Synthesis of functional polymers—Vinylidene fluoride based fluorinated copolymers and terpolymers bearing bromoaromatic side‐group

The radical co‐ and terpolymerization of 4‐[(α,β,β‐trifluorovinyl)oxy]bromo benzene (TFVOBB) with 1,1‐difluoroethylene (or vinylidene fluoride, VDF, or VF₂), hexafluoropropene (HFP), perfluoromethyl vinyl ether (PMVE), and chlorotrifluroroethylene (CTFE) is presented. Although TFVOBB could be thermocyclodimerized, it could not homopolymerize under radical initiation. TFVOBB could be copolymerized in solution under a radical initiator with VDF or CTFE comonomers, while its copolymerization with HFP or PMVE were unsuccessful. The terpolymerization of TFVOBB with VDF and HFP, or VDF and PMVE, or VDF and CTFE also led to original fluorinated terpolymers bearing bromoaromatic side‐groups. The conditions of co‐ and terpolymerization were optimized in terms of the nature of the radical initiators, and of the nature of solvents (fluorinated or nonhalogenated). Various monomer concentrations in the co‐ and terpolymers were assessed by ¹⁹F and ¹H‐NMR spectroscopy. The thermal and physico chemical properties were also studied. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5077–5097, 2004     

Reversible addition–fragmentation transfer (RAFT) copolymerization of methyl methacrylate and styrene in miniemulsion

In the reversible addition–fragmentation transfer (RAFT) copolymerization of two monomers, even with the simple terminal model, there are two kinds of macroradical and two kinds of polymeric RAFT agent with different R groups. Because the structure of the R group could exert a significant influence on the RAFT process, RAFT copolymerization may behave differently from RAFT homopolymerization. The RAFT copolymerization of methyl methacrylate (MMA) and styrene (St) in miniemulsion was investigated. The performance of the RAFT copolymerization of MMA/St in miniemulsion was found to be dependent on the feed monomer compositions. When St is dominant in the feed monomer composition, RAFT copolymerization is well controlled in the whole range of monomer conversion. However, when MMA is dominant, RAFT copolymerization may be, in some cases, out of control in the late stage of copolymerization, and characterized by a fast increase in the polydispersity index (PDI). The RAFT process was found to have little influence on composition evolution during copolymerization. The synthesis of the well‐defined gradient copolymers and poly[St‐b‐(St‐co‐MMA)] block copolymer by RAFT miniemulsion copolymerization was also demonstrated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 6248–6258, 2004     

Near-field thermoelastic imaging coupled with infrared detection

Near-field thermoelastic imaging is a simple way to investigate the thermal and coupled thermoelastic properties of materials. A few microscopes, deriving from the atomic force microscope, have been used to observe and to quantify the samples observed. But the main problem is the absolute measurement of the temperature, because surface topography and thermal expansion contributions are not easily discernible. In the proposed SThEM (scanning thermoelastic microscope), the tip is excited at the resonance frequency of the cantilever and the sample is periodically heated by the Joule effect. Thus the static contributions (drift, topography) are reduced. Moreover, a radiometric sensor, operating in the far field, has been added in order to quantify the temperature. This multi-acquisition microscope enables one to investigate small objects at the nanoscale with complementary information at the micrometric scale.     

Magnetic pole pinning at rectangular defects on MnAs/GaAs(0 0 1)

Strong magnetic poles at characteristic rectangular defects have been observed using a magnetic force microscope on a MnAs(  1 0 0) thin film with the thickness of 30 nm. The MnAs thin film was epitaxially grown on a GaAs(0 0 1) substrate. The magnetic poles were in one-arranging direction, being independent of the magnetization direction of the film. The poles were pinned at the edges of the rectangular defects until just below the Curie temperature, and formed a stable magnetic-field loop on the MnAs surface. The stability of the magnetic pole pinning shows the distinctive feature of the magnetic domain structure on the surface with a strong anisotropy, which was built in the heterostructure of MnAs and GaAs.     

Synthesis and Crystal Structure of Di-n-butyltin(IV) Complex with 2-Oxo-propionic Acid (4-Pyridinecarbonyl) Hydrazone

Introduction The studies of diorganotin(IV) complexes are of current interest owing to their wide range of applica-tions such as biocides and homogeneous catalysts in industry.1 In recent years there have been more and more reports on the synthesis, antitumour activities and structural elucidation of various diorganotin(IV) deriva-tives of carboxylic acid.2-5 In particular, people take considerable interest in structural studies of diorgano-tin(IV) complexes of carboxylic acid, because there…     

关于RNP和SCS的若干等价条件

使用切片方法，讨论了Banach空间中有界闭凸子集的RNP和SCS的若干等价条件．     

网上协作学习模式研究

主要针对网上协作学习的基本模式、实现方式和存在的问题进行了初步研究。     

Time-Space Label Switching Protocol (TSL-SP)—A New Paradigm of Network Resource Assignment

In this paper we propose a new protocol called time-space label switching protocol (TSL-SP) in optical burst switching (OBS), and define the terms time-space label (TSL) and time-space routing (TSR). An important concept of response time is introduced in the time label mechanism. The TSL-SP is a new technology that can quickly and efficiently forward data with a label on the optical networks. A two-dimension label switched path (TD-LSP) can be set up, that is maintained and deleted by the TSL-SP. For clearly illuminating the operation principles of the TSL-SP, we propose a new approach of orthogonal time-space coordinates in which the vertical coordinate is the space label and the horizontal coordinate is the time label. The proposed TD-LSP can dramatically reduce the routing failure probability and greatly improve the link network efficiency compared with other signaling protocols. Moreover, we define the time-space label control plane that can achieve the higher efficiency. When the TSL-SP is applied to networks, switching performance can be improved by two orders compared to the switching performance with the conventional OBS signaling protocols. The fundamental goal of TSL-SP is to band the signaling and routing functions together closely. Also, the TSL-SP can reduce the complexity of the network, support automatic service offering, and provide traffic engineering.     

光纤喇曼放大器的功率转换效率分析

在定义光纤喇曼放大器(FRA)功率转换效率(PCE)的基础上,考察了不同工作条件下光纤喇曼放大器的功率转换效率,分析PCE与光纤喇曼放大器的输入信号功率、输入泵浦功率和光纤长度的关系,比较了分布式与集总式FRA的功率转换效率,给出提高FRA功率转换效率的途径。     

LXT384接口芯片的几种环回形式

LXT384是一个用于SONET/SDH设备的八进制T1/E1/J1线路接口单元芯片。文中简述了该芯片在实际应用中进行自检的若干种不同的环回形式(包括：模拟环回、数字环回、运程环回等)，直观地指出了各种环回形式的特点和区别。