全文获取类型
收费全文 | 595篇 |
免费 | 23篇 |
国内免费 | 3篇 |
专业分类
化学 | 361篇 |
力学 | 13篇 |
数学 | 52篇 |
物理学 | 64篇 |
无线电 | 131篇 |
出版年
2023年 | 6篇 |
2022年 | 8篇 |
2021年 | 7篇 |
2020年 | 15篇 |
2019年 | 2篇 |
2018年 | 6篇 |
2017年 | 15篇 |
2016年 | 9篇 |
2015年 | 9篇 |
2014年 | 31篇 |
2013年 | 33篇 |
2012年 | 35篇 |
2011年 | 28篇 |
2010年 | 18篇 |
2009年 | 43篇 |
2008年 | 40篇 |
2007年 | 60篇 |
2006年 | 32篇 |
2005年 | 21篇 |
2004年 | 52篇 |
2003年 | 30篇 |
2002年 | 21篇 |
2001年 | 14篇 |
2000年 | 13篇 |
1999年 | 14篇 |
1998年 | 15篇 |
1997年 | 15篇 |
1996年 | 9篇 |
1995年 | 8篇 |
1994年 | 3篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有621条查询结果,搜索用时 15 毫秒
481.
482.
通过建立检漏结果不确定度的评定模型,应用蒙特卡罗方法对检漏数据进行随机模拟,获得了各输入量的随机样本,计算了检漏结果的不确定度,并与传统评定方法得到的不确定度进行了比较和分析。研究表明,两种方法计算得到的不确定度一致,说明蒙特卡罗方法可以作为评定氦质谱检漏结果不确定度的有效方法,且蒙特卡罗评定方法计算效率更高,应用范围更广。 相似文献
483.
Lott S Henrion A Malz F Kessler A Güttler B Aderjan R 《Analytical and bioanalytical chemistry》2008,391(3):1003-1010
An isotope dilution gas chromatography/mass spectrometry (ID-GC/MS) reference measurement procedure for Δ9-tetrahydrocannabinol
(THC) in serum was developed and validated. The method complies with the concept of a ratio primary reference measurement
procedure. The uncertainty was determined for two concentrations of THC in serum (1 ng/mL and 2.4 ng/mL). The calculation
procedure is based on the Guide to the Expression of Uncertainty in Measurement (GUM). The relative expanded uncertainty was found to be less than 2% for both concentration levels, corresponding to a 95%
confidence interval. For the reference method, it was shown that the measurement of THC within the concentration range covered
by the current threshold values is very accurate. The method has the potential to provide traceability for the methods used
in practical forensics. 相似文献
484.
Thin-walled pressure vessels are widely used in modern industry. It is important to measure pressure of the vessels. It has been proved that the velocity of ultrasonic propagation in the material could be affected by the stresses applied to it. The pressure measurement should consider the effect of temperature as the velocity of ultrasonic is affected by the temperature and thermo-stress is produced in the vessels wall. Furthermore, the propagation distance of ultrasonic is influenced by thermal deformation due to temperature changes. In consideration of these influencing factors, a modified model of pressure measurement has been developed, and according to this model, a reference method for the temperature compensation is presented. The relationship between the time delay and pressure was established through this method. The correlative time estimation method based on Hilbert-Huang Transform is presented to estimate the time delay. Therefore, a new method for measuring the pressure of thin-walled vessels nondestructively is presented. Two vessels made of different kinds of materials were used as specimens in our experiments. The results obtain from the tests are used to validate the modified model and demonstrate that the reference method is effective. 相似文献
485.
486.
以电解法制备的MnO2粉体为原料,研制了可用于混凝土环境中的固体MnO2长效参比电极. 在饱和Ca(OH)2溶液中近一年的监测数据显示,该参比电极具有较好的电位稳定性和抗干扰能力,其电极电位的漂移< 10 mV. EIS和极化曲线测试结果表明,相对于化学法合成的MnO2电极,电解法制备的MnO2参比电极具有较小的内阻、较大的交换电流密度、较强的抗极化能力和较低的温度系数(~ 0.68 mV·°C-1). 在硬化砂浆中的长期测试表明,该电极在混凝土中的电极电位基本不受Cl-、有机胺阻锈剂的影响,能作为埋入式参比电极,满足混凝土中Cl-浓度、pH值和钢筋半电池电位的长期监测的要求,这对于海洋混凝土工程的耐久性监测具有较高的应用价值. 相似文献
487.
江泓 《中国无机分析化学》2022,12(3):1-6
本文提出用计算机模拟取样对不同的取样量重复进行测试多次,统计其检测结果的标准偏差,做出标准偏差s对取样量m的拟合曲线,再计算最小取样量。设计的模式是一颗一颗地取样,这样不存在取样操作及测试过程带来的误差,操作是可行的,结果是可靠的。计算机运算速度快,参数转换方便,也可以取毫克甚至亚毫克样进行实验。只要有足够的岩矿鉴定的资料,可以模拟不同状态下的样品取样过程。 相似文献
488.
I. Papadakis E. Vendelbo L. Van Nevel P. D. P. Taylor 《Accreditation and quality assurance》2001,6(12):507-513
For the first time in the International Measurement Evaluation Programme (IMEP)-14, a sediment sample was offered to analytical
laboratories to perform measurements of As, Cd, Cr, Cu, Fe, Pb, Hg, Ni, U and Zn. In line with IMEP policy, the results were
presented according to the certified / assigned reference values established by several reference laboratories around the
world. The certification campaign is described in detail. Isotope dilution mass spectrometry was applied as a primary method
of measurement, whenever possible, to achieve SI-traceable results. For reference measurements of As, Fe, Hg and Zn, k0-neutron activation analysis and Zeeman atomic absorption spectrometry were applied. The reference values (ranges) were characterised
as ”certified” (for Cd, Cr, Pb, Ni and U) or ”assigned” (for As, Cu, Fe, Hg and Zn) according to IMEP policy. The measurement
uncertainty of the certified / assured reference values was calculated according to the ISO/BIPM Guide.
Received: 7 June 2001-10-27 Accepted: 19 August 2001 相似文献
489.
490.