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991.
992.
993.
A kind of biodegradable material, poly(ɛ-caprolactone-co-lactic acid) [P(CL-co-LA)] was synthesized via the direct melting polycondensation of lactic acid (LA) and ɛ-caprolactone (CL). The influences
of the polycondensation time, and the catalyst type on the intrinsic viscosity of P(CL-co-LA) were also investigated. The results indicate that P(CL-co-dl-LA), with an intrinsic viscosity of 0.4733 dL/g, can be prepared by direct melting polycondensation with the molar ratio
LA/CL = 3:7 at 180°C and 70 Pa for 12 h, using 0.5% (mass fraction) of SnCl2 as the catalyst. Compared with lactide ring-opening polycondensation (ROP), the direct melting polycondensation of LA and
CL is more practicable and simple.
Translated from Journal of South China University of Technology, 2006, 34(7): 7–11 (in Chinese) 相似文献
994.
I. K. Battisha A. El Beyally S. Abd El Mongy A. M. Nahrawi 《Journal of Sol-Gel Science and Technology》2007,41(2):129-137
Structural characteristics of pure silica gel (silica-xerogel, SiO2) and silica gel doped with some rare earth elements (REEs) such as, praseodymium Pr3+, and Europium Eu3+, Erbium Er3+ and Holmium Ho3+ ions, with different concentrations ranging from 1 up to 6%, in the form of monolith materials were prepared by sol-gel technique,
Using tetra-ethoxysilane as precursor materials, which are of particular interest for sol-gel integrated optics applications.
Some structural features of sol-gel derived monolith are analyzed, namely the structure of nano-particle momolith samples,
based on X-ray diffraction (XRD) and Fourier Transform Infrared (FTIR). We show that the XRD spectra of α-crystobalite are
obtained for the pure samples at 1100°C and even by doping with the four REEs ions. 相似文献
995.
Himansu Sekhar Sahoo S. Mahalakshmi Md. Hedayetullah Mir R. Raghunathan 《Tetrahedron letters》2007,48(5):761-765
A remarkable upfield shift of the pyα protons of complexed 2,2′-bipyridine in [cis-Pd(bpy)(NO3)2] is observed which is considered to originate from the anisotropic influence of suitably positioned coordinated nitrate anions around the Pd(II) centre of the molecule. A typical complexation-induced downfield shift is observed for the NH2 protons in [cis-Pd(en)(NO3)2] where ‘en’ stands for ethylenediamine. 相似文献
996.
(R)-4-Menthenone in the synthesis of optically pure sex pheromone of the peach leafminer moth (Lyonetia clerkella) 总被引:1,自引:0,他引:1
Kharisov R. Ya. Latypova E. R. Talipov R. F. Muslukhov R. R. Ishmuratov G. Yu. Tolstikov G. A. 《Russian Chemical Bulletin》2003,52(10):2267-2269
The synthesis of (14S)-methyloctadec-1-ene, sex pheromone of the peach leafminer moth (Lyonetia clerkella), is described to demonstrate a new potential of the synthetic use of (R)-4-menthenone. 相似文献
997.
A. N. Chekhlov 《Journal of Structural Chemistry》2005,46(1):182-184
The crystal and molecular structure of tris(m-chlorophenyl)phosphine selenide, C18H12Cl3PSe (I), was investigated by X-ray diffraction (XRD) analysis. The trigonal rhombohedral structure of I (space group \(R\overline 3 c\), a = 14.110(2) Å, c = 32.360(4) Å, Z = 12) was solved by direct methods and refined by least squares in an anisotropic approximation (R = 0.029) for 1319 averaged measured reflections (CAD-4 automatic diffractometer, λCuKα). 相似文献
998.
999.
Simple two-parameter Hückel and Pitzer equations were used for the calculation of the activity coefficients of aqueous hydrochloric acid at 25°C up to a molality of 2.0 mol-kg–1. The data obtained by Harned and Ehlers(12,13) from galvanic cells without liquid junction were used in the analysis and the parameters obtained were compared to those obtained from all reliable data presented in the literature for HCl at this temperature. A good agreement between the parameters was always observed. The activity coefficients obtained by the new equations were compared to those suggested by Robinson and Stokes,(8) Hamer and Wu,(1) and Pitzer and Mayorga,(9) and good agreement was also found. The data from the most important literature data sets for HCl were also predicted using the new activity coefficient equations, and the magnitude of the resulting errors was close to the precision of the measurements, the errors forming an almost random pattern for all data sets. 相似文献
1000.
低氧条件下,钴(Ⅲ)的氮芥配合物具有合适的还原电位,就可能还原得到比较活泼的Co(Ⅱ)配合物,在溶液中其活性配体很快被体内的小分子取代,释放出的活性配体可以杀死低氧区内外的癌细胞,因此筛选合适的钴配合物作为低氧选择性抗癌药物的研究很有意义。本文以双 (2 氯乙基)胺(简称BCA)为活性配体,取代乙酰丙酮为辅助配体,合成一系列Co(Ⅲ)配合物(下图)。初步评估结果表明,其中两个配合物具有一定的低氧选择性,配合物的还原电位对药物的低氧选择性影响很大,合适的还原范围可能比较窄。1 实验部分1.1 试剂与仪器按文献[1]的方法合成… 相似文献