Highly Sensitive AdSV Method for Fe(III) Determination in Presence of Solochrome Violet RS on Renewable Amalgam Film Electrode

The new DP AdSV method for high sensitive Fe(III) determination in the presence of Solochrome Violet RS was developed. The use of an innovative renewable amalgam film electrode Hg(Ag)FE allowed to obtain high sensitivity and significantly minimize the mercury consumption. The best results were obtained for surface area of Hg(Ag)FE equal to 11.8 mm². Instrumental parameters were optimized. The optimal results were obtained using differential pulse technique for the following values: sampling and waiting time ts=tw=10 ms, step potential Es=5 mV, pulse amplitude ΔE=50 mV. Measurements were conducted in 0.05 M acetate buffer (pH 5.6), the concentration of SVRS was equal to 5 μM. Deposition step was carried out at the potential ?400 mV for 20 s. Calculated detection limit for 40 s preconcentration time was equal to 1.4 nM (78 ng L^?1). The influence of the common in environment, organic and inorganic interferences was studied. The developed method for Fe(III) determination was successfully applied and validated by investigation of certified reference material SPS‐SW2 Batch 118 and recovery of Fe(III) from various spiked samples as snow, tap water and bottom sediments. The repeatability (for 50 nM of Fe(III)) of the developed method expressed as CV was equal 3.1 % (n=5).     

Optimising the Termofluids CFD code for petascale simulations

ABSTRACT

This paper presents some recent efforts carried out on the expansion of the scalability of TermoFluids multi-physics Computational Fluid Dynamics (CFD) code, aiming to achieve petascale capacity for a single simulation. We describe different aspects that we have improved in our code in order to efficiently run it on 131,072 CPU-cores. This work has been developed using the BlueGene/Q Mira supercomputer of the Argonne Leadership Computing Facility, where we have obtained feedback at the targeted scale. In summary, this is a practical paper showing our experience at reaching the petascale paradigm for a single simulation with TermoFluids.     

叠加训练序列设计及其高效传输技术研究

采用训练序列与信息数据叠加的传输方案由于消除训练序列占用的频带开销而受到广泛关注。然而,如何高效的分离叠加信号是实现高效信道估计和可靠检测的基础。通过叠加周期训练序列,研究了基于数据依赖的叠加训练(DDST)方案的高效信道估计和检测方案。并结合信道编码技术,研究了编码条件下DDST方案与传统时分复用(TDM)方案的性能。仿真结果表明,在消除训练带宽开销的情况下,获得DDST方案与TDM的误码率基本保持一致。     

DS-SS/EBPSK调制的码分多址研究

为了实现直序扩频扩展的二元相移键控(DS-SS/EBPSK)调制的多址通信,研究了一种DS-SS/EBPSK调制的码分多址实现方法.首先对DS-SS/EBPSK调制信号进行分析,公式化表述了DS-SS/EBPSK的调制过程,得到了可用于解扩和码分多址的等效扩频序列;在此基础上,设计了相关接收机对DS-SS/EBPSK调制信号进行检测,利用不同用户扩频序列互相关很小的特点实现多址传输;最后以m序列为例,仿真了期望用户的误码性能与用户数量和m序列周期长度的关系.仿真结果验证了此种码分多址实现方式的可行性,同时也表明多用户的于扰程度取决于扩频序列之间的互相关性.     

多跳相干探测光谱幅度码标记交换系统传输特性分析

提出了一种基于标记栈技术的两跳相干探测光谱幅度码(SAC)标记交换系统.利用仿真软件,搭建了包含两个转发节点、两个156 Mb/s光谱幅度码标记、与40 Gb/s差分正交相移键控(DQPSK)净荷的光标记交换系统.利用接收光功率与光信噪比(OSNR)分析系统传输性能,并得到结论:经两个节点传输后,标记与净荷产生的功率代价与OSNR代价均未超过3 dB.     

北斗二号B1信号捕获方法研究

为了缩短北斗B1信号的捕获时间,提高多普勒频率和码相位的估计精度,针对北斗NH码对差分相干累积值的影响,改进了广义差分相干累积捕获方法。并采用二次频率-码相位捕获法来提高载波多普勒频率和码相位的估计精度。理论分析与仿真实验表明,改进的广义差分相干累积法能够克服NH码的影响。用4个1ms的相干累积值,改进的广义差分法可成功捕获信噪比为-27dB的信号。最后,用实测的北斗数据验证了算法的正确性。