Solid-phase microextraction for qualitative and quantitative determination of migrated degradation products of antioxidants in an organic aqueous solution

Low molecular weight aromatic substances may migrate out from plastic packaging to their contents, especially if they consist of organic aqueous solutions or oils. It is, therefore, extremely important to be able to identify and quantify any migrated substances in such solutions, even at very low concentrations. We have in this work investigated and evaluated the use of solid-phase microextraction for the specific task of extraction from an organic aqueous solution such as a simulated pharmaceutical solution consisting of 10 vol.% ethanol in water. The goal was furthermore to investigate the possibility of simultaneously identifying and quantifying the substances in spite of differences in their chemical structures. Methods were developed and evaluated for extraction both with direct sampling and with headspace sampling. Difficulties appeared due to the ethanol in the solution and the minute amounts of substances present. We have shown that a simultaneous quantification of migrated low molecular weight degradation products of antioxidants using only one fibre is possible if the extraction method and temperature are adjusted in relation to the concentration levels of the analytes. Comparions were made with solid-phase extraction.     

Structural fluctuations in ensembles of nanoparticles

Caused by the interaction between the particles, structural fluctuations influence thermodynamics and order of transformation of an ensemble of nanoparticles. A stringed thermodynamic analysis revealed that, in fluctuating ensembles, the ratio of particle numbers in the equilibrium over the one in the non-equilibrium phase is independent of any metastable in between. Structural transformations in such ensembles, connected to latent heat, are of infinite order. These findings are summarized in a set of theorems ruling structural fluctuations. Finally, the consequences of fluctuations are demonstrated by an example.     

The boundary value problem and the Jensen inequality for an entropy functional of a Markov diffusion process

The paper introduces the recent results related to an entropy functional on trajectories of a controlled diffusion process, expressed through an additive functional of the diffusion process, with a Lagrangian, determined by the parameters of a controlled stochastic equation. These results include a minimum condition for the entropy functional and the functional's Jensen inequality, which both are useful for the solution of important mathematical and applied problems.     

An interdependency index for the outputs of uncertain systems

The study of mechanical systems with uncertain parameters is gaining increasing interest in the field of system analysis to provide an expedient model for the prediction of the system behavior. Making use of the Transformation Method, the uncertain parameters of the system are modeled by fuzzy numbers in contrast to random numbers used in stochastic approaches. As a result of this analysis, a quantification of the overall uncertainty of the system outputs, including a worst-case scenario, is obtained. The inputs of the resulting fuzzy-valued model are a priori uncorrelated but after the uncertainties are propagated through the model, interdependency (or interaction) between the outputs may arise. If such interdependency is neglected, a misinterpretation of the results may occur. For example, in the case of applying uncertainty analysis in the early design phase of a product to determine the relevant design-parameter space, the interdependency between the design variables may reduce significantly the available part of the design space. This paper proposes a measure of interdependency between the uncertain system outputs. The interdependency index can be derived by a postprocessing of the data gained by the analysis with the Transformation Method. Such information can be obtained by a negligible amount of extra computation time.     

Isovariant maps from free -manifolds to representation spheres

The isovariant version of Borsuk–Ulam type theorems has been studied by Wasserman and the first author. In this paper, first we consider the relation between the existence of C_n-isovariant maps from free C_n-manifolds to representation spheres and Borsuk–Ulam type inequalities for their dimensions. Our main result classifies the C_n-isovariant maps by C_n-isovariant homotopy types when a Borsuk–Ulam type inequality holds. For proving it, we use the multidegree of a C_n-equivariant map developed by the first author.     

呼叫中心市场的演进对寻呼企业的影响

呼叫中心技术的演进、Internet的屈起使得近年来呼叫中心产业在全球迅速走红，在我国的业务发展和市场潜力也非常巨大。目前国内各大寻呼企业正在积极寻求转型，如能将其原有设备稍加改造，并利用多年来积累的电信增值服务的经验，经营呼叫服务中心业务将是一个明智之举。     

新形势下电信业转型升级的若干思考

讨论了信息化与工业化融合深入发展的新形势及其对电信业发展转型的新要求,分析国际金融危机和经济危机下各国对电信业发展的战略部署,最后,提出新形势下电信业发展转型、推动信息化与工业化融合的重点任务和主要模式。     

Extremely high concentration of electromagnetic field in the three-dimensional waveguides based on transformation optics

Based on the coordinate transformation theory, we propose a way to manipulate the field distribution in three-dimensional waveguides filled with the designed material. In this work, we show that the designed transformation media can concentrate the electromagnetic field more extremely around the center of the rectangular cross-section inside the straight waveguide. Furthermore, high concentration of the field distribution inside the waveguide bend is also performed well. Numerical simulations demonstrate that the electromagnetic wave can propagate without any signal destruction and conserve the original propagation mode at receiver side.     

Probabilistic solution of random homogeneous linear second-order difference equations

This paper deals with the computation of the first probability density function of the solution of random homogeneous linear second-order difference equations by the Random Variable Transformation method. This approach allows us to generalize the classical solution obtained in the deterministic scenario. Several illustrative examples are provided.