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991.
Mingjin Wang 《Journal of Mathematical Analysis and Applications》2008,341(2):1487-1494
In this paper, we use the Andrews-Askey integral and the q-Chu-Vandermonde formula to derive a more general integral formula. Applications of the new integral formula are also given, which include to derive the q-Pfaff-Saalschütz formula and the terminating Sears's transformation formula. 相似文献
992.
An efficient regioselective synthesis of pyronyl pendant ethyl methylthiocarbonylalkanoates 5 has been delineated from the base catalyzed reaction of suitably functionalized 2-pyranone 1 and 2-carbethoxycycloalkanones 2, 6 through successive substitution and regioselective ring opening by in situ generated mercaptide ion. To assess the effect of C-4 substituent on regioselectivity, reactions of 6-aryl-3-cyano-4-(piperidin-1-yl)-2-oxopyran 8 with 2-carbethoxycyclohexanone 6a and 2-carbethoxy-2-methylcyclohexanone 6b were carried out separately under analogous reaction conditions but the compounds isolated were identical and characterized as 4-aryl-8-methyl-2-piperidin-1-yl-5,6,7,8-tetrahydronaphthalene-1-carbonitriles 9. Ethyl 2-(5-amino-4′-bromo-4,6-dicyanobiphenyl-3-yl)-5-methylsulfanylcarbonylpentanoate 10 has also been prepared through base catalyzed ring transformation of ethyl 2-[6-(4-bromophenyl)-3-cyano-2-oxo-2H-pyran-4-yl]-5-methylsulfanylcarbonylpentanoate 5d by malononitrile in DMF. 相似文献
993.
By use of Löwdin and Guseinov relations for the radial and angular part of two-center overlap integrals, respectively, the computer calculations of overlap integrals over Slater type orbitals (STOs) in molecular coordinate system are performed. The results of calculations are valid for arbitrary principal quantum numbers, screening constants and location of STOs. Excellent agreement with benchmark results and stability of the technique are demonstrated. 相似文献
994.
Rare-earth orthoferrites, RFeO3, and rare-earth iron garnets (RIGs) R3Fe5O12 (R=rare-earth elements) were prepared by citrate-nitrate gel combustion method and characterized by X-ray diffraction method. Isobaric molar heat capacities of these oxides were determined by using differential scanning calorimetry from 130 to 860 K. Order-disorder transition temperatures were determined from the heat capacity measurements. The Néel temperatures (TN) due to antiferromagentic to paramagnetic transitions in orthoferrites and the Curie temperatures (TC) due to ferrimagnetic to paramagnetic transitions in garnets were determined from the heat capacity data. Both TN and TC systematically decrease with increasing atomic number of R across the series. Lattice, electronic and magnetic contributions to the total heat capacity were calculated. Debye temperatures as a function of absolute temperature were calculated for these compounds. Thermodynamic functions like , , Ho, Go, , , , , and have been generated for the compounds RFeO3(s) and R3Fe5O12(s) based on the experimental data obtained in this study and the available data in the literature. 相似文献
995.
So-Nhu Le 《Journal of solid state chemistry》2008,181(1):20-29
Alkali and ammonium cobalt and zinc phosphates show extensive polymorphism. Thermal behavior, relative stabilities, and enthalpies of formation of KCoPO4, RbCoPO4, NH4CoPO4, and NH4ZnPO4 polymorphs are studied by differential scanning calorimetry, high-temperature oxide melt solution calorimetry, and acid solution calorimetry.α-KCoPO4 and γ-KCoPO4 are very similar in enthalpy. γ-KCoPO4 slowly transforms to α-KCoPO4 near 673 K. The high-temperature phase, β-KCoPO4, is 5-7 kJ mol−1 higher in enthalpy than α-KCoPO4 and γ-KCoPO4. HEX phases of NH4CoPO4 and NH4ZnPO4 are about 3 kJ mol−1 lower in enthalpy than the corresponding ABW phases. There is a strong relationship between enthalpy of formation from oxides and acid-base interaction for cobalt and zinc phosphates and also for aluminosilicates with related frameworks. Cobalt and zinc phosphates exhibit similar trends in enthalpies of formation from oxides as aluminosilicates, but their enthalpies of formation from oxides are more exothermic because of their stronger acid-base interactions. Enthalpies of formation from ammonia and oxides of NH4CoPO4 and NH4ZnPO4 are similar, reflecting the similar basicity of CoO and ZnO. 相似文献
996.
Yu Lu Xianmao Lu Brian T. Mayers Thurston Herricks Younan Xia 《Journal of solid state chemistry》2008,181(7):1530-1538
This paper compares the performance of three long-chain acids—oleic and elaidic (both olefinic) and stearic (aliphatic)—as a capping agent in the synthesis of magnetic Co nanoparticles. The particles were formed through thermal decomposition of dicobalt octacarbonyl in toluene in the presence of the long-chain acid, and characterized by TEM, high-resolution TEM, and SQUID measurements. Infrared spectra revealed that some of the added olefinic acid was transformed from cis- to trans-configuration (for oleic acid) or from trans- to cis- (for elaidic acid) to facilitate the formation of a densely packed monolayer on the surface of Co nanoparticles. As compared to aliphatic acids, olefinic acids are advantageous for dense packing on small particles with high surface curvatures due to a bent shape of the cis-isomer. The presence of an olefinic acid is able to control particle growth, stabilize the colloidal suspension, and prevent the final product from oxidation by air. Our results indicate that oleic acid, elaidic acid, and a mixture of oleic/stearic acids or elaidic/stearic acids have roughly the same performance in serving as a capping agent for the synthesis of Co nanoparticles with a spherical shape and narrow size distribution. 相似文献
997.
998.
通过电子显微镜观察了阴离子gemini表面活性剂C11- p-PhCNa和阳离子传统表面活性剂DTAB混合体系双水相中囊泡形貌随体系组成和浓度的转变。结果表明,双水相较浓的一相中形成了多层囊泡,囊泡的大小和壁厚随相的组成和浓度而改变,两组分等电荷混合有利于形成较大且壁较厚的囊泡。分析表明, gemini表面活性剂在聚集体中采取的反式构象可能是其容易形成厚壁多层囊泡的重要原因,C11- p-PhCNa联接链上的苯氧基与DTA+之间的p-阳离子相互作用以及两组分相反电性头基之间的静电吸引使囊泡壁的多层结构更加稳定。 相似文献
999.
The authors use the method of moving spheres to prove the nonexistence of ground states of -△u = u^p - u^q for n≥3,-∞〈p〈(n+2)/(n-2) and q〉max (1,p),
In fact this conclusion is a special case of -△u =f(u) for n≥2. 相似文献
In fact this conclusion is a special case of -△u =f(u) for n≥2. 相似文献
1000.
鉴于传统三电平逆变电路存在谐波含量高的缺点, 在分析模块化多电平换流器(MMC)工作原理的基础上, 提出使用模块化多电平电路实现光伏并网逆变功能, 采用微分-跟踪器法实现光伏阵列最大功率点跟踪(MPPT)及逆变器PQ解耦控制, 实现了光伏系统以单位功率因数并网。在PSCAD中建立光伏并网系统动态仿真模型, 仿真结果表明, 所建模型具有开关损耗低、谐波量小的优点, 验证了所提方法的正确性和可行性。 相似文献