Photoinduced phase transition accompanied with the changes in magnetic properties

Recently, many studies have been started in search for materials which show a photoinduced phase transition (PIPT). In this work, we review two systems as typical examples of PIPT accompanied with changes in magnetic characteristics; (1) organo-metal complex [Fe(2-pic)₃]Cl₂ EtOH (2-pic = 2-amino-methyl-pyridine) and (2) III-V based magnetic semiconductors (In_1-x , Mn _x )As. In the former case, we show several nonlinear characteristics in dynamical process of photoinduced spin state transition from low-spin to high-spin states. In the latter one, photocarrier-induced ferromagnetic order has been observed by both magnetic and transport measurements.     

HSDPA实时业务调度算法在中断率(掉话率)方面的仿真分析

文章主要研究的是在HSDPA无线通信系统中,支持实时业务的分组调度算法。首先对HSDPA通信系统的分组调度算法M-LWDF和EXP算法进行了分类讨论,并通过视频流业务参考模型对M_LWDF和EXP算法在中断率(掉话率)方面进行仿真,来研究它们的性能。仿真结果表明,在条件相同的情况下,M_LWDF算法中断率略小于EXP算法中断率。     

Ultraviolet light absorber with low surface energy: synthesis and characterization

Novel fluorine-containing ultraviolet absorbers (FBPs) with low surface energy were successfully synthesized based on 2,4-dihydroxy benzophenone (BP-1), and their structures were characterized by ¹H NMR, ¹³C NMR, FTIR, and HRMS. UV absorption of FBPs was studied in 10⁻⁴ M dichloromethane (CH₂Cl₂), which demonstrated the superior UV absorption capability of FBPs (ca. ?=1.7×10⁴ to 2.2×10⁴ at λ_max) over the matrix (?=1.7×10⁴ at λ_max). Quantum chemistry calculation was performed to investigate the stable structure and UV electronic absorption bands of FBPs. The surface chemistry information of high-chlorinated polyethylene (HCPE) coating films embedded with ultraviolet absorbers (UVAs) was given by X-ray photoelectron spectroscopy (XPS) and contact angle measurement. The results show that the surface enrichment capability of FBPs is remarkably better than traditional UVAs (including BP-1, BP-3, BP-12) because of the low surface energy properties of FBPs.     

三氟乙酸酐(TFAA)促进的Stieglitz重排反应制备苯胺

本工作使用简单易得的三氟乙酸酐作为活化试剂,拓展了Stieglitz重排反应的底物适用范围,发展了一种通过C—C键断裂由苯乙基羟胺制备芳基伯胺的方法.该反应条件较为温和且对官能团具有较好的兼容性.机理研究表明,反应经历了活性三氟乙酸酯中间体的原位生成,并通过C—C和N—O键的断裂实现芳基迁移的过程.     

公务员招聘问题的研究

建立了不符合度、失望度、不满意度等概念,将公务员招聘问题转化为求不满意度总和最小的0—1规划模型,很好地解决了在不考虑和考虑应聘人员意愿的两种情形下公务员招聘的问题.充分体现了录取的公平公正性和对人才的充分利用.     

TD-SCDMA无线网络规划中应注意的一些问题

TD-SCDMA系统由于采用了时分码分的多址方式、智能天线、联合检测、接力切换、动态信道分配等一系列新型关键技术和无线资源算法,为网络规划带来了很多新特点.本文就在TD网络规划中遇到的一些问题所形成的几个观点、看法做一介绍,包括覆盖能力、容量受限因素以及可变切换点等相关内容.     

HSDPA与WiMAX的技术综合比较

本文首先介绍了HSDPA和WiMAX两种技术的特点,然后对其进行了比较,前者技术较为成熟,也容易实现,设备成本相对低廉;后者在数据传输速率和覆盖范围方面具有优势,但升级的成本较高.     

TD-SCDMA系统中多载波HSDPA结构和流控算法分析

本文在TD-SCDMA系统的N 频点小区技术的基础上,结合HSDPA 的基本技术,详细分析了多载波HSDPA技术方案,并结合实际的产品开发需求给出了相应的软件模块和结构。在此基础上,进一步分析了 HSDPA 技术中所要考虑的相关算法。由于 HSDPA 技术使用了 HARQ、16QAM以及自适应调制编码和快速的数据调度等技术,且在Node B侧增加了一个MAC-hs实体专门用来完成HSDPA的相关技术,其中用户数据快速调度算法和Iub接口的数据速率的控制算法是整个HSDPA的难点所在。本文将从产品角度对Iub接口的控制算法,即Iub接口的流控算法进行分析,给出流控算法的参考设计方案。     

加氢脱氮催化研究的新进展

化石燃料的加氢脱氮有利于改善油品质量及其稳定性,同时避免燃烧时NO_x的排放。本文介绍了不同化石燃料中有机氮化物的含量及类型,对不同加氢脱氮催化剂及其催化活性位的本质进行了探讨,同时论述了C—N键断裂机理及燃料中主要有机氮化物的HDN反应网络。着重概述了传统金属硫化物催化剂的改性方法,新型的金属碳化物、金属氮化物和金属磷化物催化剂的研究现状。