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101.
Willem Potze 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,84(4):575-586
A mathematical model is proposed to describe the heat transfer in quartz glass axisymmetric tubes. Heat is transferred inside the glass by radiation and conduction. Scattering of thermal radiation inside the glass is ignored. At the boundaries of the tube the radiative intensity is specularly reflected. The spectral dependent radiative intensity and the temperature distribution inside the tube are determined. The model is applied to simulate the cooling process of a quartz glass tube. The calculated temperature is in agreement with that obtained from an experiment. Furthermore, steady-state temperature distributions in quartz glass tubes of different lengths have been determined. 相似文献
102.
Synthesis and Structure of K3N Two phases in the binary system K/N have been obtained via co‐deposition of potassium and nitrogen onto polished sapphire at 77 K and subsequent heating to room temperature. The powder diffraction pattern of one of these phases can be satisfactorily interpreted by assuming the composition K3N, and the anti‐TiI3 structure‐type, which is also adopted by Cs3O. The resulting hexagonal lattice constants are: a = 779.8(2), c = 759.2(9) pm, Z = 2, P63/mcm. Comparison with possible structures of K3N generated by computational methods and refined at Hartree‐Fock‐ and DFT level, reveals that the energetically most favoured structure has not formed (presumable Li3P‐type), but instead one of those with very low density. In this respect, the findings for K3N are analogous to the results on Na3N. The thermal evolution of the deposited starting mixture has been investigated. Hexagonal K3N transforms to another K/N phase at 233 K. Its XRD can be fully indexed resulting in an orthorhombic cell a = 1163, b = 596, c = 718 pm. Decomposition leaving elemental potassium as the only residue occurs at 263 K. 相似文献
103.
在逻辑函数的CRM展开式和两种新运算基础上,对函数量大项展开系数和CRM展开系统(dj系数)之间的关系作了较详细的讨论,并提出了两者的矩阵转换法,快速转换法和直接代入转换法,具备较好的实用性. 相似文献
104.
Molar extinction coefficients of aqueous solutions of some organic compounds, viz. formamide (CH3NO),N-methylformamide (C2H5NO),NN-dimethylformamide (C3H7NO),NN-dimethylacetamide (C4H9NO), 1,4-dioxane (C4H8O24), succinimide (C4H5NO2) and solutions of acetamide (C2H5NO) and benzoic acid (C7H6O2) in 1,4-dioxane (C4H8O2) have been determined by narrow beam γ-ray transmission method at 81, 356, 511, 662, 1173 and 1332 keV. The experimental
values of mass attenuation coefficients of these compounds have been used to calculate effective atomic numbers and electron
densities. The additivity rule earlier used for aqueous solution has been extended to non-aqueous (1,4-dioxane) solutions. 相似文献
105.
证明了布尔减、异或运算以及布尔除、符合运算的完备性,并从与-异或及或-符合代数系统中的RM、CRM展开式出发,分别推导了任意逻辑函数在布尔减-异或及布尔除-符合代数系统中的规范展开式.举例说明了与-或-非代数系统中规范展开式与布尔减-异或、布尔除-符合代数系统中的规范展开式之间的转换. 相似文献
106.
Armin C. Schneider Christoph Pasel Michael Luckas Klaus Gerhard Schmidt Jan-Dirk Herbell 《Journal of solution chemistry》2004,33(3):257-273
The single ion activity coefficients of hydrogen and chloride ions in aqueous HCl solutions have been estimated at 25°C at concentrations up to 1 mol-kg–1, using potentiometric measurements with ion-selective electrodes and appropriate calibration procedures. Two methods are described for an internal calibration of the electrodes in the extended Debye–Hückel concentration range. The results are compared to the conventional pH calibration with external buffer solutions. Since the latter calibration method does not account for the liquid junction potential E
J which arises at the reference electrode, the resulting activity coefficients are quite different in HCl solutions of higher concentration. These differences between internal and external calibration decrease significantly, when a correction for E
J is introduced into the conventional pH calibration. Hence, in solutions of higher ionic strength the accuracy of the conventional pH electrode calibration using buffer solutions is very limited, when exact H+ activities are required. The consistency of the results indicates that the liquid junction potentials in the examined systems calculated by the Henderson/Bates approximation are of reasonable precision. 相似文献
107.
The temperature dependence of pressure broadening of 134 rovibrational transitions of several branches in the ν4 and 2ν2 bands of ammonia perturbed by H2 and N2 has been measured using a high-resolution Fourier transform spectrometer. The temperature range covered during the experiments was between 235 and 296 K. The pressure-broadening linewidths were obtained using the method of multipressure fitting to the measured shapes of the lines. These broadenings were also calculated using a semiclassical model leading to a reasonable agreement with the observations and reproduces well the strong systematic experimental J and K quantum number dependencies. The retrieved values of the linewidths, along with those previously determined from the spectra at room temperature, were used to derive the temperature dependence of both H2 and N2 broadening of NH3 lines. The broadening coefficients were shown to fit closely the well-known exponential law. For both experimental and theoretical results, the temperature exponent n has been obtained. Careful inspection of the experimental values shows that, contrary to the linewidths, the coefficient n is nearly K independent within each J multiplet. Also for a given J it does not seem to exhibit any noticeable variation with the type of rotational transition. On the other hand, the calculated n values exhibit a strong J and K systematic dependencies. n increases with K for a given J, decreases with J for a given K and are independent of the type of rotational transition. 相似文献
108.
本文在Q-正则Loewner空间中用环模不等式刻划了拟对称映射.另外,在 Q-维Ahlfors-David正则空间中建立了拟对称映射作用下的Grotzsch-Teichmuller型 模不等式,它是通过伸张系数的积分平均来表示. 相似文献
109.
110.