一类树的SL谱刻画

图的谱理论是图论与组合矩阵论的一个重要研究领域。设图G是一个有n个顶点、m条边的简单图,Q（G）为图G的无符号拉普拉斯矩阵,树图是图论研究的一类重要的图,为了确定一类树的sL谱惟一性,利用图与同谱图之间的关系,运用删边缩边原理,探讨了两组顶点数目的树图。通过比较两组图中子树数目的大小逐项排除和删边删点的方法证明了一类树的SL谱惟一性。     

顶空气相色谱质谱法快速测定液体食品中的挥发性酸

建立了一种用于快速测定食品中挥发性有机酸的分析方法.利用顶空技术对样品进行前处理,并与气相色谱质谱联用,用离子选择对11种挥发性有机酸进行定量分析.在优化的实验条件下,方法线性关系良好,线性范围为0.20 ～5 mg/L.11种挥发性有机酸的相关系数均大于0.998 6,检出限为0.000 2 ～35.5 mg/L,比全扫描检出限低1 ～3个数量级.11种挥发性有机酸的回收率为93% ～99%,相对标准偏差均小于10%.该方法简便、快速、重复性好、定性定量准确,适于食品中挥发性有机化合物的检测.     

Numerical discussions on complete empirical correlation in Langtry's transition model

Recently, introducing a transition predicting model into the Reynolds averaged Navier-Stokes (RANS) environment has been paid more and more attention. Langtry proposed a correlation-based transition model in 2006, which was built strictly on local variables. However, two core correlations in the model had not been published until 2009. In this paper, after considerable analyses and discussions of the mechanism of this transition model and a series of numerical validations in the skin friction coefficient of flat plate boundary layers, a new correlation based on free-stream turbulence intensity is developed, and the empirical correlation of the transition onset momentum thickness Reynold number aiming at the hypersonic transition is improved. Low-speed/transonic airfoils and a hypersonic double wedge flat are tested to prove the reliability and practicability of this correlation.     

Numerical discussions on complete empirical correlation in Langtry＇s transition model

Recently, introducing a transition predicting model into the Reynolds averaged Navier-Stokes （RANS） environment has been paid more and more attention. Langtry proposed a correlation-based transition model in 2006, which was built strictly on local variables. However, two core correlations in the model had not been published until 2009. In this paper, after considerable analyses and discussions of the mechanism of this transition model and a series of numerical validations in the skin friction coefficient of flat plate boundary layers, a new correlation based on free-stream turbulence intensity is developed, and the empirical correlation of the transition onset momentum thickness Reynold number aiming at the hypersonic transition is improved. Low-speed/transonic airfoils and a hypersonic double wedge fiat are tested to prove the reliability and practicability of this correlation.     

基于单片机的无线仓储湿度检测系统设计

系统以单片机STC89C52RC作为控制处理核心,采用芯片nRF905为无线传输模块,HS1100/HS1101传感器采集湿度信号,设计了一种无线仓储湿度检测仪。经实验测试表明:系统湿度检测范围为10%RH~100%RH;精度达±1%RH,数据无线传输距离200米。设计的系统符合预期要求,可在仓储日常管理、气象、酒厂等不易布线,且需要实时监测湿度参数的场合推广应用。     

无约束最优化的Polak—Ribiere和Hestenes—Stiefel共轭梯度法的全局收敛性

本文在很弱的条件下得到了无约束最优化的Polak-Ribiere和Hestenes-Stiefel共轭梯度法的全局收敛性的新结果,这里PR方法和HS方法中的参数β^PRk和β^HSk可以在某个负的区域内取值,这一负的区域与k有关,这些新的收敛性结果改进了文献中已有的结果。数值检验的结果表明了本文中新的PR方法和HS方法是相当有效的。     

Development of a broad toxicological screening technique for urine using ultra-performance liquid chromatography and time-of-flight mass spectrometry

Withdrawal of the support for the REMEDi HS drug profiling system has necessitated its replacement within our laboratories with an alternative broad toxicological screening technique. To this end, a novel method, based on ultra-performance liquid chromatography (UPLC) and time-of-flight (TOF) mass spectrometry, was developed for the routine analysis of urine samples. Identification was achieved by comparison of acquired data to libraries containing more than 300 common drugs and metabolites, and was based on a combination of retention time, exact mass and fragmentation patterns. Validation data for the method is presented and comprised an evaluation of the following parameters: precision; transferability of the methodology between the six collaborating laboratories; specificity; extraction recovery and stability of processed samples; matrix effects and sensitivity.This paper presents the benefits of supplementary fragmentation data with particular regard to increasing specificity and confidence of identification and its usefulness with overdosed samples. The utility of the method was assessed by the parallel analysis of 30 authentic urine samples using the REMEDi HS and UPLC-TOF. The latter provided enhanced detection, leading to the identification of twice as many drugs. Furthermore it did not miss any compounds that were identified by REMEDi HS. The UPLC-TOF findings were further verified by a combination of data from three other conventional screening techniques, i.e., GC-MS, HPLC-DAD and UPLC-MS/MS.     

无约束最优化的Polak-Ribière和Hestenes-Stiefel共轭梯度法的全局收敛性

本文在很弱的条件下得到了关于无约束最优化的Ｐｏｌａｋ—Ｒｉｂｉｅｒｅ和Ｈｅｓｔｅｎｅｓ－Ｓｔｉｅｆｅｌ共轭梯度法的全局收敛性的新结果,这里 ＰＲ方法和ＨＳ方法中的参数β_k~(PR)和β_k~HS可以在某个负的区域内取值,这一负的区域与ｋ有关．这些新的收敛性结果改进了文献中已有的结果．数值检验的结果表明了本文中新的 ＰＲ方法和 ＨＳ方法是相当有效的．     

Headspace‐single drop microextraction with a commercial capillary electrophoresis instrument

Automated coupling of headspace‐single drop microextraction (HS‐SDME) and CE has been demonstrated using a commercial CE instrument. When a drop hanging at the inlet tip of a capillary for CE is used as the acceptor phase, HS‐SDME becomes a simple but powerful sample pretreatment technique for CE before injection to facilitate sample cleanup and enrichment. By combining HS‐SDME with an on‐line sample preconcentration technique, large volume sample stacking using an electroosmotic flow pump, the sensitivity can be improved further. The overall enrichment factors for phenolic compounds were from 1900 to 3400. HS‐SDME large volume sample stacking using an electroosmotic flow pump was successfully applied to a red wine sample to obtain an LOD of 4 nM (0.8 ppb) for 2,4,6‐trichlorophenol which is a precursor for 2,4,6‐trichloroanisole causing the foul odor in wine called cork taint.     

Headspace solid-phase microextraction with on-fiber derivatization for the determination of aldehydes in algae by gas chromatography-mass spectrometry

A simple, fast, sensitive and cost-effective method based on headspace solid-phase microextraction (HS-SPME) with on-fiber derivatization coupled with gas chromatography-mass spectrometry was developed for the determination of six typical aldehydes, 2E-hexenal, heptanal, 2E-heptenal, 2E,4E-heptadienal, 2E-decenal and 2E,4E-decadienal in laboratory algae cultures. As derivatization reagent, O-2,3,4,5,6-(pentafluorobenzyl) hydroxylamine hydrochloride, was loaded onto the poly(dimethylsiloxane)/divinylbenzene fiber for aldehydes on-fiber derivatization prior to HS-SPME. Various influence factors of extraction efficiency were systematically investigated. Under optimized extraction conditions, excellent method performances for all the six aldehydes were attained, such as satisfactory extraction recoveries ranging from 67.1 to 117%, with the precision (relative standard deviation) within 5.3-11.1%, and low detection limits in the range of 0.026-0.044 μg/L. The validated method was successfully applied for the analysis of the aldehydes in two diatoms (Skeletonema costatum and Chaetoceros muelleri), two pyrrophytas (Prorocentrum micans and Scrippsiella trochoidea) and Calanus sinicus eggs (feeding on the two diatoms above).