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141.
JIA Zhen-hong 《半导体光子学与技术》2006,12(1):18-20,42
Two-layer structure consisting of PS/PMMA-DR1 composite film planar waveguide layer on porous silicon cladding layer was fabricated in our experiment. The induced grating based on the third nonlinear optical properties was formed by interaction of two Nd : YAG laser beams at 1 064 nm in the porous silicon/PMMA-DR1 waveguide. The diffraction efficiency of the first order diffracted light is measured to be about 0.2% of the total output. 相似文献
142.
In this work, porous graphite nanofibers (PGNFs) were manufactured as promising catalyst supporter by a physical activation method for direct methanol fuel cells, and Pt nanoparticles were loaded on the PGNFs in order to prepare electrode materials by a chemical reduction method. The pore structures of the Pt/PGNFs were analyzed by N2 adsorption isotherms at 77 K. Electrocatalytic activities of final products were investigated by voltammetry and conductivity measurements in a 1.0 M CH3OH/0.5 M H2SO4. As a result, electrocatalytic activities of Pt/PGNFs were increased in the presence of Pt particles on the PGNFs and with increasing the specific surface area of the carbons. 相似文献
143.
Partially oxidized free-standing porous silicon films show a strongly superlinear increase in photoluminescence (PL) intensity above a threshold cw excitation intensity of 10 W/cm2. The PL-intensity increase can be expressed by a power law with n9 as a function of the excitation intensity. The PL-peak wavelength of this emission is slightly redshifted from that at low-excitation levels. These changes are fully reversible and reproducible, but not observed in samples on substrate. We attribute this behavior to thermal reexcitation of carriers trapped at the dangling bond states in initially nonluminescent Si nanocrystallites. 相似文献
144.
145.
Welch K Mousavi S Lundberg B Strømme M 《The European physical journal. E, Soft matter》2005,18(1):105-112
A newly developed method for determining the frequency-dependent complex Young's modulus was employed to analyze the mechanical
response of compacted microcrystalline cellulose, sorbitol, ethyl cellulose and starch for frequencies up to 20 kHz. A Debye-like
relaxation was observed in all the studied pharmaceutical excipient materials and a comparison with corresponding dielectric
spectroscopy data was made. The location in frequency of the relaxation peak was shown to correlate to the measured tensile
strength of the tablets, and the relaxation was interpreted as the vibrational response of the interparticle hydrogen and
van der Waals bindings in the tablets. Further, the measured relaxation strength, holding information about the energy loss
involved in the relaxation processes, showed that the weakest material in terms of tensile strength, starch, is the material
among the four tested ones that is able to absorb the most energy within its structure when exposed to external perturbations
inducing vibrations in the studied frequency range. The results indicate that mechanical relaxation analysis performed over
relatively broad frequency ranges should be useful for predicting material properties of importance for the functionality
of a material in applications such as, e.g., drug delivery, drug storage and handling, and also for clarifying the origin of hitherto unexplained molecular processes. 相似文献
146.
Song YQ Hürlimann MD Flaum C 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,161(2):222-233
This paper describes a method to determine molecular displacements as a function of time in just two scans: one reference scan using the Carr-Purcell-Meiboom-Gill (CPMG) sequence, a second scan using a modified CPMG sequence (KCPMG). Measurements on free diffusion in bulk fluids, and on restricted diffusion in porous rock samples are reported. This technique can also be used for rapid measurement of flow and chemical exchange. 相似文献
147.
N. Sankara Subramanian R. Vivek Sabaapathy P. Vickraman G. Vimal Kumar R. Sriram B. Santhi 《Ionics》2007,13(5):323-328
P-type porous silicon (PS) structure has been prepared by anodic electrochemical etching process under optimized conditions.
Photoluminescence studies of the PS structure show emission at longer wavelengths (red) for the excitation at 365 nm. Scanning
electron microscope investigations of the PS surface confirm the formation of uniform porous structure, and the pore diameter
have been estimated as 25 μm. Pd:SnO2/PS/p-Si heterojunction with top gold ohmic contact developed by conventional methods has been used as the sensor device.
Sensing properties of the device towards liquefied petroleum gas (LPG) and NO2 gas have been investigated in an indigenously developed sensor test rig. The response and recovery characteristics of the
sensor device at different operating temperatures show short response time for LPG. From the studies, maximum sensitivity
and optimum operating temperature of the device towards LPG and NO2 gas sensing has been estimated as 69% at 180 °C and 52% at 220 °C, respectively. The developed sensor device shows a short
response time of 25 and 57 s for sensing LPG and NO2 gases, respectively.
Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006. 相似文献
148.
This paper introduces a relative structural complexity measure for the characterization of disordered surfaces. Numerical solutions of 2d+1 KPZ equation and scanning force microscopy (SFM) patterns of porous silicon samples are analyzed using this methodology. The results and phenomenological interpretation indicate that the proposed measure is efficient for quantitatively characterize the structural complexity of disordered surfaces (and interfaces) observed and/or simulated in nano, micro and ordinary scales. 相似文献
149.
Graft polymerization of acrylic acid (AA) onto porous polyethersulfone (PES) membrane surfaces was developed using corona discharge in atmospheric ambience as an activation process followed by polymerization of AA in aqueous solution. The effects of the corona parameters and graft polymerization conditions on grafting yield (GY) of AA were investigated. The grafting of AA on the PES membranes was confirmed by ATR-FTIR and X-ray photoelectron spectroscopy (XPS) analysis. Porosimetry measurements indicate the average pore diameters and porosities of the modified membranes decrease with the increase of the GY. The hydrophilicity and surface wetting properties of the original and modified membranes were evaluated by observing the dynamic changes of water contact angles. It is found that the grafting of AA occurs not only on the membrane surfaces, but also on the pore walls of the cells inside the membrane. The permeability experiments of protein solution reveal that the grafting of PAA endows the modified membranes with enhanced fluxes and anti-fouling properties. The optimized GY of AA is in the range of 150-200 μg/cm2. In addition, the tensile experiments show the corona discharge treatment with the power lower than 150 W yields little damage to the mechanical strength of the membranes. 相似文献
150.
R. Cristescu A. Doraiswamy G. Socol E. Axente R.J. Narayan A. Moldovan I.N. Mihailescu D.B. Chrisey 《Applied Surface Science》2007,253(19):7702-7706
We report the successful deposition of the porous polymer poly(d,l-lactide) by matrix assisted pulsed laser evaporation (MAPLE) using a KrF* excimer laser (248 nm, τ = 7 ns) operated at 2 Hz repetition rate. The chemical structure of the starting materials was preserved in the resulting thin films. Fluence played a key role in optimizing our depositions of the polymer. We demonstrated MAPLE was able to improve current approaches to grow high quality thin films of poly(d,l-lactide), including a porosity control highly required in targeted drug delivery. 相似文献