基于单分类支持向量机和主动学习的网络异常检测研究

对基于支持向量机和主动学习的异常检测方法进行了研究,首先利用原始数据采用无监督方式建立单分类支持向量机模型,然后结合主动学习找出对提高异常检测性能最有价值的样本进行人工标记,利用标记数据和无标记数据以半监督方式对基于单分类支持向量机的异常检测模型进行扩展。实验结果表明,所提方法能够利用少量标记数据获取性能提升,并能够通过主动学习减小人工标记代价,更适用于实际网络环境。     

轮廓特征包在激光主动照明识别系统中的应用

提出了一种结合轮廓转动惯量和特征包(Bo F)算法的激光主动照明目标识别方法。介绍了转动惯量的定义,并提出了一种多尺度轮廓转动惯量特征区域检测方法和轮廓转动惯量局部不变特征提取方法。多尺度轮廓转动惯量特征区域检测方法能够提取出包含轮廓的最小特征区域,而轮廓转动惯量局部不变特征能够很好地描述轮廓的大小、位置、规则度等信息,对于各种图像变换具有不变性,并且计算效率较高。使用Bo F算法统计图像的轮廓转动惯量局部不变特征,生成归一化特征直方图作为整幅图像的特征向量,输入训练好的支持向量机分类器进行识别。实验结果表明与基于Hu矩和BP神经网络的目标识别方法相比,所提算法在旋转和仿射变换下的识别率分别提高7.33%和19.08%。     

Study of stability problems due to undesired coupling of a RF power amplifier using a distributed active transformer

In this study, we investigate the stability problems induced by undesired coupling between input feed lines and an output transformer for a linear CMOS power amplifier using a distributed active transformer (DAT) as an output balun. We extracted the losses of the input and output transformer, the undesired coupling, and the gains of the driver and the power stages to calculate the closed-loop gain. To determine the possibility of oscillation according to the location of the driver stage related to the undesired coupling and the closed-loop gain, we investigated the stability factor and stability circle. We show that the location of the driver stage of the power amplifier can be used to manage the value of the closed-loop gain. From the analyzed results, the driver stage of the linear power amplifier should be located outside the DAT to mitigate the stability issues.     

一种考虑互耦的脉冲天线阵列快速计算方法

基于有源单元方向图思想,提出了一种可用于计算脉冲天线阵列时域辐射场的快速方法.该方法在考虑单元间互耦的情况下,将大型阵列的时域辐射场计算问题转化为一个小型阵列的计算问题,大大地减少了计算量.采用文中的阵列综合方法,结合有限积分法软件,仅对一个5×5元阵列进行模拟,即可推算出大型阵列的远场方向图,其计算时间不超过全波模拟时的十分之一.计算结果与仿真软件的仿真结果吻合较好,验证了方法的正确性.     

Synthesis and Stereochemistry of Optically Active Selenium and Tellurium Compounds

Abstract

The synthesis and stereochemistry of tricoordinated optically active selenium and tellurium compounds are described. Telluronium salts, telluronium imides, and seleninic acids were prepared and optically resolved by fractional recrystallization of diastereomeric mixtures or by chromatography using a chiral column of racemic mixtures. Diphenyl dichalcogenides also were optically resolved by chiral crystallization. Their absolute configurations were determined or estimated based on X-ray crystallographic analysis, specific rotations, and circular dichroism spectra. The kinetic studies and the mechanism for the racemization were also studied.     

SYNTHESIS AND BIOLOGICAL ACTIVITIES OF NEW INDOLE DERIVATIVES CONTAINING SULFIDE AND/OR SULFONE MOIETIES. PART I

Abstract

4-Amino-halonitrodiphenyl sulfides(I) and/or 4-amino-halonitrodiphenyl sulfones have been found to react with isatin, N-acetyl isatin, isatin-N-Mannich bases, indole-3-carboxaldehyde and N-substituted indole-3-carboxaldehyde producing the corresponding indole derivatives. The biological activity of some of these products was screened against selected strains of bacteria.     

SYNTHESIS AND CONFORMATIONAL STUDIES OF A NUMBER OF SATURATED BICYCLIC SIX-MEMBERED RING PHOSPHITES

Abstract

An ¹H NMR study of the conformation of the dioxaphosphorinane ring of a number of diastereoisomeric bicyclic saturated six-membered ring phosphites (3ab-10ab) has been performed. The dioxaphosphorinane ring of these phosphites is transannelated with a tetrahydrofuran, cyclopen-tane, tetrahydropyran or cyclohexane ring. The substituent on the phosphorus atom is a methoxy or phenoxy group. It is shown that the cis isomers 3a-10a prefer a chair conformation of the dioxaphosphorinane ring, independent of the substituent on the phosphorus atom and of the nature of the transannelated ring. In contrast, for the trans isomers 3b-10b a twist rather than a chair conformation of the dioxaphosphorinane ring is preferred. The fraction of the twist conformer in the trans isomers is mainly determined by the substituent on phosphorus. The size and composition of the transannelated ring are relatively unimportant in this respect. For both cis and trans isomers the preferred geometry is solvent-independent. The measured ^3JPOCH couplings of the cis isomers 3a-10a are used to formulate an expression for the dependence of such couplings upon dihedral angles in bicyclic phosphites.     

Preparation and Characterization of New Optically Active Poly(amide-imide)s from N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetra carboxylic)-bis-L-isoleucine and Aromatic Diamines

Five new optically active aromatic poly(amide-imide)s (PAIs) 5a–e were prepared from a direct polycondensation reaction of a new diacid of N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetra carboxylic)-bis-L-isoleucine 3 with various aromatic diamines 4a–e in a medium consisting of triphenyl phosphite (TPP), calcium chloride (CaCl₂), pyridine (Py) and N-methyl-2-pyrrolidone (NMP). The polycondensation reaction produced a series of novel poly(amid-imide)s 5a–e in quantitative yields with inherent viscosities of 0.39–0.51 dL/g. The resulting polymers were fully characterized by means of ¹H-NMR, FT-IR spectroscopy, elemental analyses, inherent viscosity, solubility test, specific rotation and thermal properties of them were investigated using TGA/DTG and differential scanning calorimeter (DSC). The diacid 4 was synthesized by the condensation reaction of bicyclo[2,2,2]oct-7-ene-2,3,5,6- tetracarboxylic dianhydride 1 with L-isoleucine 2 in acetic acid solution.     

Computational Enzyme Design

Recent developments in computational chemistry and biology have come together in the “inside‐out” approach to enzyme engineering. Proteins have been designed to catalyze reactions not previously accelerated in nature. Some of these proteins fold and act as catalysts, but the success rate is still low. The achievements and limitations of the current technology are highlighted and contrasted to other protein engineering techniques. On its own, computational “inside‐out” design can lead to the production of catalytically active and selective proteins, but their kinetic performances fall short of natural enzymes. When combined with directed evolution, molecular dynamics simulations, and crowd‐sourced structure‐prediction approaches, however, computational designs can be significantly improved in terms of binding, turnover, and thermal stability.     

退火温度对TiO2/CdSe纳米片异质结薄膜光电性能的影响

采用水热法在FTO上制备（001）高活性晶面主导的TiO₂纳米片薄膜,利用循环伏安法在TiO₂纳米片薄膜上沉积CdSe颗粒,制备了TiO₂/CdSe纳米片异质结薄膜。分别在150、250、350、450 ℃,氩气保护气氛中对样品进行退火。利用X射线衍射仪（XRD）、场发射扫描电镜（FESEM）、X射线光电子能谱分析仪（XPS）、紫外-可见（UV-Vis）分光光度计以及电化学工作站对不同温度退火后的TiO₂/CdSe纳米片异质结薄膜的微观形貌、晶体结构、光电化学性能进行表征和测试。结果表明：六方相CdSe纳米颗粒均匀包覆在TiO₂纳米片表面,直径30 nm左右;随着退火温度的升高CdSe纳米颗粒长大,形成光滑的CdSe薄膜,且晶化程度提高;TiO₂纳米片表面的Se元素与Cd元素发生氧化;TiO₂/CdSe纳米片异质结薄膜对可见光的吸收光谱发生红移,禁带宽度逐渐减小。光电化学性能测试表明随着退火温度的升高,TiO₂/CdSe纳米片异质结薄膜的光电流密度显著提高,开路电压减小,但由于SeO2和CdO的出现,导致填充因子减小,影响光电转换效率的提高。在本实验条件下,TiO₂/CdSe纳米片异质结薄膜的最佳退火温度为150 ℃,填充因子为0.77,光电转换效率达到3.12%。