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71.
Dr. Xiaolong Zu Yuan Zhao Dr. Xiaodong Li Runhua Chen Weiwei Shao Li Li Panzhe Qiao Prof. Wensheng Yan Prof. Yang Pan Qian Xu Prof. Junfa Zhu Prof. Yongfu Sun Prof. Yi Xie 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(1):e202215247
Herein, we first design a model of reversible redox-switching metal–organic framework single-unit-cell sheets, where the abundant metal single sites benefit for highly selective CO2 reduction, while the reversible redox-switching metal sites can effectively activate CO2 molecules. Taking the synthetic Cu-MOF single-unit-cell sheets as an example, synchrotron-radiation quasi in situ X-ray photoelectron spectra unravel the reversible switching CuII/CuI single sites initially accept photoexcited electrons and then donate them to CO2 molecules, which favors the rate-liming activation into CO2δ−, verified by in situ FTIR spectra and Gibbs free energy calculations. As an outcome, Cu-MOF single-unit-cell sheets achieve near 100 % selectivity for CO2 photoreduction to CO with a high rate of 860 μmol g−1 h−1 without any sacrifice reagent or photosensitizer, where both the activity and selectivity outperform previously reported photocatalysts evaluated under similar conditions. 相似文献
72.
《Current Applied Physics》2018,18(1):127-132
By utilizing a near infrared laser diode as an excitation light source, we demonstrated a photothermally controlled current gating of 50 mA in a two-terminal planar device based on a vanadium dioxide (VO2) thin film grown by a pulsed laser deposition method. The photothermally controlled on/off triggering of the device current was accomplished by controlling the output power of the laser beam that illuminated the VO2 film. The transient responses of photothermally triggered currents were analyzed when periodical laser pulses from the laser diode stimulated the VO2 device at a variety of pulse widths and repetition rates. A switching contrast between off-state and on-state currents was evaluated as ∼11905, and average rising and falling times were measured as ∼45 and ∼19 ms, respectively. 相似文献
73.
Simultaneous two‐state lasing is a unique property of semiconductor quantum‐dot (QD) lasers. This not only changes steady‐state characteristics of the laser device but also its dynamic response to perturbations. In this paper we investigate the dynamic stability of QD lasers in an external optical injection setup. Compared to conventional single‐state laser devices, we find a strong suppression of dynamical instabilities in two‐state lasers. Furthermore, depending on the frequency and intensity of the injected light, pronounced areas of bistability between both lasing frequencies appear, which can be employed for fast optical switching in all‐optical photonic computing applications. These results emphasize the suitability of QD semiconductor lasers in future integrated optoelectronic systems where a high level of stability is required. 相似文献
74.
《Stochastic Processes and their Applications》2020,130(5):2693-2736
We give necessary and sufficient criteria for the Feller–Dynkin property of solutions to martingale problems in terms of Lyapunov functions. Moreover, we derive a Khasminskii-type integral test for the Feller–Dynkin property of multidimensional diffusions with random switching. For one dimensional switching diffusions with state-independent switching, we provide an integral-test for the Feller–Dynkin property. 相似文献
75.
We investigate a model consisting of a predator population and both susceptible and infected prey populations. The predator can feed on either prey species but instead of choosing individuals at random the predator feeds preferentially on the most abundant prey species. More specifically we assume that the likelihood of a predator catching a susceptible prey or an infected prey is proportional to the numbers of these two different types of prey species. This phenomenon, involving changing preference from susceptible to infected prey, is called switching. Mukhopadhyay studied a switching model and proposed that the interaction of predators with infected prey is beneficial for the growth of the predator. In this model, we assume that the predator will eventually die as a result of eating infected prey. We find a threshold parameter and showed that the disease will be eradicated from the system if . 相似文献
76.
Detailed model, analysis and design technique are presented for simulating a high-speed polymer Mach-Zehnder interferometer (MZI) electro-optic switch with push-pull dual driving electrodes and rib waveguides. The novel formulas of the time-domain response are derived. Thorough optimization and simulation for the designed device are performed. The total length of the basic function unit of the switch is about 5049 μm, the push-pull switching voltage is 2.23 V, the switching time is 18.1 ps, and the insertion loss and crosstalk are less than 2.64 and −30 dB, respectively, within the range of the operation wavelength from 1534 to 1566 nm. These results are in good agreement with those obtained from the beam propagation method (BPM). 相似文献
77.
This paper presents results computed using a meshless method in a point collocation formulation to investigate the effects of temperature and frequency on the magnetization switching mode in the circular amorphous magneto-impedance sensor (element). Specifically, the solutions characterizing the MI effect are solved from a set of coupled nonlinear equations consisting of the Maxwell’s equations, the Landau-Lifshitz-Gilbert equation, and the thermal diffusion equation. This coupled nonlinear space-time model predicts the formation and propagation of dynamic domain walls in switching and it is shown how they contribute to experimentally observed temperature and frequency effects. Computed results (that agree well with reported experimental data) suggest radial domain walls may play a larger role in the MI effect than originally believed even for the realistic conditions considered here at 1 MHz or more. 相似文献
78.
K. -M. Haendel U. Denker O. G. Schmidt A. G. M. Jansen R. J. Haug 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):487
We use magneto-transport spectroscopy to study a dramatic instability between a low and high conductivity mode in Si/SiGe-based resonant tunneling diodes with an embedded layer of self-assembled Ge hut cluster quantum dots in the Si barrier. In the low current regime a simple activation-type behavior with an astonishingly low activation energy in the order of 0.1 meV is determined. In the high current regime a region of negative differential conduction can be observed. We discuss the influence of different layer structures and magnetic fields. 相似文献
79.
The synthesized macrocycle L is the novel fluorescent receptor having the switching ability by the external stimuli as well as having the recognizing ability of various metal ions. In particular, this macrocycle L shows the possibility of the selectivity of metal ions even in the same charge ions of a different metal, and the values of association constant (M−1) of that for metal ions are consistent with the tendency of increasing charge number of metal ion. In addition, the values of quantum yield (ΦF) of metal complexes of macrocycle L were ranged from 0.021 to 0.111 enough to recognize the metal ions in macrocycle L. We know from the fluorescent pH titration of macrocycle L by acid/base that the change of fluorescence intersects at about pH=5. 相似文献
80.
In this paper, the various Optical Burst Switching (OBS) reservation schemes have been examined in order to reduce data loss caused by either channel scheduling or resources. A novel multi-service OBS edge node with synchronized bandwidth reservation mechanism (SRM) has been proposed, which enables high-speed network transport nodes to dynamically reserve bandwidth needed for active data burst flows. The performance of the proposed mechanism is evaluated by means of NS-2 simulation. The results show that the packet delay is kept within the constraint for each traffic flow and the performance metrics such as burst loss rate, throughput and fairness are remarkably improved. 相似文献