Consolidation around a borehole embedded in media with double porosity under release of geostatic stresses

The paper deals with the stress, displacement, pore and fissure pressures fields induced by the drilling and/or the pressurization of a vertical borehole in a formation of water-saturated porous media with double porosity. The solution includes the boundary condition of non-hydrostatic in situ state of stress. The solid skeleton is assumed to behave as a linearly poroelastic material with compressible constituents. The analytical solution is derived in Laplace’s space and transformed to the time domain using a numerical inversion technique. The histories of pore and fissure pressures are illustrated to show the influence of permeabilities of the pore and fissure systems.     

Domain decomposition for an asymptotic geological fault modeling

We present in this paper a domain decomposition method to treat faults in geological basin modeling. The particularity of this model is that the faults whose widths are very small in comparison with the basin size, are not characterized as subdomains any more but as interfaces between sedimentary blocks. The originality of this work lies in the formulation of this new fault model and in the definition and the computation of the interface conditions between the subdomains. To cite this article: E. Flauraud et al., C. R. Mecanique 331 (2003).     

Existence of a solution for two phase flow in porous media: The case that the porosity depends on the pressure

In this paper we prove the existence of a solution of a coupled system involving a two phase incompressible flow in the ground and the mechanical deformation of the porous medium where the porosity is a function of the global pressure. The model is strongly coupled and involves a nonlinear degenerate parabolic equation. In order to show the existence of a weak solution, we consider a sequence of related uniformly parabolic problems and apply the Schauder fixed point theorem to show that they possess a classical solution. We then prove the relative compactness of sequences of solutions by means of the Fréchet-Kolmogorov theorem; this yields the convergence of a subsequence to a weak solution of the parabolic system.     

Catalytic partial oxidation of methane using RhSr- and Ni-substituted hexaaluminates

This paper reports the results of experimental and modeling efforts to characterize partial oxidation of methane to produce synthesis gas (H₂ and CO) using metal-substituted hexaaluminate catalysts in short-contact-time reactors. Hexaaluminate catalysts offer excellent high-temperature stability compared to the equivalent metal-based catalysts. The hexaaluminates are synthesized by a metal-exchange process using alumoxane precursors that enable a wide range of metal substitutions. Of all the combinations tested, RhSr-substituted hexaaluminates yielded the best performance. The catalysts are supported on alumina porous-foam structures, which are positioned within a tube furnace to control the operating temperature. Two-stage combinations of RhSr- and Ni-substituted hexaaluminates are shown to improve conversion activity and selectivity compared to a single-catalyst system.     

On the blow-up rate of large solutions for a porous media logistic equation on radial domain

In this paper we establish the exact blow-up rate of the large solutions of a porous media logistic equation. We consider the carrying capacity function with a general decay rate at the boundary instead of the usual cases when it can be approximated by a distant function. Obtaining the accurate blow-up rate allows us to establish the uniqueness result. Our result covers all previous results on the ball domain and can be further adapted in a more general domain.     

Conductivity and dielectric properties of sol–gel derived porous zirconia

The 8-mol percentage Y₂O₃-stabilized Porous Zirconia was prepared using sol–gel method. Zirconium oxalate gel was prepared by the addition of appropriate amount of oxalic acid solution into the 1 M aqueous solution of zirconium-oxy chloride. A cubic phase zirconia powder was obtained by calcination and milling of the zirconium oxalate gel. Crystallization temperature was found about 450 °C from the Differential thermal analysis. The phase analysis by X-ray diffraction shows the presence of cubic phase. Pellets sintered at 1,350 °C were highly porous, and the electrical conductivity was found with lower value due to the porosity, and the hardness was about 8.0 GPa. Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006.     

Investigation on hexamethyldisilazane vapor treatment of plasma-damaged nanoporous organosilicate films

Hexamethyldisilazane (HMDS) vapor treatment of plasma-damaged nanoporous organosilicate thin films has been studied as a function of treatment temperature in this work. Although, the HMDS vapor treatment facilitated incorporation of methyl (CH₃) groups subsequent to the removal of free hydroxyl (OH) groups in the damaged films at treatment temperature as low as 55 °C, the bonded OH groups were not removed. More significantly, detailed analysis of the results reveals that HMDS vapor modified only the surface of the plasma-damaged samples and not the entire film as expected. This is attributed to the formation of a thin solid layer on the surface, which effectively prevents penetration of HMDS vapors into the bulk. The Fourier transform-infrared (FT-IR) absorption and dielectric constant measurements confirm that the vapor treatment assists only partial curing of the plasma-damaged films. Alternative processes of curing the films with HMDS dissolved in supercritical carbon dioxide (SCCO₂) as a medium of reaction in static and pulsed modes were also attempted and the results are presented in this paper.     

Oblique reflection of shock waves from rigid porous materials

A study to determine the general gas dynamic behaviour associated with the impact of a shock wave on a porous wedge has been undertaken. A number of interesting features are noted. The pattern of wave reflection is shown to be significantly affected by the inflow of gas into the wedge. This has the effect of reducing the triple point trajectory angle for cases of Mach reflection and for strongly reducing the reflection angle in regular reflection. The permeability of the wedge has a significant effect on the strength of the reflected wave and in some cases this wave can be attenuated to the extent that it is almost eradicated. Pressure measurements taken under the wedge are characterized by oscillations which are of similar shape, for a given wedge, over a range of shock wave Mach numbers. It is shown that the wave transmitted into the wedge is attenuated to varying degrees depending on the material properties, and that for weak incident waves the mean propagation velocity can be less than the sound speed in the pore fluid. Photographs taken using a specially constructed wedge which allows the transmitted wave to be visualised, show that the transmitted wave is nearly plane.This article was processed using Springer-Verlag T_EX Shock Waves macro package 1.0 and the AMS fonts, developed by the American Mathematical Society.     

多孔硅发光机制的分析

从量子力学的基本理论出发讨论了量子限制效应，推导出多孔硅有效禁带宽度增量并用量子限制效应和表面态及其物质在发光中作用的理论解释了ＰＳ光致发光的实验现象。     

Transition-metal-templated synthesis of rotaxanes and catenanes: From small molecules to polymers

This article provides an overview of the fundamental principles of the synthesis of metallocatenanes and metallorotaxanes. It also describes the synthesis and properties of electronic conducting polymers—polypyrrole and polythiophene—built around metallocatenanes and metallorotaxanes. The particular properties of this new class of polymers, including the possibility of transmetallation reactions being performed with them and the observation of electronic coupling between the metal centers and the conducting matrix, are discussed. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3470–3477, 2003