全文获取类型
收费全文 | 118240篇 |
免费 | 8322篇 |
国内免费 | 12646篇 |
专业分类
化学 | 71309篇 |
晶体学 | 1153篇 |
力学 | 2436篇 |
综合类 | 846篇 |
数学 | 13014篇 |
物理学 | 19274篇 |
无线电 | 31176篇 |
出版年
2024年 | 338篇 |
2023年 | 1467篇 |
2022年 | 2567篇 |
2021年 | 2531篇 |
2020年 | 2961篇 |
2019年 | 2879篇 |
2018年 | 2682篇 |
2017年 | 3862篇 |
2016年 | 3875篇 |
2015年 | 3700篇 |
2014年 | 4704篇 |
2013年 | 8093篇 |
2012年 | 7939篇 |
2011年 | 7052篇 |
2010年 | 5656篇 |
2009年 | 7255篇 |
2008年 | 7607篇 |
2007年 | 8128篇 |
2006年 | 7527篇 |
2005年 | 6400篇 |
2004年 | 5821篇 |
2003年 | 4776篇 |
2002年 | 5716篇 |
2001年 | 3440篇 |
2000年 | 3082篇 |
1999年 | 2829篇 |
1998年 | 2512篇 |
1997年 | 2004篇 |
1996年 | 1715篇 |
1995年 | 1633篇 |
1994年 | 1400篇 |
1993年 | 1141篇 |
1992年 | 1043篇 |
1991年 | 732篇 |
1990年 | 593篇 |
1989年 | 544篇 |
1988年 | 394篇 |
1987年 | 303篇 |
1986年 | 284篇 |
1985年 | 228篇 |
1984年 | 244篇 |
1983年 | 144篇 |
1982年 | 212篇 |
1981年 | 176篇 |
1980年 | 196篇 |
1979年 | 183篇 |
1978年 | 171篇 |
1977年 | 122篇 |
1976年 | 109篇 |
1973年 | 67篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
本文首先将文[1]中的BLD映射推广为弱(L1,L2)-BLD映射,并证明了如下正则性结果:存在两个可积指数 P1=P1(n,L1,L2)<n<q1=q1(n,L1,L2),使得对任意弱(L1,L2)-BLD映射f∈(Ω,Rn),都有f∈(Ω,Rn),即f为(L1,L2)-BLD映射. 相似文献
92.
Nicolas Bergeron 《Mathematische Zeitschrift》2002,241(1):101-125
Let M be an arithmetic hyperbolic manifold and be a codimension 1 geodesic cycle. In this paper, we study the asymptotic growth of the -norm of the lifts of F in the congruence tower above M. We obtain an explicit value for the growth rate of this norm. In particular, we provide a new proof of a celebrated result
of Millson [Mi] on the homology of the arithmetic hyperbolic manifolds. The method is quite general and gives a new way of
getting non zero homology classes in certain locally symmetric spaces.
Received: 20 April 2001; in final form: 26 September 2001 / Published online: 28 February 2002 相似文献
93.
Mariusz Gadzinowski Stanislaw Sosnowski 《Journal of polymer science. Part A, Polymer chemistry》2003,41(23):3750-3760
New biodegradable/biocompatible ABC block copolymers, poly(ethylene oxide)‐b‐poly(glycidol)‐b‐poly(L ,L ‐lactide) (PEO‐PGly‐PLLA), were synthesized. First, PEO‐b‐poly(1‐ethoxyethylglycidol)‐b‐PLLA was synthesized by a successive anionic ring‐opening copolymerization of ethylene oxide, 1‐ethoxyethylglycidyl ether, and L ,L ‐lactide initiated with potassium 2‐methoxyethanolate. In the second step, the 1‐ethoxyethyl blocking groups of 1‐ethoxyethylglycidyl ether were removed at weakly acidic conditions leaving other blocks intact. The resulting copolymers were composed of hydrophilic and hydrophobic segments joined by short polyglycidol blocks with one hydroxyl group in each monomeric unit. These hydroxyl groups may be used for further copolymer transformations. The PEO‐PGly‐PLLA copolymers with a molecular weight of PLLA blocks below 5000 were water‐soluble. Above the critical micellar concentration (ranging from 0.05 to1.0 g/L, depending on the composition of copolymer), copolymers formed macromolecular micelles with a hydrophobic PLLA core and hydrophilic PEO shell. The diameters of the micelles were about 25 nm. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3750–3760, 2003 相似文献
94.
贝克曼Allegra^TM 21R型超高速离心机开机后,操作面板上出现错误代码“28”,离心机不旋转。离心机的电机采用无刷感应驱动,由电机驱动电源模块BSMl0GD60DN2驱动离心机的电机。故障是由于电源模块BSMl0GD60DN2损坏引起的。采用东芝三相桥式IGBT电源模块MG25Q6ES42代替BSMl0GD60DN2,并更换已烧毁的栅极电阻后。开机试验,仪器恢复正常。 相似文献
95.
[Na(18-C-6)]2[Cu(i-mnt)2]的合成与结构分析 总被引:2,自引:2,他引:0
研究了18-冠-6与Na2[Cu(i-mnt)2][i-mnt=异丁二腈烯二硫醇阴离子,S2CC(CN)2-2]的反应,得到的配合物[Na(18-C-6)]2[Cu(i-mnt)2](1)通过元素分析、红外光谱、X射线单晶衍射进行了结构分析.配合物为单斜晶系,空间群P2(1)/c.晶体学结构数据a=1.2819(11),b=1.1793(10),c=1.4928(13)nm,β=99.121(16)°,V=2.228(3)nm3,Z=2,Dcaled.=1.369g/cm3,F(000)=958,R1=0.0521,wR2=0.1003.1中的[Cu(i-mnt)2]基团通过配体i-mnt的氮原子与两个[Na(18-C-6)]基团中的钠原子成键,形成稳定的中性配合物. 相似文献
96.
P. R. Latthe P. S. Shinge Bharati V. Badami P. B. Patil S. N. Holihosur 《Journal of Chemical Sciences》2006,118(3):249-256
3-[4-(Azidocarbonyl)]phenylsydnone (2) obtained from 3-(4-hydrazinocarbonyl) phenylsydnone (1) on Curtius rearrangement with alcohols, water and amines afforded the corresponding carbamates (3a-h), 4,4′-(sydnone-3-yl) diphenyl urea (4) and 4-(heterocyclyl)phenyl ureas (5a-l). Compounds (5a-l) on one-pot ring conversion yielded the 1,3,4-oxadiazolin-2-one derivatives (6a-l), which on reaction with N2H4 gave the 4-amino-1,2,4-triazolin-3-ones (7a-l). All these compounds exhibited moderate antimicrobial activity against the few microbes tested. The carbamates have been
found to be more toxic against fourth instar larvae ofAedes aegypti, in particular, then-butyl derivative (3e). 相似文献
97.
We predict ultraslow collapse of “tubular image states” (TIS) on material surfaces. TIS are bound Rydberg-like electronic states formed at large distances (∼30 nm) from the surfaces of suspended circularly-symmetric nanowires, such as metallic C nanotubes. The states are formed in potential wells, resulting from a combination of the TIS-electron attraction to image charges in the nanotube and its centrifugal repulsion, caused by spinning around the tube. We demonstrate that TIS can collapse on the tube surface by passing their angular momentum l to circularly polarized flexural phonons excited in the tube. Our analysis shows that for highly detached TIS with l ? 6 the relaxation lifetimes are of the order of 10 ns-1 μs, while for l < 6 these lifetimes are reduced by several orders of magnitude. 相似文献
98.
本文提出一种多输入多输出(MIMO)天线系统中简单的扩展空时块编码(SSTBC)分集技术,采用沃尔什码来区分各天线发送数据子流。采用这种方法,在系统带宽一定时,不降低发送信息速率,同时接收机简单。不同天线的发送信息经过了所有收一发天线对之间的空间子信道,获得了所有路径的部分空间分集增益,仿真结果表明,这种增益的获得不受限于接收分集阶数,并且随发射天线的增加以一定的线性关系增加。 相似文献
99.
研究了多径信道下OFDM系统的一种新的载波频率跟踪算法,这种算法以判决反馈和接收端的时域信号重构为基础。推导了估计结果的精确解,比较了使用原估计结果和新的估计结果进行频偏补偿时系统跟踪性能的不同。通过对算法的仔细分析,发现除了通常的加性噪声外,信道估计误差、子载波数目和子载波的调制方式也影响频偏的估计结果和跟踪范围,而且子载波的数目和调制方式是决定性的因素。这种频率跟踪方法的优点是即使在很低的信噪比下仍然能获得高的跟踪精度,且实现相对简单。 相似文献
100.
The development of the poly(3‐hydroxybutyrate) (PHB) morphology in the presence of already existent poly(vinylidene fluoride) (PVDF) spherulites was studied by two‐stage solidification with two separate crystallization temperatures. PVDF formed irregular dendrites at lower temperatures and regular, banded spherulites at elevated temperatures. The transition temperature of the spherulitic morphology from dendrites to regular, banded spherulites increased with increasing PVDF content. A remarkable amount of PHB was included in the PVDF dendrites, whereas PHB was rejected into the remaining melt from the banded spherulites. When PVDF crystallized as banded spherulites, PHB could consequently crystallize only around them, if at all. In contrast, PHB crystallized with a common growth front, starting from a defined site in the interfibrillar regions of volume‐filling PVDF dendrites. It formed by itself dendritic spherulites that included a large number of PVDF spherulites. For blends with a PHB content of more than 80 wt %, for which the PVDF dendrites were not volume‐filling, PHB first formed regular spherulites. Their growth started from outside the PVDF dendrites but could later interpenetrate them, and this made their own morphology dendritic. These PHB spherulites melted stepwise because the lamellae inside the PVDF dendrites melted at a lower temperature than those from outside. This reflected the regularity of the two fractions of the lamellae because that of those inside the dendrites of PVDF was controlled by the intraspherulitic order of PVDF, whereas that from outside was only controlled by the temperature and the melt composition. The described morphologies developed without mutual nucleating efficiency of the components. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 873–882, 2003 相似文献