全文获取类型
收费全文 | 73329篇 |
免费 | 5496篇 |
国内免费 | 5449篇 |
专业分类
化学 | 25201篇 |
晶体学 | 502篇 |
力学 | 4960篇 |
综合类 | 538篇 |
数学 | 10887篇 |
物理学 | 24481篇 |
无线电 | 17705篇 |
出版年
2024年 | 219篇 |
2023年 | 978篇 |
2022年 | 1604篇 |
2021年 | 1856篇 |
2020年 | 1947篇 |
2019年 | 1675篇 |
2018年 | 1472篇 |
2017年 | 1900篇 |
2016年 | 2318篇 |
2015年 | 1989篇 |
2014年 | 3183篇 |
2013年 | 4537篇 |
2012年 | 3459篇 |
2011年 | 3940篇 |
2010年 | 3082篇 |
2009年 | 4308篇 |
2008年 | 4470篇 |
2007年 | 5112篇 |
2006年 | 4451篇 |
2005年 | 3403篇 |
2004年 | 2954篇 |
2003年 | 3115篇 |
2002年 | 3269篇 |
2001年 | 2571篇 |
2000年 | 2343篇 |
1999年 | 1978篇 |
1998年 | 1897篇 |
1997年 | 1197篇 |
1996年 | 1154篇 |
1995年 | 994篇 |
1994年 | 1004篇 |
1993年 | 762篇 |
1992年 | 808篇 |
1991年 | 567篇 |
1990年 | 547篇 |
1989年 | 404篇 |
1988年 | 339篇 |
1987年 | 301篇 |
1986年 | 267篇 |
1985年 | 251篇 |
1984年 | 246篇 |
1983年 | 156篇 |
1982年 | 213篇 |
1981年 | 195篇 |
1980年 | 133篇 |
1979年 | 157篇 |
1978年 | 132篇 |
1977年 | 121篇 |
1976年 | 79篇 |
1973年 | 63篇 |
排序方式: 共有10000条查询结果,搜索用时 10 毫秒
31.
GaAs器件工艺中等离子刻蚀及计算机辅助监控技术研究 总被引:2,自引:1,他引:1
陈正明 《固体电子学研究与进展》1994,14(2):182-185
用N2气和NF3反应气体,在较低的刻蚀功率下实现了用薄正性光刻胶AZ1518作掩模,均匀、快速刻蚀SiO2,SiON,Si3N4,WN,W等材料的等离子刻蚀技术。利用到蚀过程中射频参数的变化和计算机技术,将射频参数的变化在计算机屏幕上实时显示,实现了计算机辅助监控和终点检测技术。 相似文献
32.
本文论述了寄生电容不敏感型开关电容四象限模拟乘法器的设计,并提出了一种新型的电路结构,分析了它的性能,以及元器件的非理想特性对其性能的影响和采取的补偿方法。 相似文献
33.
本文详细系统地介绍了我国有线是视发展历史和现状,及其经营和管理方法。重点介绍了北美的CATV技术发展动向。最后,指出我国CATV事业发展中的应用重视的问题。 相似文献
34.
微机在应变测量中的应用,采用上位机和下位机组合方式.上位机为一台IBM-PC/XT微机,用于对数据进行后处理.下位机以Z80-CPU为控制器,由传感器、转换器、接口及外设等组成数据采集器,实施对应变、压力和位移等参数的采集、显示和打印(即数据的预处理).上位机和下位机之间的数据传输,采用串行的方式,通过RS-232接口完成.本文主要以应变的采集处理为例,介绍系统功能、硬件配置及软件设计. 相似文献
35.
The acute influences of arsenic compounds on the metabolism of porphyrins and heme in various organs of rats after oral or intratracheal administration of disodium arsenate (Na2HAsO4) and gallium arsenide (GaAs) were examined and compared. For the oral administration experiments, 21 or 84 mg of Na2HAsO4, or 2 or 4 g of GaAs, per cm3 saline per kg body weight of each animal was administered to Jcl: Wistar male rats and the organs were removed after exsanguination from the vein of the right axilla under anesthesia with ether, 16 h after administration. In the case of intratracheal administration, rats given 8.2 or 16.4 mg of Na2HAsO4, or 0.2 or 0.4 g GaAs per cm3 saline per kg body weight were examined under the same experimental conditions as for the administration route. Increase in the body weight of rats was suppressed after intratracheal administration of the two arsenic compounds. In these rats the hematocrit value increased significantly. These changes were not shown by the orally administered rats. Elevation in δ-aminolevulinate synthase (ALA-S, EC 2.3.1.37) activity in erythroblasts by Na2HAsO4 was much higher after intratracheal administration than after oral administration. Suppression in the activities of δ-aminolevulinate dehydratase (ALA-D, EC 4.2.1.24) and porphobilinogen deaminase (PBG-D, EC 4.3.1.8) in peripheral erythrocytes by Na2HAsO4 and GaAs were stronger by intratracheal administration than by the oral route. Influences of GaAs on the activity of PBG-D in rat liver were shown to be more effective by oral administration than by the intratracheal route. Oral administration of Na2HAsO4 and GaAs had a stronger suppression effect on the activities of ALA-D and PBG-D in rat kidney. It seems from these results that the different extents of the influence of arsenic compounds might depend on the routes of intake. 相似文献
36.
本文用不热形变栅状直丝化学气相沉积(CVD)法生长金刚石膜,在Si及WC-Co硬质合金衬底上金刚石膜晶面显露规律随衬底温度和甲烷浓度而异,经适当表面处理及选择合适的工艺条件,当生长初期衬底上就呈现出良好晶形的沉积膜,衬底与膜之间的粘结力能得到提高。Raman谱分析表明此膜仅具有特征金刚石1332cm ̄(-1)峰,通过SEM观察揭示出盒刚石膜可在表面、侧面及棱上生长,并与衬底有良好的联结。 相似文献
37.
R. Souzy B. Ameduri B. Boutevin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(20):5077-5097
The radical co‐ and terpolymerization of 4‐[(α,β,β‐trifluorovinyl)oxy]bromo benzene (TFVOBB) with 1,1‐difluoroethylene (or vinylidene fluoride, VDF, or VF2), hexafluoropropene (HFP), perfluoromethyl vinyl ether (PMVE), and chlorotrifluroroethylene (CTFE) is presented. Although TFVOBB could be thermocyclodimerized, it could not homopolymerize under radical initiation. TFVOBB could be copolymerized in solution under a radical initiator with VDF or CTFE comonomers, while its copolymerization with HFP or PMVE were unsuccessful. The terpolymerization of TFVOBB with VDF and HFP, or VDF and PMVE, or VDF and CTFE also led to original fluorinated terpolymers bearing bromoaromatic side‐groups. The conditions of co‐ and terpolymerization were optimized in terms of the nature of the radical initiators, and of the nature of solvents (fluorinated or nonhalogenated). Various monomer concentrations in the co‐ and terpolymers were assessed by 19F and 1H‐NMR spectroscopy. The thermal and physico chemical properties were also studied. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5077–5097, 2004 相似文献
38.
The self-diffusion of benzene, toluene, and ethylbenzene in polystyrene have been analyzed using the Vrentas/Duda free-volume diffusion model. Diffusion coefficient predictions suggest an exponential concentration dependence of the activation energy required to overcome attractive forces, E. Without the use of any diffusion data approximating E as zero over the entire concentration range yields self-diffusion coefficient predictions which are in good agreement with experimental data. © 1992 John Wiley & Sons, Inc. 相似文献
39.
From flash photolysis data of benzil and 2,2′-dichlorobenzil, the role of conformeric triplets in the formation of hydrogen
adduct radicals has been discussed. The planar relaxed triplet absorbing at 470 nm is less efficient in forming a hydrogen
adduct radical as compared to its puckered conformeric partner. Among the hydrogen donors, triethyl amine and isopropanol,
the former is more efficient in converting puckered triplets and less efficient in the case of planar conformers. Absorptions
of radicals and radical anions of 2,2′-dichlorobenzil appear at 355 nm and 460 nm respectively. These are blue-shifted as
compared to those of the parent compound benzil appearing at 370 nm and 540 nm, respectively. This blue-shift has been discussed
in terms of steric hindrance due to ortho-substitution. 相似文献
40.
Utilizing forward recoil spectrometry (FRES), we have determined the segregation isotherm which describes the interfacial excess zi* of diblock copolymers of poly (d8-styrene-b-2-vinylpyridine) (dPS-PVP) at the interface between the homopolymers PS and PVP as a function of ?∞, the volume fraction of diblock copolymer remaining in the host homopolymer. All the samples were analyzed after annealing at temperatures and times sufficient to achieve equilibrium segregation. The effect of the degree of polymerization of both the diblock copolymers and the host homopolymers on the segregation isotherm is investigated. When the degree of polymerization of the homopolymer is much larger than that of the diblock copolymer, the normalized interfacial excess (zi*/Rg), where Rg is the radius of gyration of an isolated block copolymer chain, is a universal function of that portion of the block copolymer chemical potential due to chain stretching. The existence of such a universal function is predicted by theory and its form is in good agreement with self-consistent mean field calculations. Using these results, one can predict important aspects of the block copolymer segregation (e.g., the saturation interfacial excess) without recourse to the time-consuming numerical calculations. © 1994 John Wiley & Sons, Inc. 相似文献