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21.
从理论上探讨了溶质在柱头产生的自富集作用过程,说明了进样时间及流动相组成对富集效果的影响规律,并以安息香和美芬妥因两种药物为例对理论加以验证.结果表明,较好地控制实验条件,在基本不影响柱效的情况下,可以达到十余倍的自富集效果. 相似文献
22.
Guang-qi Li Xin Sun and Sheng Li State Key Laboratory of Surface Physics Research Center for Theoretical Physics Fudan University Shanghai China National Laboratory of Infrared Physics Shanghai Institute of Technical Physics Shanghai China 《高分子科学》2001,(6):573-578
The transition from the biexciton to the exciton can turn over the direction of the electric dipole of a polymericmolecule. This turning-over action combined with the photoinduced polarization reversion can be used as a switch. Theswitching speed is governed by the relaxation time of the turning-over process, which can be determined by a dynamicalsimulation. 相似文献
23.
Dimitra Papadimitriou Efthymios Liarokapis Wolfgang Richter 《Mikrochimica acta》2001,136(3-4):165-169
Strain effects on semiconductor layers were studied by means of optical spectroscopic techniques with a device developed
especially for the study of layered structures and microstructures. Raman, modulated photoreflectance and reflectance anisotropy
spectroscopy (RAS) were applied. Measurements were performed on elemental semiconductors (Si), semiconductor alloys (Si–Ge)
and III–V semiconductor compounds (GaAs). By application of RAS, strains lower than 10−4 could be resolved, which is at least one order of magnitude lower than those observable with Raman and modulated reflectance
techniques. The RAS spectra of layers strained along either the [010] or [011] direction showed a derivative-like structure
at E1-gap energies, which increased linearly and very quickly with increasing strain. The dependence of this spectral feature on
applied strain was used to evaluate strain-dependent effects. This behaviour strongly suggests that RAS can be applied for
the optical characterisation of strain in semiconductor microstructures and devices, with a higher efficiency and accuracy
than that achieved by previously established optical methods such as Raman and modulation spectroscopy. In addition, the compactness
and ease of operation of the instrumentation of RAS provides considerable potential for in situ monitoring/control of semiconductor fabrication conditions. 相似文献
24.
《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2018,130(27):8164-8168
Dielectric switches that can be converted between high and low dielectric states by thermal stimuli have attracted much interest owing to their many potential applications. Currently one main drawback for practical application lies in the non‐tunability of their switch temperatures (TS). We report here an ionic co‐crystal (Me3NH)4[Ni(NCS)6] that contains a multiply rotatable Me3NH+ ion and a solely rotatable one due to a more spacious supramolecular cage for the former one. This compound undergoes an isostructural order–disorder phase transition and it can function as a frequency‐tuned dielectric switch with highly adjustable TS, which is further revealed by the variable‐temperature structure analyses and molecular dynamics simulations. In addition, the distinct arrangements and molecular dynamics of two coexisting Me3NH+ ions confined in different lattice spaces as well as the notable offset effect on the promoting/hindering of dipolar reorientation after dielectric transition provide a rarely observed but fairly good model for understanding and modulating the dipole motion in crystalline environment. 相似文献
25.
The phase behavior and motional mobility in binary blends of poly(4‐methylstyrene) (P4MS) and poly(cyclohexyl methacrylate) (PCHMA) have been examined by 13C solid state NMR techniques. The blend miscibility was studied by measuring the 1H spin‐relaxation times in the laboratory frame (T1H) and in the rotating frame (T1ρH), respectively. Although intermolecular spin diffusion contributes to the proton relaxations in accordance with homogeneity, T1ρH data shows signs of in complete averaging. The T1ρH relaxation behavior indicates the existence of heterogeneous do mains with shortest dimensions in the nanometer range, which is also sup ported by the intermolecular cross polarization experiments with variable contact times. In addition, according to the resuits of carbon T1ρ relaxation time measurements, it is concluded that mixing is intimate some what enough to cause a reduction in local chain mobility for P4MS and vice versa for PCHMA. 相似文献
26.
用动态力学损耗温度谱作为测试手段,研究了非晶态PET膜片在78—112℃温度范围内的单轴拉伸。实验结果说明,在较低温度下所得结晶的拉伸试样,完全由于应变诱发结晶,发生在应力-应变曲线的屈服后应力开始上升的阶段。在较高温度下(90℃或更高)拉伸可得非晶态而且光学各向同性的试样,是由于分子链的小尺度取向在拉伸过程中已完全热松弛所致,而分子链的大尺度取向要通过高弹态流动而松弛,其速率较慢,用拉伸后试样两端固定时的应力松弛进行了观察。在较低温度下应力松弛后仍为非晶态,在较高温度下应力松弛到起始应力的1O%下才开始结晶。FTIR研究表明在这种状态下的结晶有一结晶诱导期,其时间尺度与应力松弛阶段相当。 相似文献
27.
The cohesive interaction among polymer chains in a polyacrylamide (PAAm)–D2O solution has been studied by NMR relaxation. The NMR relaxation times of PAAm in the good solvent D2O were measured at different temperatures. The results show that the solution system has a high local viscosity and that its
relaxation characteristic is soft-solid-like. The temperature dependence of the relaxation behavior of the solution is obviously
different from that of ordinary polymer solutions. The difference lies in the relaxation behavior of the methylene protons
in the main chain of PAAm, as shown by analyzing the relaxation process with single exponential and biexponential decays.
As the temperature increases, the solvation is weakened, leading polymer chains to form curling coils, thus hindering the
movement of the methylene protons among the main chains. It can be expected from the existence of 80% fast-relaxing protons
that there are a zhigh number of entanglements among the polymer chains in PAAm solution. The information about entanglements
among the polymer chains can be deduced from the biexponential dependence of the spin–spin relaxation on the concentration
of the polymer solutions.
Received: 14 April 1999/Accepted in revised form: 12 October 1999 相似文献
28.
H.X. Zhu 《Journal of the mechanics and physics of solids》2010,58(5):696-709
Detailed mathematical derivation and simple closed form results for the size-dependent elastic properties of micro- and nano-sized honeycombs are presented in this paper. The results indicate that at micrometer scale, strain gradient has a dominant effect and at nano-meter scale, surface elasticity dominates the effect on the honeycomb elastic properties. The in-plane elastic properties of a nano- or micro-honeycomb could be controlled to vary over a range of around 10% by adjusting the initial stress in the cell walls by applying an electric potential. In addition, the bending and shear rigidities of some commonly used micro- and nano-structural elements have been obtained and presented in this paper, which could be of important applications in the design of MEMS and NEMS. 相似文献
29.
Dr. Olatz Larrañaga Prof. Dr. Ana Arrieta Prof. Dr. Célia Fonseca Guerra Prof. Dr. F. Matthias Bickelhaupt Dr. Abel de Cózar 《化学:亚洲杂志》2021,16(4):315-321
We have quantum chemically studied the structure and nature of alkali- and coinage-metal bonds (M-bonds) versus that of hydrogen bonds between A−M and B− in archetypal [A−M⋅⋅⋅B]− model systems (A, B=F, Cl and M=H, Li, Na, Cu, Ag, Au), using relativistic density functional theory at ZORA-BP86-D3/TZ2P. We find that coinage-metal bonds are stronger than alkali-metal bonds which are stronger than the corresponding hydrogen bonds. Our main purpose is to understand how and why the structure, stability and nature of such bonds are affected if the monovalent central atom H of hydrogen bonds is replaced by an isoelectronic alkali- or coinage-metal atom. To this end, we have analyzed the bonds between A−M and B− using the activation strain model, quantitative Kohn-Sham molecular orbital (MO) theory, energy decomposition analysis (EDA), and Voronoi deformation density (VDD) analysis of the charge distribution. 相似文献
30.
Reyhaneh Armin Sebastian Zühlke Gisela Grunewaldt-Stcker Felix Mahnkopp-Dirks Souvik Kusari 《Molecules (Basel, Switzerland)》2021,26(12)
Apple Replant Disease (ARD) is a significant problem in apple orchards that causes root tissue damage, stunted plant growth, and decline in fruit quality, size, and overall yield. Dysbiosis of apple root-associated microbiome and selective richness of Streptomyces species in the rhizosphere typically concurs root impairment associated with ARD. However, possible roles of Streptomyces secondary metabolites within these observations remain unstudied. Therefore, we employed the One Strain Many Compounds (OSMAC) approach coupled to high-performance liquid chromatography-high-resolution tandem mass spectrometry (HPLC-HRMSn) to evaluate the chemical ecology of an apple root-associated Streptomyces ciscaucasicus strain GS2, temporally over 14 days. The chemical OSMAC approach comprised cultivation media alterations using six different media compositions, which led to the biosynthesis of the iron-chelated siderophores, ferrioxamines. The biological OSMAC approach was concomitantly applied by dual-culture cultivation for microorganismal interactions with an endophytic Streptomyces pulveraceus strain ES16 and the pathogen Cylindrocarpon olidum. This led to the modulation of ferrioxamines produced and further triggered biosynthesis of the unchelated siderophores, desferrioxamines. The structures of the compounds were elucidated using HRMSn and by comparison with the literature. We evaluated the dynamics of siderophore production under the combined influence of chemical and biological OSMAC triggers, temporally over 3, 7, and 14 days, to discern the strain’s siderophore-mediated chemical ecology. We discuss our results based on the plausible chemical implications of S. ciscaucasicus strain GS2 in the rhizosphere. 相似文献