On the separation of a suspension in a tube centrifuge: critical comments on theoretical models and experimental verifications

Summary We consider the batch centrifugal separation of a suspension of heavy particles in a cylindrical tube which rotates about an axis perpendicular to the axis of the tube. The theoretical analysis by means of a kinematic approximation covers two models: (1) the one-dimensional, which assumes that the particles settle along lines parallel to the sidewalls of the tube and sediment on the outer wall, and (2) the two-dimensional, which assumes that the particles settle along the centrifugal-field lines and sediment on both sidewalls and outer wall. A comparison shows that both models produce similarly simple formulas for the motion of the interface and the volume fraction as functions of time. However, the two-dimensional model is recommended for use because its results and insights are more reliable from both mathematical and physical considerations, and provide a more acceptable interpretation to recent experimental data, [5]. The author wishes to thank Prof. W. Schneider for stimulating discussions on the subject. The research was partially supported by the the Technion Fund V.P.R Fund – New York Metropolitan Research Fund.     

A discrete 3D model for bridge aerodynamics and aeroelasticity: nonlinearities and linearizations

A framework for the numerical analysis of bridges under wind excitation is outlined. It is based on structural finite element scheme and cross-sectional wind load models. Two aspects are investigated: (1) how considering the mean steady configuration in the aerodynamic stability calculation; and (2) the effects of load nonlinearities on structural response. A quasi-steady load model is adopted, which is able to deal with the considered problems by using experimental data easily available in the practice. By means of numerical examples, it is pointed out (1) that both the modifications in structural tangential stiffness and in the aerodynamic coefficients due to the mean steady deformation may affect the aeroelastic stability threshold and (2) that load linearization may produce an underestimation of the structural response.     

Model of the UIC link suspension for freight wagons

Summary The paper presents a model of the UIC link suspension for freight wagons with emphasis on its longitudinal and lateral characteristics, which influence the lateral dynamics of the vehicle. The functioning of the suspension in the horizontal plane is realised by a number of technical (pivoted) pendulums composing linkages. The main feature of the joints of linkages is internal rolling/sliding in the presence of dry friction. The dissipation of energy by dry friction in the joints is the only source of damping, which influences the lateral dynamics of the vehicle. After detailed modelling of the technical pendulum, phenomenological models of the suspension are built, which reproduce the characteristics of the suspension using simple elements. A three-parameter model with one dry-friction slider and two linear springs reproduces the lateral characteristic of the suspension. A nine-parameter model with four dry-friction sliders and five springs reproduces the longitudinal characteristic. The models, using a method of non-smooth mechanics, may be directly implemented to vehicle/track dynamic simulations.Professor Hans True of TU Denmark for stressing the importance of the problem of the UIC suspension modelling for successful upgrading of freight wagons.     

Rheology of carbon black suspensions. III. Sol-gel transition system

Linear viscoelastic properties of carbon black (CB) suspensions with various CB volume fractions () in a rosin-modified phenol resin type varnish (Varnish-1) were investigated at various temperatures (T). The CB/Varnish-1 suspensions exhibited a sol-gel transition on an increase in , and the _gel value at the gelation point decreased with increasing T. This T dependence of _gel, being opposite to the dependence seen for usual gelling systems, can be related to a phenol resin type polymeric component included in the Varnish-1. At low T, this polymeric component appeared to be rather well solvated in the Varnish-1 thereby allowing the gelation due to bare attraction between the CB particles at large . In contrast, at high T, the polymeric component appeared to have been less solvated, as evidence from a moderate failure of the time-temperature superposition of pure Varnish-1 and a decrease of its elasticity (in a shifted frequency scale) with increasing T. This less solvated polymeric component would have been adsorbed on the CB particles, thereby allowing the agglomeration of the particles at small _gel at high T.     

Elastic modulus and yield stress of suspensions

A recent technique, developed to measure yield stress has here also been used to determine the elastic modulus of a suspension. Temperature effects have been measured.     

Non-linear vibrations of suspension bridges with external excitation

Non-linear coupled vertical and torsional vibrations of suspension bridges are investigated. Method of Multiple Scales, a perturbation technique, is applied to the equations to find approximate analytical solutions. The equations are not discretized as usually done, rather the perturbation method is applied directly to the partial differential equations. Free and forced vibrations with damping are investigated in detail. Amplitude and phase modulation equations are obtained. The dependence of non-linear frequency on amplitude is described. Steady-state solutions are analyzed. Frequency-response equation is derived and the jump phenomenon in the frequency-response curves resulting from non-linearity is considered. Effects of initial amplitude and phase values, amplitude of excitation, and damping coefficient on modal amplitudes, are determined.     

Field-induced gelation, yield stress, and fragility of an electro-rheological suspension

 Electro-rheological suspensions (ERS) are known to undergo liquid-to-solid transition under the application of an electric field. Long-range interaction between neighboring particles results in sample-spanning particulate structures which behave as soft solids. Here, we studied the rheological expression of this field-induced transition which has many similarities with chemical gelation. This similarity shows in mechanical spectroscopy on a suspension of monodisperse silica in PDMS as model ERS. Upon application of the electric field, dynamic moduli G′, G′′ grow by orders of magnitude and evolve in a pattern which is otherwise typical for gelation of network polymers (random chemical or physical gelation). At the gel point, the slow dynamics is governed by power-law relaxation behavior (frequency-independent tan δ). A low field strength is sufficient to reach the gel point and, correspondingly, the percolating particle structure at the gel point is still very fragile. It can be broken by the imposition of low stress. For inducing a finite yield stress, the field strength needs to be increased further until the long-range electrostatic interaction generates string-like particle alignments which become clearly visible under the optical microscope. The onset of fragile connectivity was defined experimentally by the tan δ method. The ERS was probed dynamically at low frequencies where the transition is most pronounced, and also in steady shear where the rate of structure formation equals the rate of internal breaking. Received: 1 May 2001 Accepted: 11 August 2001     

Nonlinear rheological behavior of a concentrated spherical silica suspension

Linear and nonlinear viscoelastic properties were examined for a 50 wt% suspension of spherical silica particles (with radius of 40 nm) in a viscous medium, 2.27/1 (wt/wt) ethylene glycol/glycerol mixture. The effective volume fraction of the particles evaluated from zero-shear viscosities of the suspension and medium was 0.53. At a quiescent state the particles had a liquid-like, isotropic spatial distribution in the medium. Dynamic moduli G^* obtained for small oscillatory strain (in the linear viscoelastic regime) exhibited a relaxation process that reflected the equilibrium Brownian motion of those particles. In the stress relaxation experiments, the linear relaxation modulus G(t) was obtained for small step strain (0.2) while the nonlinear relaxation modulus G(t, ) characterizing strong stress damping behavior was obtained for large (>0.2). G(t, ) obeyed the time-strain separability at long time scales, and the damping function h() (–G(t, )/G(t)) was determined. Steady flow measurements revealed shear-thinning of the steady state viscosity () for small shear rates (< ^–1; = linear viscoelastic relaxation time) and shear-thickening for larger (>^–1). Corresponding changes were observed also for the viscosity growth and decay functions on start up and cessation of flow, + (t, ) and _– (t, ). In the shear-thinning regime, the and dependence of ₊(t,) and _–(t,) as well as the dependence of () were well described by a BKZ-type constitutive equation using the G(t) and h() data. On the other hand, this equation completely failed in describing the behavior in the shear-thickening regime. These applicabilities of the BKZ equation were utilized to discuss the shearthinning and shear-thickening mechanisms in relation to shear effects on the structure (spatial distribution) and motion of the suspended particles.Dedicated to the memory of Prof. Dale S. Parson     

Rheological behavior of concentrated suspensions as affected by the dynamics of the mixing process

The rheological characterizations of concentrated suspensions are generally carried out assuming “well-mixed” suspensions. However, the variation of the concentration distributions of the ingredients of the formulation, i.e., the “goodness of mixing”, the size and shape distributions of the particle clusters and the rheological behavior of the suspension all depend on the thermo-mechanical history that the suspension is exposed to during the mixing process. Here, various experimental tools are used for the characterization of the degree of mixedness (concentration distributions) of various ingredients along with the characterization of rheological material functions, wall slip behavior and the maximum packing fraction of a graphite/elastomer suspension. The degree of mixedness values of the ingredients of the suspensions processed using batch and continuous processes and under differing operating conditions were characterized quantitatively using wide-angle X-ray diffraction and thermo gravimetric analysis and were elucidated under the light of the electrical properties of the suspension as affected by the mixing process. Upon achieving better homogeneity of the graphite particles and the binder and decreases in the size and breadth of the size distributions of particle clusters (as inferred from electrical measurements and maximum packing fraction values), the elasticity (storage modulus) and the shear viscosity (magnitude of the complex viscosity from small-amplitude oscillatory shear and shear viscosity from steady torsional and capillary rheometry) of the suspension decreased significantly and the wall slip velocity values increased. These findings demonstrate the intimate relationships that exist between the rheological behavior of concentrated suspensions and the thermo-mechanical history that they are exposed to during the processing stage and suggest that the preparation conditions for suspensions should be carefully selected and well documented to achieve reproducible characterization of rheological material functions.     

Generalized nonlinear models of suspension bridges

This paper generalizes some results established in [J. Malík, Nonlinear models of suspension bridges, J. Math. Anal. Appl., in press]. The geometric nonlinearity connected with the torsion of a road bed is included in the generalized model. The basic variational equations are derived from the principle of minimum energy. The existence of a solution to the generalized problem is proved. The existence is based on the Brouwer fixed-point theorem.