Spondias mombin L. as a green corrosion inhibitor for aluminium in sulphuric acid: Correlation between inhibitive effect and electronic properties of extracts major constituents using density functional theory

The inhibition of aluminium in 0.5 M H₂SO₄ by extracts of Spondias mombin L. was investigated using the standard gravimetric technique at 30–60 °C. The trend of inhibition efficiency with temperature was used to propose the mechanism of inhibition. It was found that the S. mombin L. extract acts as an inhibitor for acid-induced corrosion of aluminium. Inhibition efficiency (%I) of the extract increased with an increase in concentration of the S. mombin L. extract but decreased with temperature. Furthermore, inhibition efficiency (%I) synergistically increased on addition of potassium iodide. Inhibitor adsorption characteristics were approximated by Langmuir adsorption isotherm at all the concentrations and temperatures studied. The mechanism of physical adsorption is proposed from the trend of inhibition efficiency with temperature and from the calculated values of Gibbs free energy, activation energy and heat of adsorption. Quantum chemical calculations were performed using the density functional theory at B3LYP/6-31G (d) level of theory to find out whether a clear link exists between the inhibitive effect of the extract and the electronic properties of its main constituents.     

耦合渐变槽线天线及其和差波束的矩量法分析

本文阐述一种新型渐变槽线天线（ＴＳＡ）结构,耦合渐变槽线天线ＣＴＳＡ。单片的ＣＴＳＡ除可降低副瓣电平,提高增益,改善Ｅ面Ｈ面波束的对称外,还可通过与之配合的平面印刷奇偶模双工器馈电,同时实现和差波束。本文应用空间域矩量法（ＭｏＭ）建立了分析各种ＴＳＡ结构的数值模型;该方法在没有介质基片的情况下是严重的,本文集中讨论简化ＭｏＭ中阻抗矩阵积分运算的各种技术,有效地减小了计算量,并获得较高的精度。计算结     

宽带DOA估计的类MUSIC波束形成算法

为了提高频域波束形成的宽带波达方向估计性能,提出了类MUSIC波束形成算法(MBM,MUSIC-like Beamfomfing Method).在频域将宽带信号划分为若干窄带信号,叠加各窄带的MBM算法的空间谱后其峰值对应角度即为宽带波达方向估计结果.MBM算法的主瓣宽度在不同分析频率下基本保持不变,计算量与常规波束...     

关于耦合谐振滤波器中耦合极性的几点讨论

对改变带有交叉耦合的耦合谐振滤波器中的耦合系数的极性而不改变滤波器的性能 ,本文给出了一个充分条件及其两个推论。这为滤波器的设计和实现带来了一定的灵活性。结合这一充分条件 ,本文还详细解释了滤波器中的耦合极性的相对性问题。最后给出了在确定耦合系数矩阵后实现滤波器时设计耦合结构的一种通用方法。     

一种基于无线携能通信的MEC与用户匹配算法

多接入边缘计算（Multi-access Edge Computing,MEC）和无线携能通信可有效提高用户的服务质量和体验。在计算、通信和能量等资源的约束条件下,用户匹配是优化MEC任务卸载时系统效用的重要方法。针对无线携能通信的MEC网络结构,综合考虑用户的需求差异性和多元化能量供给,建立了基于计算资源、传输资源和能量资源的系统效用函数;以系统效用最大化为目标,采用基于多维背包理论的多轮拍卖,提出了一种适用于多用户和多网络边缘服务器的用户匹配算法。仿真验证了所提用户匹配算法的有效性与可靠性,结果表明所提匹配算法可优化系统资源配置,有效提高整体性能。     

无线传感器网络中分阶段的无需测距定位算法

为了提高无线传感器网络中基于无需测距算法定位精度,改进质心算法和DV-Hop算法,定位过程分为两个阶段:第一阶段在最佳通信半径与最佳阈值下,用基于阈值的优先质心算法定位部分节点;第二阶段在最佳通信半径与最佳指数值下用DV-Hop算法定位剩余节点。将算法应用在一种锚节点人工部署环境下,并与其他算法对比。MTLAB仿真结果表明,改进的算法在不增加泛洪次数、计算量和网络硬件成本下能提高定位精度,同时实现100%定位。     

Extraction and separation of lanthanides from aqueous chloride and nitrate media using mixtures of binary extractants based on secondary and tertiary amines

1. Download : Download high-res image (97KB)
2. Download : Download full-size image

     

Keller–Osserman estimates and removability result for the anisotropic porous medium equation with gradient absorption term

We study “large” nonnegative solutions for a class of quasilinear equations model of which is We give a sufficient condition on the exponents and for the removability of isolated singularities.