Magnetospectroscopy of double HgTe/CdHgTe QWs with inverted band structure in high magnetic fields up to 30 T

Magnetoabsorption in far and mid IR ranges in double HgTe/CdHgTe quantum wells with inverted band structure has been studied in high magnetic fields up to 30 T. Numerous intraband and interband transitions have been revealed in the spectra and interpreted within axial 8 × 8 k·p model. Splitting of dominant magnetoabsorption lines resulting from optical transitions from hole-like zero-mode Landau level has been discovered and discussed in terms of a built-in electric field and collective phenomena.     

前苏联和俄罗斯模糊理论研究与应用情况概述

对前苏联20世纪80年代及苏联解体后俄罗斯20世纪90年代的模糊理论研究与应用情况作了概述,列举了在人工智能认知的模糊原理、信息论的模糊性和模糊空间、随机模糊规划、工业用综合模糊控制系统等领域的研究成果,并列出90多篇（部）俄文文献资料。     

俄罗斯微型集成电路命名方法(OCT 11 073.915-2000标准)

介绍了俄罗斯OCT 11 073.915-2000标准规定的微型集成电路命名方法,给出器件命名的规则,使用符号及命名中使用的俄罗斯各生产厂家代码.     

Free energy of nonideal two-component thermal plasma

The free energy of nonideal two-component thermal plasma is calculated using the Poisson-Boltzmann equation. The possibility of the existence of a metastable state is shown for a component of heavy multicharged particles with particle charge values bounded from below and plasma temperature values bounded from above. The component of oppositely-charged light singly-charged particles and plasma generally do not feature the metastable state.     

基于可变模糊模型的非毗邻地区经济协调发展研究——以中俄豫伊两地为例

区域经济协调性是区域经济协同发展和可持续发展的基本保障,也是区域间经济合作和贸易的基础.以区域经济系统为研究对象,利用可变模糊识别模型对中俄豫伊两地2013-2019年的经济协调度发展进行了定量分析,探求两地经济协调发展的静态及动态机制.研究表明,近7年两地区经济经历了动态平衡到协调的调整和转变过程,向良好协调的状况发...     

俄罗斯翠榴石的化学成分及光谱学表征

翠榴石为石榴石家族中最为贵重的亚种,以其漂亮的外观和稀有性深受欢迎。尤其是俄罗斯所产翠榴石更是国内外收藏家最为追捧的对象。前人从不同角度对石榴石族矿物研究较多,但关于翠榴石的研究较少。为了探究俄罗斯翠榴石的化学成分及光谱学特征,运用LA-ICP-MS,IR,Raman和UV-Vis,对俄罗斯翠榴石进行系统研究,旨在获得其化学成分尤其是稀土元素特征、光谱学特征,分析致色原因,为其品种鉴定及产地溯源提供重要数据。化学成分研究表明,俄罗斯翠榴石几乎为纯的钙铁榴石(Andradite>96.39 Mol.%)。次要成分中,Cr₂O₃含量较高,平均0.502 Wt%,除此以外还含少量Al,Mn,Ti和V。其中Cr和V均为石榴石中致绿色的元素。稀土元素含量总体不高,∑REE平均4.85 μg·g-1;且轻稀土元素明显富集,∑LREE平均4.56 μg·g-1;重稀土元素相对亏损,∑HREE平均0.29 μg·g-1, ∑LREE/∑HREE=5.35~100.48。多数样品显示Eu正异常。主要拉曼位移为994.5,873.5,841.5,815,576,552,515,492,451,369,351,323,310.5,295,263,234.5和172 cm-1。拉曼光谱仅可作为翠榴石品种鉴定的手段之一,对其产地溯源作用不大。红外光谱研究表明,指纹区红外反射光谱可以有效鉴别翠榴石,红外光谱官能团区显示结构水的吸收峰,表明俄罗斯翠榴石含有少量结构水,这与其形成过程与热液交代作用有关。紫外-可见吸收光谱研究显示,俄罗斯翠榴石在384和440 nm处具明显吸收峰,436 nm见弱吸收峰,620 nm附近出现宽缓吸收带,从500 nm附近至紫外区强烈吸收。分析认为440 nm吸收带归于八面体位Fe3+的6A₁→4A_1g+4E_g(G)跃迁所致;620 nm吸收带归于八面体位Cr3+的4A_2g(F)→4T_2g(F) d-d跃迁所致,Fe和Cr同为致色元素,O-Fe荷移带及440 nm强吸收带使得钙铁榴石产生黄色、黄绿色,Cr3+的加入,产生620 nm宽缓吸收带,吸收橙黄色光,使得宝石颜色向绿色端偏移,显示纯正的绿色。拉曼光谱、红外光谱指纹区特征可以用于准确鉴定翠榴石;稀土元素特征及中红外光谱官能团区结构水特征,可以为其产地溯源提供重要信息。     

Naphthalene derivatives of a conformationally locked GFP chromophore with large stokes shifts

The active development of fluorescence microscopy requires an increase in the variety of the dyes and their characteristics. Compounds with a large Stokes shift, i.e., a large difference between the positions of the absorption and emission maxima, have attracted the interest of researchers as a tool that can be used for multicolor labeling. One of the known approaches to increase the Stokes shift is the introduction of additional polycyclic fragments. Herein, we report novel derivatives of a conformationally locked GFP chromophore containing the naphthalene ring. The proposed modification leads not only to the enhancement of the Stokes shift up to 100 nm but also leads to the noticeable red-shift of the emission and absorption spectra in contrast with the corresponding derivatives with one benzene ring.     

Multicomponent reaction of conjugated enynones with malononitrile and sodium alkoxides: Complex reaction mechanism of the formation of pyridine derivatives

Reaction of conjugated enynones,1,5-diarylpent-2-en-4-yn-1-ones, with malononitrile and sodium alkoxides in the corresponding alcohols at room temperature for 3–23 h results in the formation of two types of compounds (E)-/(Z)-6-aryl-4-(2-arylethenyl)-2-alkoxypyridine-3-carbonitriles (substituted nicotinonitriles), as the major reaction products in yields up to ca. 40–80%, and 6-aryl-4-arylethynyl-2-alkoxypyridines, as the minor reaction products in yields of 5–17%. Plausible mechanism of this complex and multistep reaction is discussed. The obtained pyridines possess fluorescent properties.     

中国与俄罗斯中学化学实验室安全规则设置的比较

通过对比中国与俄罗斯中学化学实验室安全规则的差异与共性,探讨中俄2国实验教学中对学生实验能力培养的价值取向,并分析了我国中学化学实验教学中存在的优点及不足,提出可行性的建议以优化我国化学实验教学。     

俄罗斯卫星通信技术的发展

作者根据不久前赴俄罗斯考察所获的第一手资料简述了俄罗斯卫星通信技术的发展过程,着重介绍了现在运行的“荧光屏”和“地平线”卫星系统以及正在研制的“快车”卫星。最后,还对俄罗斯卫星通信技术的优缺点进行了分析。