无催化纳米氧化锌的制备及其光学性质研究

本文采用无催化剂直接蒸发高纯Zn粉,在800℃氧气氛条件下,在Si(111)衬底上生长得到以四角状为主的纳米ZnO(T-ZnO)。T-ZnO纳米线每个角约互成110°,长度约为1.5μm,直径100nm左右;Raman分析表明E2(H)普遍存在于各形态的ZnO;光致发光光谱表明,T-ZnO纳米线的光致发光除了与材料性质有关,还与杂质缺陷有关,蓝绿光带是ZnO的缺陷产生的。     

傅里叶变换红外光谱与拉曼光谱分析碳青霉烯药物亚胺培南的结构特征

本文采用傅里叶变换红外光谱和激光拉曼光谱对碳青霉烯药物亚胺培南进行光谱检测,并对其的分子振动光谱与结构特征进行分析和探讨,分析了亚胺培南在固相状态下的结构形式,从而为药物合成及质量控制提供了重要的参考价值。     

A high-pressure Raman and X-ray diffraction study of the perovskite SrCeO3

A high-pressure structural study of SrCeO₃ has been performed at room temperature by Raman spectroscopy and X-ray diffraction up to 32 and 45 GPa, respectively. A first-order reversible phase transition is observed at about 12 GPa in both techniques. A second weak structural change, taking place between 18 and 25 GPa, can be suspected from Raman data. The increase in the number of Raman bands and diffraction lines is an indication that the symmetry is lowered and the compound does not evolve towards the ideal cubic perovskite structure. A Rietveld analysis of X-ray data was performed for the low-pressure phase and the atomic positions and the cell lattice parameters variations are reported in this paper. The volume compressibility derived from Raman modes (5.6×10⁻¹² Pa⁻¹), involving mainly bond-stretching for each type of polyhedron, is found to be close to the one obtained from volume cell variations measured by X-ray diffraction (7.9×10⁻¹² Pa⁻¹).     

混杂配体金属簇合物的分子振动光谱与结构

由于原子簇化合物在催化，生物活性，功能材料等方面所呈现的重要性，使其成为无机和物理化学最重要的研究领域之一。文章中和谱学方法对一些具有混配体的过渡金属簇合物的结构及其两者之间的关系进行.     

Vibrational spectra of (NH4)3ZnCl5

IR and Raman spectra of (NH₄)₃ZnCl₅ have been recorded. The observed spectra have been analysed on the basis of the vibrations of ZnCl ₄ ²⁻ and NH ₄ ⁺ ions. The appearance of multiple Raman bands indicates the presence of two different types of ammonium ions. The effect of anisotropic crystalline field over the ZnCl₄ and NH₄ tetrahedra is also discussed. The assignment of internal modes has been verified by the potential energy distribution calculations.     

Self-organized ZnAl2O4 nanostructures grown on -sapphire

Self-organized ZnAl₂O₄ nanostructures with the appearance (in SEM) of high aspect ratio horizontal nanowires are grown on uncatalysed c-sapphire by vapour phase transport. The nanostructures grow as three equivalent crystallographic variants on c-sapphire. Raman and cathodoluminescence spectroscopy confirm that the nanostructures are not ZnO and TEM shows that they are the cubic spinel, zinc aluminate, ZnAl₂O₄, formed by the reaction of Zn and O with the sapphire substrate.     

广义米理论及其在粒度分析中的应用

有形波束的散射问题在粒度分析测量仪器的研究中有着特殊重要的意义，本文介绍了处理均匀球形粒子对有形波束散射的广义米理论，并应用该理论研究了双柱形激光波束粒子测量系统的散射问题，与未理论和几何光学相比，其结果与实验吻合很好。     

改进的FD—TD法分析二维理想导体TM近区散射问题

本文针对一般ＦＤ－ＴＤ方法分析计算二维理想导体散射问题所遇到散射体边角处难以精确处理的缺点进行了改进。将边角处总场近似解析解直接引入ＦＤ－ＴＤ法差分公式，得到了有关修正系数，为了检验此方法的有效性，有无限长导体方柱为例分别用一般ＦＤ－ＴＤ法和本文的ＦＤ－ＴＤ方法进行了分析研究，并与ＭＯＭ法进行了比较，所得结果说明改进后的ＦＤ－ＴＤ方法对分析计算导体边角附近电流分布特性是较有效的。     

光纤喇曼放大器的功率转换效率分析

在定义光纤喇曼放大器(FRA)功率转换效率(PCE)的基础上,考察了不同工作条件下光纤喇曼放大器的功率转换效率,分析PCE与光纤喇曼放大器的输入信号功率、输入泵浦功率和光纤长度的关系,比较了分布式与集总式FRA的功率转换效率,给出提高FRA功率转换效率的途径。     

Modification to the Fringe Component of Diffraction Coefficient in TD-EEC Method

A modified formulation for fringe component of diffraction coefficient is implemented to TD-EEC method. An example of diffraction by perfectly conducting plate is used to illustrate our scheme. Comparing with the FDTD results we observe that the improved expression for fringe component is more accurate than that of Michaeli's formulation. This high frequency time domain technique is available for treating the bistatic scattering problems for millimeter waves.