1477 nm LD泵浦掺铒光纤放大器的研究

报道了采用１４７７ｎｍ激光二极管（ＬＤ）泵浦的掺铒光纤放大器的实验结果。研究了放大器的增益和时域特性。对１５２０ｎｍ的信号光，获得了２３ｄＢ的增益，泵浦效率为２．２８ｄＢ／ｍＷ。低频脉冲信号经过放大器后未发生波形畸变。     

锥形有源条半导体光放大器增益和饱和特性分析

以行波半导体光放大器速度方程为基础，采用传输矩阵方法，对锥形结构半导体光放大器的增益和饱和特性进行理论研究。讨论了不同锥形长度，不同结构时的增益和饱和特性差异。理论研究表明，锥形结构能改善半导体光放大器的偏振灵敏度。在同一锥度下，长锥形长度能提高饱和增益，降低偏振度。在进行半导体光放大器有源条结构设计时要综合考虑锥度及锥形长度的影响，以实现结构优化 。     

最新水冷式全固态数字调幅600kW中波发射机

数字调幅制式是当前国际上较先进的调制技术，ＤＸ系列全固态数字调幅中波发射机的电声指标和工业效率都是很先进的，过去的ＤＸ大功率机采用风冷方式，本文介绍了最新水冷ＤＸ－６００发射机的设备情况和技术特点。     

分子束外延生长CdTe／ZnTe超晶格室温喇曼散射

首次报道了室温和非共振条件下,分子束外延(MBE)生长的CdTe/ZnTe超晶格的喇曼散射测量和分析。观察到最低级次的CdTe和ZnTe纵光学声子限制模,并用应力和限制效应精确计算了频移,得到的ZnTe纵光学声子频移理论值与实验结果符合得较好。特别指出,当CdTe和ZnTe层厚小于2nm时,声子频移的限制效应不可忽略,对所测样品的喇曼全谱作了分析。     

Interdiffusion of hydroxyl groups and of doping additions between a bearing pipe and a deposited layer in billets of fiber light guides

Using Raman spectroscopy, a quantitative analysis of the distribution of OH⁻ ions on the boundary between a bearing pipe and a glass layer deposited from chlorides in billets for quartz fiber light guides is carried out. Water penetrated into the light-reflecting shell to a depth of several tenths of a millimeter, depending on the composition of the doping layer (i.e., ultimately on the temperature of the depsoition process). A. F. Ioffe Physical-Technical Institute, Academy of Sciences of Russia, 26, Politekhnicheskaya St., St. Petersburg, 194021, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 4, pp. 548–550, July–August, 1997.     

转动喇曼散射截面的群论计算

本文利用群链U(4)U(3)O(3)描述双原子分子N_2和O_2振转谱的对称性质,并利用群论方法计算了N_2和O_2分子转动喇曼散射的跃迁矩阵元,给出了它们的转动喇曼散射的截面。结果与实验较好地符合。     

利用喇曼光谱测量氧碘化学激光器氯气利用率的实验研究

 介绍了利用自发喇曼散射光谱测量氧碘化学激光器单态氧发生器氯气利用率的原理及实验装置，并给出了在以氮气作为稀释气的0.1mol/s射流式氧发生器上测试的结果，测试相对误差小于12%。由于该方法只需要通过测量喇曼谱线相对强度之比，即可算出氯的利用率，因此不需要另外的标定实验，从而避免了因标定带来的影响。该方法减小了测试误差，简化了实验过程，提高了测试效率。     

Electronic structure and vibrational spectra of cis-diammine(orotato)platinum(II), a potential cisplatin analogue: DFT and experimental study

Orotic acid (vitamin B₁₃) is a key intermediate in biosynthesis of the pyrimidine nucleotides in living organisms, moreover, it may serve as the biological carrier for some metal ions. cis-Diammine(orotato)platinum(II), cis-[Pt(C₅H₂N₂O₄)(NH₃)₂] can be considered as a new potential cisplatin analogue. The FT-Raman and FT-IR spectra of the title complex are reported, for the first time. The molecular structure, vibrational frequencies, and the theoretical infrared and Raman intensities have been calculated by the density functional mPW1PW91 method. The detailed vibrational assignment has been made on the basis of the calculated potential energy distribution. The theoretically predicted IR and Raman spectra show very good agreement with experiment. Natural bond orbital (NBO) analyses were performed for cisplatin, carboplatin and the title complex. The results provided new data on the nature of platinum–ligand bonding in these compounds. Strong intramolecular hydrogen bond between the orotate ligand and the coordinated ammonia group stabilizes the structure of the platinum(II) complex. Thus, it is suggested that the orotate ligand in the title complex is more inert to the substitution reactions than the chloride ligands in cisplatin.     

CARS光谱测温及仪器狭缝函数对测量的影响

设计了一种利用光参量振荡器(OPO)来代替染料激光器的宽带相干反斯托克斯喇曼散射(CARS)光谱测温实验装置。为了提高CARS测量温度的精度,测量和分析了检测系统中狭缝函数对测量结果的影响,确定了狭缝函数的具体形式。将测量结果与热电偶读数比较,发现在温度范围300K～1200K内,温度测量的不确定度小于2%。     

掺杂对碳纳米管拉曼光谱及场发射性能的影响

采用高温热解法在860℃分别制备出了镓、氮以及硼和氮掺杂的碳纳米管,提纯后利用丝网印刷工艺分别将它们制备成薄膜,并测试了它们的拉曼光谱与场发射性能。测试结果表明,掺杂纳米管的缺陷密集度比纯碳纳米管明显增大,而它们的场致电子发射性能则与掺杂元素的性质密切相关。镓和氮掺杂的纳米管均具有非常优异的场发射性能,而硼和氮共掺杂的纳米管的场发射性能很差。掺杂引起碳纳米管费米能级附近能态密度的变化及功函数的降低是其具有优异场致电子发射性能的主要原因。