高岭土凝胶及氧化硅的制备与光谱性质研究

高岭土经氢氧化钠活化后与盐酸反应制备了硅铝酸盐凝胶,所得硅铝酸盐凝胶经过干燥与酸化处理得到氧化硅。利用红外光谱(IR)、X射线衍射(XRD)和X荧光光谱(XRF)对所得硅铝酸盐凝胶及氧化硅进行了表征研究,探索了高岭土制备硅铝酸盐凝胶的最佳条件。结果表明,高岭土矿为40 g时制备硅铝酸盐凝胶和氧化硅的最佳条件为：氢氧化钠用量15～20 g、盐酸浓度4～5 mol·L-1;IR,XRD及XRF表征结果显示,最终产物具有氧化硅的结构且其纯度较好。     

Preparation and Crystal Structure of 3-（2-Hydroxyphenyl） -6- （4-nitrophenyl）-7H- 1,2,4-triazolo[3,4-b][1, 3,4]thiadiazine

Introduction3,6- Disubstituted- 7H- 1 ,2 ,4- triazolo[3,4- b][1 ,3,4]thiadiazines are amongst the various hete-rocycles that received considerable attention duringthe last two decades as potential biologically activeagents.This kind of N- bridged heterocycles hasbeen reported to possess the wide spectrum of bio-logical properties,such as antimicrobial[1] ,an-tibacterial,antifungal[2 ] ,antiinflammatory[3 ] ,di-uretic[4] ,anthelmintic,and analgesic properties[5] .They can be also used as plant…     

基于均值漂移实现非发射线天体光谱的谱线自动提取

非发射线天体的光谱是天体光谱谱线提取中最难处理的一种。针对非发射线天体,给出了一种基于均值漂移的谱线自动提取方法。首先,利用均值漂移总是指向局部密度最大点也即密度的模式点这一性质,提取出较为满意的伪连续谱;其次,均值漂移滤波同时工作在空间域和幅度域上,是一种非线性的边缘保持滤波方法,在去除噪声的同时,能够较好地保持特征谱线的信息,文章在连续谱归一化后,采用均值漂移去噪得到谱线光谱;最后,对谱线光谱设置局部阈值提取出特征谱线。通过对恒星、正常星系等的实验表明：该方法是有效的, 这将对后续的参数测量和基于谱线的光谱分类非常有利。     

激光等离子体光谱测量影响因素分析

建立了一套激光等离子体光谱测量实验装置,以Nd:YAG调Q固体激光器(单脉冲平均能量38 mJ)为激发光源,铜合金为样品,得到了Cu原子辐射谱线随时间的变化情况,分析了系统中软、硬件因素对测量的谱线影响。实验证明激光器输出能量波动、每个数据点的平均次数、靶面相对于透镜焦点的位置、接受辐射的光纤束相对靶面法线的位置以及接受光纤束的有效通光口径都影响测量谱线的强度和重复精度。     

新型L-氨基酸尾式卟啉及其锌(Ⅱ)配合物的合成与光谱性质

用L-氨基酸和5-[邻-(2-溴乙氧基)苯基]-10,15,20-三苯基卟啉为原料合成了三种新型L-氨基酸尾式卟啉及其锌(Ⅱ)配合物,通过元素分析、红外光谱、紫外光谱、化学分析和质谱等对其进行了结构表征。测试并研究了它们在4 000～400 cm-1范围内的傅里叶变换红外光谱,对主要谱带进行了经验归属。     

SPECTRAL ANALYSIS OF THE FIRST-ORDER HERMITE CUBIC SPLINE COLLOCATION DIFFERENTIATION MATRICES

It has been observed numerically in [1] that, under certain conditions, all eigenvalues of the first-order Hermite cubic spline collocation differentiation matrices with unsymmetrical collocation points lie in one of the half complex planes. In this paper, we provide a theoretical proof for this spectral result.     

Nonlinear Time Series Forecast Using Radial Basis Function Neural Networks

In the research of using Radial Basis Function Neural Network (RBF NN) forecasting nonlinear time series, we investigate how the different clusterings affect the process of learning and forecasting. We find that k-means clustering is very suitable. In order to increase the precision we introduce a nonlinear feedback term to escape from the local minima of energy, then we use the model to forecast the nonlinear time series which are produced by Mackey-Glass equation and stocks. By selecting the k-means clustering and the suitable feedback term, much better forecasting results are obtained.     

广义部分Bent函数和广义Bent函数的关系

Bent函数是一类特殊的布尔函数,因其非线性性和稳定性在密码学和通信等领域有很重要的应用,但它们数量少,不平衡且无相关免疫性,为了弥补Bent函数的不足,Claud Carlet提出了部分Bent函数的概念,部分Bent函数是包含Bent函数的更大的函数类,后来,人们又将这两种函数概念先后都拓广到了环zm^n(m为正整数）上,分别被称为zm^n上的广义Bent函数和广义部分Bent函数,本文利用zp^n(p为素数）上广义部分Bent函数的Chrestenson循环谱特征讨论了zp^n上的广义部分Bent函数和广义Bent函数之间的关系,给出了这两种函数之间的函数关系式和谱值关系式。     

A Structured Family of Clustering and Tree Construction Methods

A cluster A is an Apresjan cluster if every pair of objects within A is more similar than either is to any object outside A. The criterion is intuitive, compelling, but often too restrictive for applications in classification. We therefore explore extensions of Apresjan clustering to a family of related hierarchical clustering methods. The extensions are shown to be closely connected with the well-known single and average linkage tree constructions. A dual family of methods for classification by splits is also presented. Splits are partitions of the set of objects into two disjoint blocks and are widely used in domains such as phylogenetics. Both the cluster and split methods give rise to progressively refined tree representations. We exploit dualities and connections between the various methods, giving polynomial time construction algorithms for most of the constructions and NP-hardness results for the rest.     

低真空时激光诱导Al等离子体辐射分析

用Nd :YAG激光烧蚀Al靶获得等离子体 ,激光脉冲能量为 145mJ·pulse-1,光源中通入Ar气作保护气体 ,压强为 10 0Pa。利用时间分辨技术获得纳秒级时间分辨光谱。分析了等离子体连续辐射、连续辐射的吸收、Al原子谱线辐射的时间演化规律 ,并进行了简短的讨论。结果发现 ,低真空时激光诱导Al等离子体的连续辐射、连续辐射的吸收、Al原子谱线辐射的时间演化规律以及它们之间的相互关系 ,与常压时的情况十分相似