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11.
高效液相色谱及联用技术在砷形态分析中的应用 总被引:4,自引:0,他引:4
砷与人类的生活息息相关,是环境中存在的一种极为重要的非金属元素。由于不同形态的砷其毒性各不同,因此无论对环境样品、食品、药物还是对人体的体液进行砷的形态分析都是至关重要的。高效液相色谱因具有较高的分离能力而被广泛地应用于砷形态的分离研究中。随着对分析灵敏度与准确度要求的不断提高,作为砷形态分析的检测器不断发展,不同的联用技术也日益完善。其中,电感耦合等离子体质谱法以其极高的灵敏度、多元素同时检测能力、极宽的动态范围以及同位素比检测能力而被成功地作为高效液相色谱的检测器,广泛地应用于砷的形态分析中。 相似文献
12.
Even though various wireless Net-work Access Technologies (NATs) with dif-ferent specifications and applications have been developed in the recent years, no single wireless technology alone can satisfy the any-time, anywhere, and any service wire-less-access needs of mobile users. A real seamless wireless mobile environment is only realized by considering vertical and horizontal handoffs together. One of the major design issues in heterogeneous wireless networks is the support of Vertical Handoff (VHO). VHO occurs when a multi-interface enabled mobile terminal changes its Point of Attachment (PoA) from one type of wireless access technology to another, while maintaining an active session. In this paper we present a novel multi-criteria VHO algorithm, which chooses the target NAT based on several factors such as user preferences, system parameters, and traffic-types with varying Quality of Service (QoS) requirements. Two modules i.e., VHO Necessity Estimation (VHONE) module and target NAT selection module, are designed. Both modules utilize several “weighted” users’ and system’s parameters. To improve the robustness of the proposed algorithm, the weighting system is designed based on the concept of fuzzy linguistic variables. 相似文献
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The analysis of an anisotropic plate Faraday rotator coated with multilayer dielectric plates is presented by means of the matrix methods in conjunction with Fourier transformation technigues. It provides a closed-form representation of the electromagnetic field over the whole multilayer regions. The treatment does not limit the direction of the biased magnetic field and the numbers of the coated dielectric plates. Numerical results are presented and compared with that calculated with the method in ref.[1], and full-waveguide-band bandwidth for 47.5°±1.5° rotation angle is obtained for transmission type rotator in W band. Calculation for reflection type rotator is also presented and compared with the experiments. 相似文献
15.
软计算技术越来越广泛地应用于解决各领域的实际问题。文章将多种不同软计算技术的集成应用于入侵检测。由于网络攻击事件的日益增多,建立有效的入侵检测系统对保护信息安全是非常必要的,但要实现这一点仍面临巨大的挑战。分析了两种类型的软计算技术:人工神经网络和支持向量机。实验证明这两种方法的集成在入侵检测的检测精度方面要优于单一方法。 相似文献
16.
BOC调制是一种新的调制方式,能够实现频谱分离并能够充分利用整个频带,比传统的BPSK调制拥有更好的自相关特性,以至于能够改善定位精度。由于BOC调制信号在载波频率点处有较低的功率谱密度,因而,在未来的卫星导航系统中使用BOC调制信号将能够减少信号间的干扰。本文详细地分析了BOC调制信号的特点,通过对功率谱密度函数、自相关函数、Gabor带宽和码跟踪精度等参数的分析和仿真,验证了BOC调制信号在相关特性、抗干扰能力和码跟踪精度方面的优越性。并针对BOC调制信号自相关峰的多峰带来的跟踪不确定性会使捕获复杂度增加和带来跟踪误差的问题,本文介绍了几种BOC调制信号的接收技术,可为我国自主研发的导航系统的信号体制设计和系统优化提供技术支撑。 相似文献
17.
We show that the blockage in transmission of a screen with a periodic microstructure integrated over all wavelengths is bounded by the static polarizability per unit area of the screen. Physical bounds on the co-polarized transmission coefficient over a wavelength interval are presented using only information from the zero-frequency properties of the microstructure. The theoretical results are compared to and verified by measurements on a screen composed of a large number of split ring resonators printed on a dielectric substrate.https://doi.org/10.1209/0295-5075/87/34002 相似文献
18.
《Europhysics letters》2010,92(3)
The performance of a low-pass screen designed to block electromagnetic waves in a stop band is shown to have an upper bound defined by the static electric and magnetic polarizability per unit area of the screen. The bound is easy to calculate for all angles of incidence and polarizations, and applies regardless of how complicated the screen's microstructure is. For a homogeneous dielectric sheet the bound for TM polarization is more restrictive than the bound for TE, but this is not generally true for a screen with microstructure. The results are verified by measurements and simulations of oblique transmission through an array of split ring resonators, printed on a dielectric substrate.https://doi.org/10.1209/0295-5075/92/34009 相似文献
19.
Chung-Shang Shao Richard Byrd Elizabeth Eskow Robert B. Schnabel 《Journal of Global Optimization》2000,16(2):167-196
Strategies involving smoothing of the objective function have been used to help solve difficult global optimization problems arising in molecular chemistry. This paper proposes a new smoothing approach and examines some basic issues in smoothing for molecular configuration problems. We first propose a new, simple algebraic way of smoothing the Lennard-Jones energy function, which is an important component of the energy in many molecular models. This simple smoothing technique is shown to have close similarities to previously-proposed, spatial averaging smoothing techniques. We also present some experimental studies of the behavior of local and global minimizers under smoothing of the potential energy in Lennard-Jones problems. An examination of minimizer trajectories from these smoothed problems shows significant limitations in the use of smoothing to directly solve global optimization problems. 相似文献
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