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41.
42.
Claudius Lupfer Sebastian Seitel Oliver Skarsetz Andreas Walther 《Angewandte Chemie (International ed. in English)》2023,62(41):e202309236
Cellular organisms possess intricate mechano-adaptive systems that enable them to sense forces and process them with (bio)chemical circuits for functional adaptation. Inspired by such processes, this study introduces a hydrogel system capable of mechanically activated and chemically transduced self-destruction. Our judiciously designed hydrogels can mechanically generate radicals that are processed and amplified in a self-propagating radical de-crosslinking reaction, ultimately leading to mechanically triggered self-immolation. We put such systems to work in mechano-induced debonding, and in a bilayer actuator, where swelling-induced bending generates sufficient force for selective degradation of one layer, leading to autonomous self-regulation associated with unbending. Our work helps define design criteria for molecularly controlled adaptive and self-regulating materials with embodied mechano-chemical information processing, and showcases their potential for adhesives and soft robotics. 相似文献
43.
Summary A modified derivative of chromatographic signal is proposed for detection of the appearance of a new peak. The method is shown to yield peak areas of good precision even in very noisy systems.This paper is dedicated to Dr. Leslie Ettre on his 60th birthday. 相似文献
44.
O. Slaby S. Sager O. S. Shaik U. Kummer 《Mathematical and Computer Modelling of Dynamical Systems: Methods, Tools and Applications in Engineering and Related Sciences》2013,19(5):487-502
We demonstrate how model-based optimal control can be exploited in biological and biochemical modelling applications in several ways. In the first part, we apply optimal control to a detailed kinetic model of a glycolysis oscillator, which plays a central role in immune cells, in order to analyse potential regulatory mechanisms in the dynamics of associated signalling pathways. We demonstrate that the formulation of inverse problems with the aim to determine specific time-dependent input stimuli can provide important insight into dynamic regulations of self-organized cellular signal transduction. In the second part, we present an optimal control study aimed at target-oriented manipulation of a biological rhythm, an internal clock mechanism related to the circadian oscillator. This oscillator is responsible for the approximate endogenous 24 h (latin: circa dies) day-night rhythm in many organisms. On the basis of a kinetic model for the fruit fly Drosophila, we compute switching light stimuli via mixed-integer optimal control that annihilate the oscillations for a fixed time interval. Insight gained from such model-based specific manipulation may be promising in biomedical applications. 相似文献
45.
《Journal of computational and graphical statistics》2013,22(2):399-421
Wavelet-based denoising techniques are well suited to estimate spatially inhomogeneous signals. Waveshrink (Donoho and Johnstone) assumes independent Gaussian errors and equispaced sampling of the signal. Various articles have relaxed some of these assumptions, but a systematic generalization to distributions such as Poisson, binomial, or Bernoulli is missing. We consider a unifying l1-penalized likelihood approach to regularize the maximum likelihood estimation by adding an l1 penalty of the wavelet coefficients. Our approach works for all types of wavelets and for a range of noise distributions. We develop both an algorithm to solve the estimation problem and rules to select the smoothing parameter automatically. In particular, using results from Poisson processes, we give an explicit formula for the universal smoothing parameter to denoise Poisson measurements. Simulations show that the procedure is an improvement over other methods. An astronomy example is given. 相似文献
46.
《Journal of computational and graphical statistics》2013,22(2):283-309
A simple and yet powerful method is presented to estimate nonlinearly and nonparametrically the components of additive models using wavelets. The estimator enjoys the good statistical and computational properties of the Waveshrink scatterplot smoother and it can be efficiently computed using the block coordinate relaxation optimization technique. A rule for the automatic selection of the smoothing parameters, suitable for data mining of large datasets, is derived. The wavelet-based method is then extended to estimate generalized additive models. A primal-dual log-barrier interior point algorithm is proposed to solve the corresponding convex programming problem. Based on an asymptotic analysis, a rule for selecting the smoothing parameters is derived, enabling the estimator to be fully automated in practice. We illustrate the finite sample property with a Gaussian and a Poisson simulation. 相似文献
47.
This letter presents a new method for continuous signal modeling. Firstly, the continuous signal can be represented as a function of the trigonometric functional extension (Fourier series). Fourier series of the signal are parameterized by the fundamental frequency and unknown parameters. Then, the gradient-based iterative identification algorithm is derived, for estimating parameters of the signal model with known and unknown frequencies, separately. Finally, the simulation results indicate that the proposed algorithm is effective. 相似文献
48.
Oliver Salazar Celis Annie Cuyt Dirk Deschrijver Dries Vande Ginste Tom Dhaene Luc Knockaert 《Applied Mathematical Modelling》2013
In this paper a novel macromodeling scheme is presented to model the per unit of length (p.u.l.) parameters of uniform transmission lines. In particular, it is focused on single on-chip interconnects, because their p.u.l. parameters are influenced by the presence of semiconductor (s) and as such exhibit a strong frequency-dependency, making the modeling process harder. Starting from a set of very accurate tabulated data samples, obtained by two-dimensional electromagnetic modeling, rational models for the four p.u.l. parameters are constructed. The novelty of the approach lies in the fact that the rational models are positive by construction and that a controllable accuracy is obtained. These models can then further be used to construct multivariate models, e.g., for variability analysis. Here, the novel scheme is applied to an on-chip inverted embedded microstrip line, of which the signal integrity behavior is assessed in both the frequency and the time domain, demonstrating the applicability of the macromodels. 相似文献
49.
Fabrice Chevalier Deepak DSouza M. Raj Mohan Pavithra Prabhakar 《Annals of Pure and Applied Logic》2009,161(3):324-336
We extend some of the classical connections between automata and logic due to Büchi (1960) [5] and McNaughton and Papert (1971) [12] to languages of finitely varying functions or “signals”. In particular, we introduce a natural class of automata for generating finitely varying functions called ’s, and show that it coincides in terms of language definability with a natural monadic second-order logic interpreted over finitely varying functions Rabinovich (2002) [15]. We also identify a “counter-free” subclass of ’s which characterise the first-order definable languages of finitely varying functions. Our proofs mainly factor through the classical results for word languages. These results have applications in automata characterisations for continuously interpreted real-time logics like Metric Temporal Logic (MTL) Chevalier et al. (2006, 2007) [6] and [7]. 相似文献
50.
In this paper we propose an Ant Colony Optimisation (ACO) algorithm for defining the signal settings on urban networks following a local approach. This consists in optimising the signal settings of each intersection of an urban network as a function only of traffic flows at the accesses to the same intersection, taking account of the effects of signal settings on costs and on user route choices. This problem, also known as Local Optimisation of Signal Settings (LOSS), has been widely studied in the literature and can be formulated as an asymmetric assignment problem. The proposed ACO algorithm is based on two kinds of behaviour of artificial ants which allow the LOSS problem to be solved: traditional behaviour based on the response to pheromones for simulating user route choice, and innovative behaviour based on the pressure of an ant stream for solving the signal setting definition problem. Our results on real-scale networks show that the proposed approach allows the solution to be obtained in less time but with the same accuracy as in traditional MSA (Method of Successive Averages) approaches. 相似文献