HOFs under light: Relevance to photon-based science and applications

Hydrogen-bonded Organic Frameworks (HOFs) are an appealing, newly emerging classes of porous materials whose bright potential as multifunctional resources is reflected in important applications like gas storage and separation, molecular recognition, electric and optical materials, chemical sensing, catalysis, and biomedicine. HOFs are assembled from organic building blocks through H-bonding interactions. The resultant framework can be further reinforced via weak connections such as π-π, van der Waals, and/or C-H-π interactions. The highly flexible and reversible HOF structures are exceptionally suitable for the realization of smart HOF materials. To this end, it is crucial to unravel and control the photobehavior of these compounds at intimate levels by the use of advanced laser-based spectroscopy and microscopy techniques. The use of light to study the photophysical processes of HOF-based systems will help to trigger further research to expand their applicability in the related fields. This Review surveys the past-10-years contributions on the spectroscopy and photoinduced fast/ultrafast dynamics of HOFs, the interactions between their building units, the effect of light on their photostability, and most important photonic applications. The aim of this work is to give a rich up-to-date summary of photochemistry and related applications of HOFs and their composites. The reviewed HOFs have been divided into different families based on the nature of the linker, with the purpose of offering to the reader a concise understanding of the related photoinduced processes within each family. The relevant applications of HOFs are also briefly summarized to validate their potential use in modern science and technology.     

Butterfly scale form birefringence related to photonics

Wings of the butterflies Morpho aega and Eryphanis reevesi were investigated in the present study by fluorescence, polarization and infra-red (IR) spectroscopic microscopy with the aim of identifying the oriented organization of their components and morphological details of their substructures. These wings were found to exhibit a strong iridescent glow depending on the angle of the incident light; their isolated scales exhibited blue fluorescence. Parallel columns or ridges extend from the pad and sockets to the dented apical scale's region, and they are perpendicular to the ribs that connect the columnar ridges. The scales reveal linear dichroism (LD) visually, when attached on the wing matrix or isolated on slides. The LD was inferred to be textural and positive and was also demonstrated with IR microscopy. The scale columns and ribs are birefringent structures. Images obtained before and after birefringence compensation allowed a detailed study of the scale morphology. Form and intrinsic birefringence findings here estimated and discussed in the context of nonlinear optical properties, bring to the level of morphology the state of molecular order and periodicity of the wing structure. FT-IR absorption peaks were found at wavenumbers which correspond to symmetric and asymmetric (–N–H) stretching, symmetric (–C–H) stretching, amide I (–CO) stretching, amide II(–N–H), and β-linking. Based on LD results obtained with polarized IR the molecular vibrations of the wing scales of M. aega and E. reevesi are assumed to be oriented with respect to the long axis of these structures.     

Core temperature in super-Gaussian pumped air-clad photonic crystal fiber lasers compared with double-clad fiber lasers

In this paper we investigate the core temperature of air-clad photonic crystal fiber (PCF) lasers pumped by a super-Gaussian (SG) source of order four. The results are compared with conventional double-clad fiber (DCF) lasers pumped by the same super-Gaussian and by top-hat pump profiles.      

光子晶体光纤非线性光谱特性的理论与实验研究

光子晶体光纤具有特殊的导光机制和结构可调性,可以产生奇异的色散特性及高非线性,为非线性光纤光学领域的研究提供了新的条件。受多种非线性光学效应的共同作用,在不同泵浦光脉冲参数条件下,不同结构参数及传输特性的光子晶体光纤能产生丰富的非线性光谱。利用分步傅里叶方法求解非线性薛定谔方程,模拟飞秒激光脉冲在光子晶体光纤中的传输过程,获得输出光谱与入射光脉冲参数(泵浦光峰值功率P、泵浦光波长λ、光脉冲形状、光脉冲宽度T_FWHM)、光纤结构参数(孔间距Λ、空气填充比d/Λ、光纤长度z)、传输特性(色散、非线性系数)的关系,分析拉曼孤子、色散波、自相位调制等非线性效应产生的光谱特性。利用光子晶体光纤包层节区进行非线性光学实验研究,获得了孤子波和色散波的宽带光谱输出。理论分析与实验测量的光谱中都包括了波长0.5 μm附近可见光波段的蓝移色散波、0.82 μm波段的剩余泵浦光、1.1 μm波段的孤子波、2 μm附近的红移宽带色散波。理论分析与实验测量结果一致,阐明光子晶体光纤中非线性光谱产生的物理原理,实现了对宽带光谱的可控输出,为高非线性光子晶体光纤的结构设计、制备及非线性光谱的应用研究奠定基础。     

光子学的发展和光子产业

论述了光子学、光子技术的产生、发展和突破;阐明了光子学的定义、内涵、范畴和前沿;提出了关于第1类和第Ⅱ类光子产业的设想;予测了光子产业发展.     

Millimeter-Wave Signal Generation and Harmonic Upconversion Through PM-IM Conversion in Chirped Fiber Gratings

A novel technique for generating millimeter-wave signals through phase-to-intensity modulation conversion in chirped fiber gratings is proposed and demonstrated. Experimental results on generating a 28 G Hz signal using harmonics orders from 7th to 10th are provided. Excellent phase-noise performance (87 dBc Hz @ 10KHz) is demonstrated. It is also demonstrated that this technique may be efficiently used for harmonically upconverting intermediate frequency signals to the millimeter-wave band. Bit-error-rate measurements for different modulation format (QPSK MQAM) signals, which were upconverted employing the PM-IM conversion technique, show very good performance (< 10 ^{- 9}) and transparency to the modulation format.     

Photonic mm-Wave Generation Using a Double Passband Fiber Bragg Grating Filter

We report a simplified version of a mm-wave generator employing the sideband filtering technique which uses a single optical sideband filter. Instead of using a Mach-Zehnder-like fiber network to select a pair of sidebands, we employ a single Fabry-Perot fiber Bragg grating with a pair of passbands separated by the mm-wave frequency. Using a single filter eliminated the need for polarization control and pathlength matching that was required by the former interferometer-like arrangement. We describe a 30 GHz generator design and present its mm-wave signal spectrum showing an instrument-limited linewidth of ~20 Hz. The generation of such an extremely narrow signal spectrum from a laser with a 1 MHz linewidth demonstrates the remarkable laser frequency noise cancellation property of the sideband filtering technique.     

高下路空气孔型光子晶体环形谐振腔的设计

提出一种基于二维正方晶格光子晶体空气孔型高下路效率的环形谐振腔,通过压缩线缺陷波导的宽度实现单模有效控制,同时讨论内围光子晶体列数对传输场的影响,然后运用二维时域有限差分方法数值分析了耦合强度及环区局部折射率调制对下路效率、品质因子以及下路波长等参量的影响.结果表明:当波导宽度为0.7个晶格常量,耦合强度为0个晶格常量,在信道波长为1 528.1nm时,下路效率为99%,品质因子Q为379;当耦合强度提高到1个晶格常量,下路波长稍微漂移为1 524.3nm,品质因子显著提高到1 397,而下路效率下降为89%.同时,下路波长会随着环区折射率的增加呈线性红移.     

2010年通信技术和业务概貌预测──AT＆T贝尔研究院John Mayo院长演讲笔记

本文是贝尔研究院ＪｏｈｎＭａｙｏ院长１９９４年７月１１日在上海所作学术报告的听讲笔记。报告预测２０１０年通信技术和业务十大方面的概貌：（１）微电子集成芯片；（２）光子逻辑控制；（３）光纤传输容量；（４）语音信号处理；（５）传真和可视通信；（６）通信网结构进化，（７）个人无线通信；（８）计算机处理能力；（９）通信软件生产率；（１０）多媒体信息终端。