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101.
102.
Natalia Fridman Moshe Kapon Yana Sheynin Menahem Kaftory 《Journal of inclusion phenomena and macrocyclic chemistry》2006,54(3-4):153-157
1,3-Benzenediamine,N,N′-bis(4,6-dichloro-1,3,5-triazine-2-yl) and 1,3,5-Triazine,2,2′-[2-methyl-1,3-phenylenebis(oxy)] bis(4,6-dichloro) were synthesized as host molecules. The inclusion compound of 1,3-Benzenediamine,N,N′-bis(4,6-dichloro-1,3,5-triazine-2-yl) crystallizes in the monoclinic crystal system in space group C2/c. The host molecule occupies the space group 2-fold special position and packed in the crystal lattice in such a manner as to leave channels running along the c axis of a rectangular cross-section. It crystallizes with two molecules of acetone that are hydrogen bonded to the amino nitrogen atoms. Molecules of 1,3,5-Triazine,2,2′-[2-methyl-1,3-phenylene bis(oxy)]bis(4,6-dichloro) are packed in the crystal in such a manner as to leave channels of a trapezoid cross-section that are running along the a axis. Guest molecules such as metanol, ethanol, and ethyl acetate can be used to fill the channels. The crystal structures of two inclusion compounds are described. 相似文献
103.
Fiaty K Charcosset C Perrin B Couturier R Maïsterrena B 《Journal of computational chemistry》2005,26(3):201-213
Simulations of coupled interactions involving two opposite enzymatic reactions, solute diffusions, and electrostatic interactions between membrane charges and charged solutes were conducted under a fixed kinase-channel-phosphatase (KCP) topology oriented from the outside to the inside of a porous membrane structure. Depending on the kinase and phosphatase locations, we recently demonstrated that an active transport of a phosphorylated substrate may occur via the opposite topology, that is, a PCK topology. The present analysis demonstrates that, under a KCP membrane topology, which also behaves as a specific ATP-dependent transporter, the active transport of a neutral substrate may occur. This analogous active transport appears to be dependent on the phosphatase location and on the membrane surface potentials. A broad analysis of the role played by the main parameters taken into account in the model was conducted in order to define precisely the physico-chemical conditions and the membrane topology needed for the highest active transports within the shortest time. 相似文献
104.
L. Belvisi S. Brossa A. Salimbeni C. Scolastico R. Todeschini 《Journal of computer-aided molecular design》1991,5(6):571-584
Summary A structure-activity relationship study has been done on 8 compounds with the activity known as Ca2+ channel blockers. Conformational analysis was carried out using a molecular mechanics method. The 3D-QSAR approach was used and the most polar functional groups present in all the molecules were considered. Eight interatomic distances are necessary to define the relative spatial disposition of these relevant molecular fragments. The structure-activity relationship between interatomic distances and biological activity was performed using statistic and chemometric methods. In particular, with Principal Component Analysis, it was possible to reduce the number of interatomic distances: only six of the eight distances are sufficient to describe the system in a useful way. A classification method was iteratively used to select the most probable conformations linked to the biological activity and to build a model able to classify conformations according to their biological behaviour. Cluster analysis on the active selected conformations subsequently allowed the identification of two different geometrical patterns for the active compounds. Finally the validity of the model was verified by correctly predicting the activity of other molecules not used in the construction of the model but possessing known activity. 相似文献
105.
Ludovic Jullien Jean-Marie Lehn 《Journal of inclusion phenomena and macrocyclic chemistry》1992,12(1-4):55-74
An approach to a transmembrane cation channel is described. It is based on the grafting of oxygen bearing side-chains on a macrocyclic polyether unit that constitutes the organizing core. The resulting species has a structure of overall bouquet shape. The synthesis of such a molecule .
M
0
,14a is described, together with that of its analogue bearing polymethylene side-chains
M
C
,14b. The physicochemical properties of these molecules indicate that they possess the features expected on the basis of their structure.This paper is dedicated to the memory of the late Dr C. J. Pedersen. 相似文献
106.
最近几年,人们进行了许多超宽带信道模型的室内试验,提出了几种反映超宽带信道特性的模型.文中给出了路径损耗模型、修正的泊松模型、Δ-K模型、S-V模型模型、2簇模型和IEEE 802.15.3a标准模型等模型及其参数特征和优缺点,并分析了今后超宽带模型建模应该注意的问题. 相似文献
107.
采用25.344 Mbit/s光监控信息传送技术可以更好地满足当前密集波分复用(DWDM)系统中不断增加的网络监控信息和附加业务的需要.文章首先介绍了25.344 Mbit/s光监控信息传送系统的技术方案,然后详细描述了其帧结构、码型设计以及硬件实现的框图,最后介绍了该技术的优点. 相似文献
108.
OFDM是一项能有效对抗高速无线通信中多径衰落的关键技术,为了进一步提高OFDM系统的误码性能,许多信道编码技术已被应用于OFDM系统中,二元域LDPC码以其近香农限的误码性能和较低的译码复杂度成为研究的热点。在AWGN信道下,多元域LDPC码比等效码长的二元域LDPC码有更好的纠错性能。本文提出了一种将多元域LDPC码经过MPSK调制后用于OFDM系统的新方法。仿真结果表明,在多径衰落信道下,通过合理选择多元LDPC码域的阶数和调制的方法,多元域LDPC编码的高阶调制OFDM系统比等效码长的二元域LDPC编码OFDM系统具有更好的性能,并且由于采用了多元域LDPC的快速BP译码,译码复杂度只是稍有增加。 相似文献
109.
提出一种使用FPGA(现场可编程门阵列)实现一个ITU-R BT.656并行硬件接口传输4路CIF格式视频流的方法。该方法说明了从视频处理器到FPGA传输4路CIF格式视频流的数据结构,利用该数据结构,一个ITU-R BT.656的硬件接口可传输4路不同的CIF格式的视频数据流。FP-GA将4路视频数据流分离、插值生成D1(720×576像素)格式的数据输出给视频处理器。这种方法提高了视频处理器的扩展性,增加了视频处理器输出视频的路数。 相似文献
110.