微小盲孔于电镀制作的困难点与产品可靠性探讨

随着3G通信技术在中国的开放,拉开了3G手机的帷幕。3G乃至4G以上的相关移动通讯产品功能的增加,使HDI(高密度印制电路板)朝向四个技术趋势发展:一是高阶层,基本为二阶HDI结构,部分甚至需要三,四阶的HDI结构;二是缩小线宽间距,线宽间距基本在75μm左右,更小的达到50～60μm;三是堆叠设计的盲孔与电镀铜填孔;四是微盲孔的直径和焊盘的直径越来越小,微盲孔孔径发展需求从0.10mm(4mil)缩小到0.075mm(3mil)乃至0.050mm(2mil)。通讯产品功能的增加,将促使HDI高集成化发展,盲孔孔径微小化是HDI高集成化发展的一个重要方向;本文主要探讨盲孔孔径微小化后对电镀加工制作的困难度与信赖性要求。盲孔孔径从4mil发展到3mi l乃至2mi l后对电镀制程的相关搭配,以及我们应该采用何种微盲孔电镀方式来提高微盲孔的可靠性,确保微盲孔可靠性可达到相关信赖性的要求。     

基于小波变换的清浊音分类及基音周期检测算法

该文提出了一种基于小波变换的鲁棒性基音周期检测方法。检测前在小波域上用Teager能量算子对语音信号进行清浊音判决,对浊音段采用空域相关函数提取基音周期。实验表明,与传统的小波变换算法和自相关法相比,该方法鲁棒性好,具有更高的准确性。     

低速率WI编码器中4~6bit基音量化算法研究

基音在语音编码中通常采用7bit无失真均匀量化。由于浊音段语音的基音普遍具有缓慢渐变的特点,为了更有效地去除前后帧基音之间存在的相关性,该文基于Eriksson和Kang提出的4bit基音量化算法,针对汉语语音进行研究,实现了一套4~6bit基音量化算法。该算法计算简单,无需码书存储。将此基音量化方案应用于WI模型和WI编码器,主观A/B听力测试结果表明,该方案在高效量化基音的同时保证了合成语音质量几乎没有损失,完全满足低速率WI编码器对量化基音的要求。     

一种2.4kbps改进型MBELP编码

该文给出了一种改进的2.4kb/s多带激励线性预测(IMBELP)语音编码算法。与传统的MBELP算法相比,本算法在基音提取和清/浊音判决上采取了一些改进措施,使得合成语音质量有一定的提高。本文详细介绍了改进后的MBELP算法,并将其在基音提取和清/浊音判决的结果与传统的MBELP进行比较。     

语音压缩编码中的两种基音预测器

本文研究了语音压缩编码中基音预测器的两种情形,即开环和闭环结构。提出了一些简化基音预测器求解方法,比较了几种条件下的基音预测器性能。给出了计算机仿真结果。     

煤精制软沥青庚烷不溶甲苯可溶族结构的光谱分析

以高温煤焦油为原料制备软化点为32℃煤焦油精制软沥青,再以庚烷、甲苯为溶剂超声萃取得庚烷不溶甲苯可溶物。蒸气压渗透法测定庚烷不溶甲苯可溶物平均分子量为349;元素分析与平均分子量结合得平均分子式C26.65H17.62N0.12S0.06O0.51,平均分子中杂原子总数0.68;红外分析结果表明：其杂原子氧以R—O—R,Ar—O—R结构存在,氮以R—NH—R和—N=结构存在,且以—N=为主;采用改进的Brown-Lander模型得其平均结构是六环稠环;紫外分析表明,线性排列为主、面性排列为辅,即庚烷不溶甲苯可溶族的化学结构以渺位缩合为主,迫位缩合为辅。     

Carbon nanosheets derived from soluble pitch molecules and their applications in organic transistors

We report a synthesis method for carbon nanosheets (CNSs) using pitch prepared by reforming a commercially available naphtha cracking bottom oil, which is often used as a carbon fiber precursor. The pitch solution is spin-coated on a silicon wafer without using a catalyst support. After stabilization and carbonization, the CNSs as thin as 2 nm show an electrical conductivity of approximately 30,000 S/m. Although the CNSs do not have a well-developed graphitic structure, as observed using Raman spectroscopy and transmission electron microscopy, they are conductive enough for use as electrodes in an organic thin film transistor.     

Boron-doped carbon prepared from PFO as a lithium-ion battery anode

A petroleum-based Li-ion battery anode was prepared by thermal condensation of pyrolysis fuel oil (PFO) and a subsequent carbonization process. H₃BO₃ was used as a catalyst for efficient thermal condensation, carbonization and battery performance. The influence of the carbonization temperature on the carbon structure and battery performance was also investigated. Notably, H₃BO₃ promoted thermal condensation and formation of a graphitic carbon structure and acted as a boron doping agent. Boron-doping attenuated the highly active sites in carbon and effectively controlled formation of the SEI layer, which resulted in an increase in the initial efficiency of the anode. For the sample carbonized at 900 °C, a reversible capacity of 301 mAh/g and an initial efficiency of 78.6% were obtained. In addition, the samples obtained at different carbonization temperatures were all highly stable over 50 cycles, with capacity retentions greater than 90%.     

高标准无铅PCB耐热性及其影响因素研究

针对要求通讯类PCB可承受峰温超过260℃、且无铅回流焊次数达到5次的高标准要求,本项目从PCB的材料选择、工程设计、制造工艺方面出发,建立了PCB耐热性的评测模型,评测了主要的高性能无铅板材、半固化片、PCB设计和PCB制造过程中的层压、钻孔、去钻污等关键工艺过程进行了研究,提升了PCB的耐热性,并建立起高标准无铅PCB的设计和选材规则、制造工艺和品质控制规范。