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101.
A concise total synthesis of 11-O-methyldebenzoyltashironin is reported in which oxidative dearomatization-IMDA-RCM triad constitutes the key ring forming steps, while an unorthodox DIBAL-H mediated stereo- and regioselective reductive epoxide openings and implementation of the vinyl bromide-carbonyl equivalency concept were pivotal to the success of this endeavor. 相似文献
102.
The hydrolytic ring opening reactions of pyromellitic dianhydride is an effective method to prepare transition metal carboxylate complexes. In this paper, two dinuclear complexes [Ni2(2,2′‐bipy)2(btec)(H2O)6] · 2H2O ( 1 ) and [Cd2 (phen)4(H2O)2(H2btec)] · H2btec · 2H2O ( 2 ) (H4btec = 1,2,4,5‐benzenetetracarboxylic acid, phen = 1,10‐phenanthroline, and 2,2′‐bipy = 2,2′‐bipyridine) were synthesized by slow diffusion methods and their structures were determined byX‐ray structure analysis. In both structures metal atoms are in distorted octahedral environments and they are linked by bis‐monodentately coordinated 1,2,4,5‐benzentetracarboxylate ligands as bridging units. The crystalline compounds, which are insoluble in water as well as common organic solvents, have been characterized in the solid‐state by elemental analysis, thermogravimetric analysis, IR, and diffuse reflectance UV/Visspectroscopy. Moreover, the study of the physical properties of complex 2 demonstrates that it exhibits blue fluorescence emission in the solid state at room temperature. 相似文献
103.
Karsten Krohn Ishtiaq Ahmed Dietmar Gehle Mohammed Al Sahli 《Journal of carbohydrate chemistry》2013,32(2):64-77
Chiral building blocks for macrolides and related natural products are obtained from 1,6-anhydrosugars by conversion of the bicyclic acetals 2 or 12 into the open chain chiral 1,3-dithianes 6 and 13. Branched precursors can be obtained by opening of the ?erný epoxide 1 with the 1,3-dithiane anion to yield 7, followed by ring opening with 1,3-propanedithiol to the bis-1,3-dithiane 8. 相似文献
104.
Given a multiplicative band of idempotents S in a ring R, for all e,f∈S the ∇-product e
∇
f=e+f+fe−efe−fef is an idempotent that lies roughly above e and f in R just as ef and fe lie roughly below e and f. In this paper we study ∇-bands in rings, that is, bands in rings that are closed under ∇, giving various criteria for ∇ to be associative, thus making the band a skew lattice. We also consider when a given band S in R generates a ∇-band. 相似文献
105.
Ryanodine is a potent calcium channel modulator. In this Letter, we report the 10-step synthesis of the highly substituted tricyclic ring system of ryanodine. Diels-Alder reaction via dearomatization of 2,5-dimethylbenzene-1,4-diol and subsequent SmI2-mediated reductive coupling of eight-membered 1,5-diketone efficiently introduced the four consecutive fully substituted carbons of the tricyclo[3.3.2.02,6]decane system. 相似文献
106.
A new preparative method for pyrido[2,3-b][1,4]oxazines from 6-substituted 3-nitro-2-pyridones is demonstrated. This method consists of two steps: O-alkylation and reductive cyclization. In the former step, the bulkiness of both starting nitropyridones and C2 reagents is found to be essential for avoiding N-alkylation, which undergoes O-alkylation efficiently. The subsequent reductive cyclization affords pyridoxazines with carbon substituents at both the 2- and the 6-positions that have not been available. 相似文献
107.
An efficient synthesis of 9,10-disubstituted phenanthrenes is described in this Letter. These novel useful building blocks were obtained in a one-pot reaction including Suzuki-Miyaura cross-coupling followed by a Dieckmann-Thorpe ring closure under microwave irradiation. The selection of the appropriate reagents and the optimal reaction conditions to isolate the intermediate biphenyl compound or the final substituted phenanthrenes in high yields will be discussed in this Letter. 相似文献
108.
109.
结合目前我国长途骨干传输网上主要电信运营商的传输网络的网络拓扑现状,对其网络保护方案进行了分析。 相似文献
110.
We present a theoretical investigation of optical bistability in a nonlinear semiconductor ring resonator, by taking into account the two-photon absorption and the free-carrier absorption. By solving the intensity equation within the ring resonator, a parametric formulation is obtained for describing the bistability relation between the input and the output intensities. Numerical results show that the nonlinear absorption effects can affect the critical points and domain of the optical bistability. 相似文献