The availability and application of solid-state reference electrodes for potentiometric electrochemical sensors are briefly
reviewed. For a long time, considerable efforts have been made to combine solid-state indicator electrodes with equivalent
reference electrodes to take advantage of the absence of liquid system components to full capacity. In spite of various suggestions
to solve the problem, no type of solid-state reference electrode is so far available with properties completely identical
to conventional ones. 相似文献
A procedure for an all-plastic electrochemical cell comprising miniaturized planar indicator and reference electrodes is described.
All electrodes are based on conducting polymers, are fully integrated, and contain no internal electrolyte. The reference
microsensors were deposited via electrochemical polymerization from a water solution containing the monomer 3,4-ethylenedioxythiophene
(EDOT) or 1-methylpyrrole (MPy) and a biochemical buffer 3-(N-morpholino) propanesulfonic acid [MOPS], 2-(N-morpholino) ethanesulfonic acid [MES], or 2-hydroxy-5-sulfobenzoic acid [SSA]). Ion-sensitive microelectrodes were prepared
by the deposition of the ion-sensitive membrane solution (Ca2+, K+, and Cl−) directly onto the mediating poly-EDOT (PEDOT), PEDOT–SSA, PEDOT–MES, PEDOT–MOPS, or poly-MPy–MOPS layers. 相似文献
Aimed at better modeling insurance claims in an economic environment driven by business cycles, a new Markov-modulated Poisson process model is proposed, and an algorithm is derived to estimate the hidden Markov process by using the observed information. Our method differs from existing ones in the following ways: the new hidden process can model more efficiently the cyclic state of the economic environment; our theory is based on a variation of the law of large numbers and is easy to understand; the Fourier expansion-based parameter estimation algorithm is flexible and can be more easily implemented than other algorithms. Simulation results not only demonstrate the practicality of our model and algorithm, but also show the efficiency and robustness of the estimation algorithm. 相似文献
Proficiency data with stated uncertainties represent a unique opportunity for testing that the reported uncertainties are consistent with the Guide to the expression of uncertainty in measurement (GUM). In most proficiency tests, however, this opportunity is forfeited, because proficiency data are processed without regard to their uncertainties. In this paper we present alternative approaches for determining a reference value as the weighted mean of all mutually consistent results and their stated uncertainties. Using an accepted reference value each reported uncertainty estimate can be expressed as an En number, but a value of confirms its validity only if the uncertainty of the reference value is negligible in comparison.Reference values calculated for results from an International Measurement Evaluation Programme (IMEP-9) by “bottom up” as well as “top down” methods were practically identical, although the first strategy yielded the lowest uncertainty. A plot of individual coefficients of variation (CV) versus En numbers helps interpretation of the proficiency data, which could be used to validate relative uncertainties down to <1%. 相似文献
The novel approach using a slope of correlation line (laser-enhanced ionization of lithium versus laser-induced plasma emission of aluminum) as analytical signal was proposed for reduction of matrix interferences in laser-enhanced ionization spectrometric determination of Li with laser sampling. 相似文献
A 1 V, programmable, accurate, high speed, single-ended charge pump is proposed, suitable for low voltage PLLs. It is designed in TSMC 90-nm digital CMOS process and it consists of four switches in a current steering configuration, a unity gain rail to rail buffer for the charge sharing effect elimination, one more rail to rail amplifier for minimizing the DC current mismatch, a programmable current bias circuitry and two drivers based on the standard cell XOR gates specific configuration for achieving good synchronization between all charge pump input pulses at the PLL lock state. Replica biasing technique is applied to all charge pump switches. Current glitches and charge mismatch are suppressed by employing a mechanism with additional switches at the output. It exhibits a maximum DC current mismatch of 1% and charge mismatch of 6% over a wide output voltage range of 0.7 V for the entire range of output currents. The wide range of the output voltage remains relatively constant and independent of the selected charge pump current amplitude. This is attained by applying appropriate variation of the W/L ratios of the bias cascode current sources via the employment of additional programmable switches such that their saturation voltages remain relatively constant, something which in turn enables the output currents range to be as wide as it is required. 相似文献