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2.
The ability of bottlebrush block copolymers (BBCPs) to self-assemble into ordered large periodic structures could greatly expand the scope of photonic and membrane technologies. In this paper, we describe a two-step synthesis of poly(l-lactide)-b-polystyrene (PLLA-b-PS) BBCPs and their rapid thin-film self-assembly. PLLA chains were grown from exo-5-norbornene-2-methanol via ring-opening polymerization (ROP) of l-lactide to produce norbornene-terminated PLLA. Norbonene-terminated PS was prepared using anionic polymerization followed by a termination reaction with exo-5-norbornene-2-carbonyl chloride. PLLA-b-PS BBCPs were prepared from these two norbornenyl macromonomers by a one-pot sequential ring opening metathesis polymerization (ROMP). PLLA-b-PS BBCPs thin-films exhibited cylindrical and lamellar morphologies depending on the relative block volume fractions, with domain sizes of 46–58 nm and periodicities of 70–102 nm. Additionally, nanoporous templates were produced by the selective etching of PLLA blocks from ordered structures. The findings described in this work provide further insight into the controlled synthesis of BBCPs leading to various possible morphologies for applications requiring large periodicities. Moreover, the rapid thin film patterning strategy demonstrated (>5 min) highlights the advantages of using PLLA-b-PS BBCP materials beyond their linear BCP analogues in terms of both dimensions achievable and reduced processing time. 相似文献
3.
Since the outbreak of the COVID-19 pandemic, most countries have recommended their citizens to adopt social distance, hand hygiene, and face mask wearing. However, wearing face masks has not been well adopted by many citizens. While the reasons are complex, there is a general perception that the evidence to support face mask wearing is lacking, especially for the general public in a community setting. Face mask wearing can block or filter airborne virus-carrying particles through the working of colloid and interface science. This paper assesses current knowledge behind the design and functioning of face masks by reviewing the selection of materials, mask specifications, relevant laboratory tests, and respiratory virus transmission trials, with an overview of future development of reusable masks for the general public. This review highlights the effectiveness of face mask wearing in the prevention of COVID-19 infection. 相似文献
4.
We present the design and study of waveguide structures based on porous silicon where the light confinement is not due to the usual total reflection effect but to the use of photonic crystals (PCs) as confining walls. These PC are omnidirectional mirrors (OMs), consisting of the periodic repetition of two porous silicon layers with different refractive indices and thicknesses. They reflect the radiation for all angles of incidence within a frequency range called the omnidirectional band gap (OBG). We have followed the PC formalism to investigate the properties of the OM as a multimode waveguide: the number of modes within the band gap, their field spatial distribution and their confinement as a function of the frequency and the core thickness. 相似文献
5.
Cosmic dust and our origins 总被引:1,自引:0,他引:1
J Mayo Greenberg 《Surface science》2002,500(1-3):793-822
The small solid particles in the space between the stars provide the surfaces for the production of many simple and complex molecules. Processes involving the effects of ultraviolet irradiation of the thin (hundredth micron) mantles are shown to produce a wide range of molecules and ions also seen in comets. Some of the more complex ones inferred from laboratory experiments are expected to play an important role in the origin of life. An outline of the chemical evolution of interstellar dust as observed and as studied in the laboratory is presented. Observations of comets are shown to provide substantial evidence for their being fluffy aggregates of interstellar dust as it was in the protosolar nebula, i.e. the interstellar cloud which collapsed to form the solar system. The theory that comets may have brought the progenitors of life to the earth is summarized. 相似文献
6.
Porous road surfaces offer an effective means of reducing the generation and propagation of noise from road traffic. However, the porosity of these surfaces can deteriorate over time, leading to a reduction in their noise reducing properties. Efficient methods are therefore required for monitoring this performance. Existing techniques for performing in-situ measurements of acoustic absorption are unsuitable for use within the traffic stream. Static measurements using time domain Maximum Length Sequence (MLS) based techniques have been demonstrated to offer advantages over traditional techniques, presenting the opportunity for measurements under dynamic conditions. This paper describes the design of a system for carrying out dynamic MLS-based measurements. Results are presented which demonstrate that stable dynamic measurements can be carried out at speeds of up to 30 km/h. 相似文献
7.
A new stochastic method of reconstructing porous media 总被引:1,自引:0,他引:1
We present a new stochastic method of reconstructing porous medium from limited morphological information obtained from two-dimensional
micro- images of real porous medium. The method is similar to simulated annealing method in the capability of reconstructing
both isotropic and anisotropic structures of multi-phase but differs from the latter in that voxels for exchange are not selected
completely randomly as their neighborhood will also be checked and this new method is much simpler to implement and program.
We applied it to reconstruct real sandstone utilizing morphological information contained in porosity, two-point probability
function and linear-path function. Good agreement of those references verifies our developed method’s powerful capability.
The existing isolated regions of both pore phase and matrix phase do quite minor harm to their good connectivity. The lattice
Boltzmann method (LBM) is used to compute the permeability of the reconstructed system and the results show its good isotropy
and conductivity. However, due to the disadvantage of this method that the connectivity of the reconstructed system’s pore
space will decrease when porosity becomes small, we suggest the porosity of the system to be reconstructed be no less than
0.2 to ensure its connectivity and conductivity. 相似文献
8.
Nanofiber bundles of Ag2S, Ag2Se, and Ag have been successfully synthesized by making use of Ag2C2O4 template nanofiber bundles, utilizing both anion‐exchange and redox reactions. The obtained bundles were polycrystalline nanofibers composed of nanoparticles in which the precursor morphology was well‐preserved, indicating that Ag2C2O4 nanofiber bundles acted as a general sacrificial template for the synthesis of silver‐based semiconductor and metal nanofibers. Dispersing media and transforming reactants were found to be key factors influencing the chemical transformation in the system. In particular, separate single‐crystalline Ag nanofibers were obtained via a nontemplate route when ascorbic acid was used as a relatively weak reductant. An electrical transfer and switching device was built with the obtained Ag2S and Ag nanofiber bundles, utilizing the unique ion‐conductor nature of Ag2S and revealing their potential applications in electronics. 相似文献
9.
10.
Structural characterisation of such bio-objects as fibrinogen solution, yeast cells, wheat seeds and bone tissues has been done using two versions of cryoporometry based on the integral Gibbs-Thomson (IGT) equation for freezing point depression of pore liquids and the measurements by 1H NMR spectroscopy (180-200 < T < 273 K) and the thermally stimulated depolarisation current (TSDC) method (90 < T < 273 K) of structured water. The IGT equation was solved using a self-consisting regularization procedure including the maximum entropy principle applied to the distribution function of pore size (PSD). Both methods give clear pictures of changes in the structural characteristics caused, e.g., by hydration and swelling of wheat seeds and yeast cells, coagulation and interaction of fibrinogen with solid nanoparticles in the aqueous media, and the human bone tissue disease. 相似文献