超强磁场下非掺杂ZnSe/BeTe Ⅱ型量子阱中激子和带电激子的光学特性

报道了液态氦温度(4.2 K)下非掺杂ZnSe/BeTe Ⅱ型量子结构中ZnSe势阱层内空间直接光致发光(PL)光谱的磁场依赖性(磁场高达53 T).实验结果显示,随着磁场的增加,激子和带电激子的PL强度呈现出相反的振动行为.当激子的PL强度增加时带电激子的PL强度减小,反之,当激子的强度减小时带电激子的强度却增加.并且在整个磁场范围内,这些振动呈现近似等间隔的周期性变化.这个行为被解释为费米能级与朗道能级的周期性共振,这个共振导致了处于费米能级上的二维电子气态密度的周期性调制. 关键词： 光致发光 二维电子气 带电激子 Ⅱ型量子阱     

Stability and vibrational properties of the hydrogen atom for p-type AlN doped with group-Ⅱ:a first-principles study

The stability and local vibrational mode (LVM) of hydrogen related p-type AlN have been studied by first-principles calculations based on density functional theory. The stable and metastable microscopic geometries ofgroup-Ⅱ (Be, Mg, Ca, Sr, Ba)-H complexes have been investigated. The calculated results indicate that BCⅡ is the most stable configuration for isolated interstitial H+ and Be-H complexes, while it is ABN,⊥ for Mg-H, Ca-H, Sr-H and BaH complexes. Moreover, the vibrational frequencies and the values ofk and |α| for the H atom with LVM are calculated. Here, the values of k and |α| are used to describe the parameters of the harmonic and anharmonic contributions, re-spectively. The calculated results indicate that the larger the size of the doped ion is, the shorter the N-H bond length is, and the larger the potential energy, the vibrational frequencies, the values of k and |α| are. This implies that the size of the doped ion has an important influence on the vibrational properties of H.     

定数截尾两参数指数——威布尔分布形状参数的Bayes估计

在不同的损失函数下,本文研究了两参数指数—威布尔分布(EWD)形状参数的Bayes估计问题.基于定数截尾试验,当其中一个形状参数α已知时,给出了另一个形状参数θ在三种不同损失函数下的Bayes估计表达式,并求得了可靠度函数的Bayes点估计.最后运用随机模拟方法,将Bayes估计和极大似然估计进行了比较.结果表明,LINEX损失下Bayes估计的精度比极大似然估计高.     

BBO晶体Ⅱ类相位匹配光参量放大理论分析

理论研究了BBO晶体在Ⅱ类相位匹配下非共线情况时的参量放大特性。计算了在不同非共线夹角下的相位匹配角度。在增益谱分布的模拟计算中发现Ⅱ类匹配具有非常窄的增益带宽，并在其参量带宽的模拟计算中得到了证实。数值模拟了转换效率随晶体长度的变化曲线。分析了抽运光脉冲和信号光脉冲的时间不同步以及初始输入的信号光脉冲形状对转换效率的影响。选择最佳晶体长度和同步时间，最大转换效率可达到25％。研究结果表明BBO的Ⅱ类相位匹配具有非常窄的参量带宽和增益带宽，这对于窄带的激光参量放大的研究有重要意义，并拓宽了BBO晶体在光参量放大技术中的用途。     

超导电流密度研究

由 GL超导波函数及 GL第二方程导出了零场下超导电流密度矢量的数学表达式 ,讨论了相关物理意义 ;并由 London第二方程验证了其正确性。     

脊椎结核患儿手术后发生喉水肿的因素分析

姜虹，周高岚．脊椎结核患儿手术后发生喉水肿的因素分析．数理统计与管理，１９９８，１７（３），１～３．根据数量化理论Ⅱ和４６３例患儿的临床研究，分析了脊椎结核患儿手术后发生喉水肿的主要原因，为今后的医疗实践提供了依据，证实了数量化理论Ⅱ的应用价值     

Synthesis,Crystal Structure,Spectroscopic Characterization,Thermal Stability and Magnetic Properties of a Dinuclear Copper(Ⅱ) Complex

A new copper(Ⅱ) complex [Cu2(MNA)2(2,2‘-bipy)2]·2.5H2 O with methy-5-norbornene-2,3-dicarboxylic acid(MNA) and 2,2’-bipyridine as ligands has been synthesized in the mixed solvents of DMF and water.It crystallizes in monoclinic,space group P 1,with a = 10.4191(11),b = 12.8883(13),c = 16.1114(16) ?,α = 70.8090(10),β = 80.568(2),γ = 77.440(2)o,V = 1984.3(4) ?3,Dc = 1.551 g/cm3,Z = 2,F(000) = 962,the final GOOF = 1.051,R = 0.0431 and w R= 0.0980.The crystal structure shows that the whole molecule consists of two independent dinuclear units,in which two copper ions are bridged by two μ2-η1:η0 3-carboxylate groups of MNA2-.The coordination environment of Cu(Ⅱ) ion is Cu O3N2,giving a distorted square pyramidal geometry.The spectroscopic characterization,thermal stability and magnetic properties of the complex were investigated.     

Synthesis,Crystal Structure and Catalytic Properties of a 2D Cobalt(Ⅱ) Coordination Polymer Based on Mixed Ligands

A new Co(II) metal-organic coordination polymer based on flexible bis(imidazole) and aromatic dicarboxylate co-ligands, namely [Co(bix)(nph)]n(H2nph = 3-nitrophthalic acid, bix = 1,4-bis(imidazole-1-ylmethyl)benzene), has been hydrothermally synthesized and characterized by elemental analyses, TG, IR spectroscopy and single-crystal X-ray diffraction. It crystallizes in the triclinic space group P1 with a = 9.3767(14), b = 10.1451(15), c = 12.1488(17), α = 102.6450(10), β = 108.856(2), γ = 98.807(2)°, V = 1035.3(3)3, Z = 2, C22H17 Co N5O6, Mr = 506.34, Dc = 1.624 g/cm3, μ = 0.882 mm-1 and F(000) = 518. In the complex, the nph2- ligands connect neighbouring cobalt atoms to form binuclear [Co(nph)]2 subunits, which are linked by pairs of bix ligands to form a 2D honeycomb-like(6,3) network. In addition, the compound is further extended into a 3D supramolecular architecture by π···π stacking interactions. Moreover, the luminescence and catalytic properties of the complex are investigated.     

Syntheses and Structures of Two Macrocyclic Nickel(Ⅱ) Complexes Bridging Benzene Polycarboxylic Acid

Two complexes with formulas [Ni L][(Ni L)(IPA)2]·8H2O(1) and [(Ni L)(H2O)2] [(Ni L)(PMA)]·4H2O(2)(L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane,IPA2– = isophthalic anion,PMA4– = 1,2,4,5-benzenetetracarboxylic anion) were synthesized and characterized by elemental analyses and IR spectra.The crystal structures were determined by X-ray diffraction.In complex 1,the [Ni L]2+ bridged IPA2– to give [(Ni L)(IPA)2]2– monomer,and the [Ni L]2+ bridged PMA4– to form a one-dimensional chain [(Ni L)(PMA)]n2n– in complex 2.The [Ni L]2+ and [(Ni L)(IPA)2]2–/[(Ni L)(PMA)]2– are connected through intermolecular hydrogen bonding to generate three-dimensional supramolecular structures.     

Hydrothermal Syntheses and Crystal Structures of Two Complexes of Cobalt and Manganese Assembled by 4,4'-Oxydibenzoic Acid

Two new coordination polymers [Co(oba)(mbix)]2n·n H2O(1) and [Mn(Hoba)2(H2O)2]n(2)(H2oba = 4,4'-oxydibenzoic acid, mbix = 1,3-bis(imidazol-1-ylmethyl)benzene) have been successfully synthesized under hydrothermal conditions. Their structures have been determined by elemental analyses, IR spectroscopy, UV and single-crystal X-ray diffraction analysis. The intermolecular hydrogen bonding and π-π stacking interactions extend the complexes into a 3D supramolecular structure.