serious concern that results in the degradation of properties of nanomaterials into the final composites. To improve the dispersion of CNTs and restacking graphene, in the present research work, we focused on the hybridization of graphene oxide and CNTs. Multiwalled carbon nanotubes (MWCNTs), functionalized carbon nanotubes (FCNTs), and graphene oxide-carbon nanotubes (GCNTs) reinforced acrylonitrile butadiene styrene (ABS) composites were prepared separately by vacuum filtration followed by hot compression molding. Further, dynamic mechanical analysis (DMA), and electromagnetic interference (EMI) shielding properties of ABS composites reinforced carbon nanofillers were investigated. The dynamic mechanical properties of polymers strongly depend on the adhesion of fillers and polymer, entanglement density of polymer chains in the presence of carbon fillers. The dynamic mechanical characteristics such as storage, loss modulus, and damping factor of prepared composites were significantly affected by the incorporation of MWCNTs, FCNTs, and GCNTs. Maximum EMI shielding effectiveness of −49.6 dB was achieved for GCNT-ABS composites which were highest compared to MWCNTs-ABS composites (−38.6 dB) and FCNTs-ABS composites (−36.7 dB) in the Ku band (12.4–18 GHz). These results depict the great potential of GCNTs-ABS composites to be used in various applications of efficient heat dissipative EMI shielding materials for electronic devices. 相似文献
22.
AbstractThe study on inhibitory effects of resveratrol glucosides (REs) on advanced glycation endproducts (AGEs) formation is still unmet. Herein, for the first time, the antiglycation activities of five REs in the fetal bovine serum proteins (FBS)/fructose system were evaluated, and its structure-activity relationship and antiglycation mechanism were further explored. These REs showed remarkable inhibition toward AGEs formation. Among them, Piceatannol-3'-O-glucoside (PG) exhibited highest antiglycation activity as reflected in approximately 80% inhibition of fluorescent AGEs at the concentration of 1.0?mM. The structure-activity relationship analysis indicated that glucoside attached to the B ring of resveratrol displays a superior antiglycation activity. Moreover, the results of antiglycation mechanism showed that the antiglycation activity of REs was proportional to their antioxidant capacity and methylglyoxal (MGO) trapping capacity. Therefore, the REs are promising candidates worthy of further exploration for preventing AGEs accumulation in vivo, thereby treating AGEs-associated diseases. 相似文献
23.
Jayakody A. Chandrasiri Charles A. Wilkie 《Journal of polymer science. Part A, Polymer chemistry》1996,34(6):1113-1120
The graft copolymerization of acrylic acid onto acrylonitrile-butadiene-styrene terpolymer (ABS), has been initiated by the use of both benzoyl peroxide and azobisisobutyronitrile. Addition occurs in the butadiene region of the polymer, either by the loss of a vinylic hydrogen and subsequent radical formation and addition of monomer or by addition to the double bond. The amount of acrylic acid which may be added is dependent upon the time and temperature of the reaction and the concentration of monomer and initiator. Thermal analysis of the grafted samples show that the residue is less than that expected based upon the composition of the copolymer; similar results have been previously obtained for acrylic acid grafted by another technique. © 1996 John Wiley & Sons, Inc. 相似文献
24.
THOMAS C. JEDREY EDGAR H. SATORIUS MARTIN J. AGAN 《International Journal of Satellite Communications and Networking》1996,14(3):191-200
This paper presents a new open-loop technique for estimating and correcting Doppler frequency shift in K/Ka-band communication systems with special reference to the advanced communications technology satellite (ACTS) mobile terminal (AMT) modem, which utilizes square-wave pulse-shaped, binary differential phase shift-keyed (DPSK) modulation. The novelty of this estimation scheme is that it exploits the Doppler-induced phase shift over a fraction of a symbol interval to provide an estimate of the Doppler offset, without requiring symbol synchronization. Furthermore, by utilizing time-differential detection (delay-and-multiply), the proposed technique can tolerate much larger frequency offsets than existing open- or closed-loop techniques. Analytical results are provided for the variance of the above estimator and the error probability performance of the AMT is evaluated in the presence of the Doppler correction. Practical design considerations are also discussed, including a method for modifying the front end, digital bandlimiting filter in such a way that Doppler bias effects in the new estimator are eliminated. Simulation results reveal that, in general, performance improves with increasing data rates, i.e., the new frequency offset estimation/compensation algorithm induces a degradation from ideal of approximately 1 dB at a 6 dB energy per data symbol (bit) and a 2⋅4 kbps data rate. However, there is no appreciable degradation when the data rate is increased to 9⋅6 or 19⋅2 kbps. 相似文献
25.
Saida Sissi Silvia Di Giacomo Claudio Ferrante Paola Angelini Alberto Macone Anna Maria Giusti Chiara Toniolo Annabella Vitalone Aghraz Abdellah Mustapha Larhsini Luigi Menghini Mohammed Markouk Gabriela Mazzanti Antonella Di Sotto 《Molecules (Basel, Switzerland)》2022,27(3)
In the present study, the phytochemical composition and bioactivities of A. maroccanus (AM) and A. radiatus (AR), two ecotypes collected in the Demnate road and Essaouira regions, respectively, were studied to highlight a pharmacological interest and to enable possible pharmaceutical development. To this end, methanolic and ethyl acetate extracts were prepared for each ecotype by fractionation; next, their phytochemical composition was evaluated by spectrophotometric and chromatographic analysis. Moreover, in line with the available evidence for Anacyclus spp. and their traditional use, a screening of bioactivities, including antioxidant, hypoglycemic, antiglycative, chelating, and antibacterial activities, was performed. The extracts were characterized by high amounts of polyphenols, tannins, and flavonoids, especially in the methanolic extracts; these samples were also enriched in carotenoids despite a lower chlorophyll content. Chlorogenic acid and rutin were the major identified compounds. The extracts also showed interesting hypoglycemic, antiglycative, and antibacterial properties, although with differences in efficacy and potency. Present results provide more scientific basis to the ethnopharmacological uses of Anacyclus spp. and suggest a further interest in AM and AR ecotypes as natural sources of bioactive compounds and/or phytocomplexes for possible pharmaceutical and nutraceutical developments. 相似文献
26.
通过熔融共混法制备了苯乙烯-马来酸酐共聚物(SMA)增容的尼龙6(Nylon-6)/ABS共混物.采用TEM、SEM、FTIR等研究了SMA增容的Nylon-6/ABS共混物的相形态与性能.发现在Nylon-6和ABS的简单共混体系中,分散相易聚集,相界面清晰,断裂面光滑,呈脆性断裂,相容性差.加入少量SMA后,共混物由共连续相结构转变为典型的"海-岛"结构,分散相分布均匀,界面粘接程度增加,表明SMA对Nylon-6/ABS体系有显著的增容效果. 相似文献
27.
在避免母体结构坍塌的前提下,通过缺陷工程对金属有机骨架(MOFs)进行处理可有效提升其去除水体污染物的性能。目前,通过调整合成条件(温度、金属/配体比例等)、添加调制剂、热处理和金属节点取代等方式可制备缺陷MOFs。粉末X射线衍射(PXRD)、比表面积分析、热重-差热分析(TGA-DSC)、电子顺磁共振(EPR)、X射线光电子能谱(XPS)、高分辨率透射电子显微镜(HR-TEM)、球差校正透射电镜(AC-TEM)和X射线吸收光谱(XAS)表征技术可证实MOFs中缺陷的特征。相比原始MOFs,从光催化等高级氧化的角度来看,构造缺陷型MOFs可促进电子转移、减小带隙以提升其高级氧化降解去除污染物的性能。此外,缺陷型MOFs还可为污染物提供更多吸附位点,进一步提升吸附剂的吸附容量和吸附速率。本文系统总结缺陷MOFs的制备方法、现有常见表征技术及其在水处理领域中的应用。同时,本文还根据缺陷MOFs用于去除水中污染物的研究现状对其今后发展予以展望。 相似文献
28.
第二代氨合成催化体系——钌系氨合成催化剂及其工业应用* 总被引:12,自引:0,他引:12
本文综述了第二代氨合成催化体系——钌系氨合成催化剂的研制、开发及工业应用情况。介绍了钌系氨合成催化剂的载体、促进剂、钌活性前身物对氨合成催化活性的影响。比较了钌系氨合成催化剂与铁系氨合成催化剂的反应机理与性能特点。新型氨合成催化工艺流程的成功开发为钌系氨合成催化剂的工业应用提供了有力的保障。 相似文献
29.
30.
Carlos M.S. Vicente Toms S. Martins Marco Leite Antnio Ribeiro Luís Reis 《先进技术聚合物》2020,31(3):501-507
This work aims to determine the influence of fused deposition modeling (FDM) printing parameters on the mechanical properties of parts fabricated on an Ultimaker2 printer with acrylonitrile butadiene styrene (ABS). The effect of several parameters such as interlayer cooling time (ILCT), nozzle diameter, infill density, raster angle and layer thickness on the ultimate tensile strength, yield strength, and elastic modulus of produced parts was evaluated. Two independent studies were conducted: a first study dedicated to the ILCT and a second study where the influence of other parameters was evaluated through a design of experiments (DoE) approach. Both studies were carried out through the execution of standard tensile tests. The statistical analysis of tensile tests results was processed with the ANOVA methodology. The obtained results indicate that a reduced ILCT improves the tensile strength of parts. It is shown that nozzle diameter and infill density are the parameters that most influence the mechanical properties of ABS, with the upper range selected values improving the studied mechanical properties. The raster angle configuration of (?45o/45o) benefits UTS and yield strength of ABS samples. Interactions of nozzle diameter on layer thickness were detected. It was observed that smaller layer thickness promotes a higher elastic modulus and UTS; however, for thinner layers (0.06‐0.10 mm), no significant differences were found on strength of samples due to potential high distortion levels. 相似文献