335 GHz非平衡式肖特基二极管三倍频器

基于混合集成的方式,采用对称锥形渐变线匹配结构设计了335 GHz非平衡式三倍频器。在保证单模传输的条件下,该匹配结构不仅能够固定二极管位置,而且可以增大匹配效果,解决了高频段倍频器3 dB带宽较窄的问题。实测结果表明,该倍频器在330~356 GHz频率范围内输出功率均大于5 mW。驱动功率为220 mW时,有最高输出功率11.2 mW,由它作为核心器件组成的固态太赫兹本振源,能够驱动超外差接收机中670 GHz二次谐波混频器。     

一种基于熵源分离模型的可重构安全原语

在信息爆炸时代,信息的安全问题受到了广泛关注。在物联网设备的加密协议中,物理不可克隆函数(PUF)与真随机数发生器成为加密协议中基本的安全原语,提供了轻量级的解决方案。文章提出了一种熵源分离模型,能够分离环形振荡器中抖动(真随机数发生器的熵)和工艺偏差(PUF熵)引起的延时。基于该模型,在FPGA上设计了一种可重构的双工作模式电路,通过改变模式可分别生成PUF和真随机数。相较于FPGA上独立设计的PUF和真随机数发生器,该结构具有资源开销小、面积利用率高、功耗低等优势。实验结果表明,生成的PUF稳定性高、唯一性强、均匀性好;真随机数序列均通过了NIST测试,具有高随机性和不可预测性。     

一种应用于HDMI接收端的宽频带锁相环设计

基于110 nm CMOS工艺设计了一种应用于HDMI接收端电路的宽频带低抖动锁相环。采用一种改进型双环结构电荷泵,在25～250 MHz的宽输入频率范围内实现了快速锁定。通过高相噪性能的伪差分环形振荡器产生了调谐范围为125 MHz～1.25 GHz的时钟信号。仿真实验结果表明,该锁相环的锁定时间小于1.2μs,在振荡器工作频率为0.8 GHz时,其相位噪声为-100.0 dBc/Hz@1 MHz,输出时钟峰峰值抖动为4.49 ps。     

用于超外差接收机提供本振源的高功率510 GHz单片集成三倍频器

本文介绍了一种基于砷化镓材料的高功率490~530 GHz单片集成三倍频器。基于提出的对称平衡结构,该三倍频器不仅可以实现良好的振幅和相位平衡,用来实现高效的功率合成,还可以在没有任何旁路电容的情况下提供直流偏置路径以保证高效倍频效率。同时,开展容差性仿真分析二极管关键电气参数与结构参数对倍频性能的影响研究,以便最大化提升倍频性能。最终,在大约80~200 mW的输入功率驱动下,研制的510 GHz三倍频,在490~530 GHz频率范围内,输出功率为4~16 mW,其中峰值倍频效率11%。在522 GHz频点处,该三倍频在218 mW的输入功率驱动下,产生16 mW的最大输出功率。该三倍频器后期将用于1 THz的固态外超外差混频器的本振源。     

Geometric modules and Quinn homology theory

LetR be a ring with unit and invariant basis property. In [1], the authors define a functorK(_;R):TOP/LIP _c-LPEP by combining the open cone construction of [7] with a geometric module construction and show this functor is a homology theory. This paper shows that if attention is restricted to objects TOP/LIP _c with a homotopy colimit structure, then the functorK(_;R) is a Quinn homology theory, In particular, for each having a homotopy colimit structure,K(;R) is a homotopy colimit in the category of -spectra. Furthermore, the constituent spectra of this homotopy colimit are obtained naturally from the fibres of .Partially supported by the National Science Foundation under grant number DMS88-03148.Partially supported by the SNF (Denmark) under grant number 11-7792.     

Axial dispersion in a liquid fluidized bed of particles akin to immobilized enzymes

The axial dispersion of a liquid fluidized bed of controlled pore silica (CPS) particles has been determined by the pulse tracer method. The CPS used was the same as for enzyme immobilization, having an average diameter of 0.436 mm and mean pore size of 37.5 nm. The fluidization liquid is α-amylase liquefied manioc starch, 30% w/v, 45°C pH=4.5. Nominal bed porosities tested were 0.7 and 0.8. The results show that the axial dispersion coefficient increases with greater superficial liquid velocities. Various available correlations tested disagree with each other to a large extent and are unable to represent collected experimental data.     

聚L－谷氨酸－炔诺酮肟酯复合体的制备

合成了聚Ｌ－谷氨酸－炔诺酮肟酯的复合体，炔诺酮的接入量为２２．８％．体外释放时间约１５大。     

Variation of the ℏω with the particle number and the appearance of “kinks” for atomic clusters

The dependence of the harmonic oscillator (HO) energy level spacing ?ω on the particle number N is studied analytically for atomic (metal) clusters on the basis of their electronic densities, parametrizing Ekardt's results (for sodium clusters) by means of a Fermi distribution. An interesting feature of such an approach is that it leads, under the assumptions made, to “kinks,” that is, to “marked discontinuities in the slope” of ?ω at the closed shells. These discontinuities diminish as N increases. For large N, ?ω becomes simply: ?ω?c₁N^?1/3+c₂N^?1. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem, 2001     

主链含膦酸酯的聚酸酐药物控制释放材料研究

通过二氯膦甲（乙）酸乙酯与对羟乙氧基苯甲酸反应，制备了二羧苯氧乙氧基膦甲（乙）酸乙酯，并其转化成混合醋酐并通过熔融缩聚，合成了主链含膦甲（乙）酸乙酯的聚酸酐，以二羧苯氧乙氧基膦甲（乙）酸乙酯，分别与１，３－双（４－羧基苯氧基）丙烷（ＣＰＰ）及癸二酸（ＳＡ）共聚，得到相应的共聚酸酐，对所合成的单体和聚合物的结构进行了表征，研究了它们的体外降解，酶促降解及其对抗肿瘤药物５－氟尿嘧啶和氨甲喋蛉的释放性能     

Sterically hindered aliphatic amines in the controlled synthesis of polystyrene

The kinetic features of radical polymerization of styrene in the presence of primary and secondary aliphatic amines combined with benzoyl peroxide and the molecular-mass characteristics of the resulting polymers were studied. In the presence of peroxide initiators, aliphatic amines, as potential sources of stable aminoxyl radicals, provide the synthesis of polystyrene with a controlled molecular mass without gel effect at a relatively high rate. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 159–164, January, 2007.