乙烯-α-烯烃共聚物的结晶性能及其临界序列结晶长度的研究

本文用DSC、WAXD及偏光显微镜(PLM)方法,研究了化学反应法催化剂合成的乙烯-α-烯烃共聚物的结晶性能及其临界序列结晶长度。结果表明,随共聚物中α-烯烃含量增大,共聚物的微晶尺寸、结晶度及熔点均逐渐减小,而晶胞参数增大。变化的辐度戊烯>辛烯。共聚物的临界结晶序列长度(n)和k值均戊烯<辛烯。上述结果表明影响支链进入晶格的主要因素是α-烯烃支链长度和结构。     

投料顺序对动态硫化PP／EPDM性能影响及其机理的研究

针对ＰＰ降解在ＰＰ／ＥＰＤＭ动态硫化中对体系产生的不利影响。考察了四种不同投料顺序对ＰＰ／ＥＰＤＭ动态硫化物的冲击韧性，加工流动性，交联程度和断面形貌等宏观和微观性能，并进行了不同ＥＰＤＭ含量的动态硫化和非硫化ＰＰ／ＥＰＤＭ的性能比较。结果表明，优化投料顺序能实现对动态硫化体系中化学反应对象和化学反应程度的有效干预。     

NMR and potentiometric determination of the high pK values and protonation sequence of dipyridino-hexaaza-28-crown-8 and its interactions with selenate,sulfate and nitrate ions in aqueous solution

The aqueous protonation and anion-binding SeO ₂ ^–/4 SO _2– ⁴ , and NO _– ³ ) constants of the macrocyclic polyamine ligand, dipyridino-hexaaza-28-crown-8(L), were measured in 0.1M KCl using a potentiometric titration technique. The protonation sequence of the aza groups of L was studied in D₂O from the chemical shifts of the nonlabile protons so as to find the charge distribution geometry as a function of pD. The study indicates that in 0.1M KC1 fully protonated L forms stable l: 1 complexes with SeO _2– ⁴ (logK=3.68) and SO _2– ⁴ (logK=3.55), but not with NO _– ³ (logK < l.5). All of the amine pK values were above 6.3, thus allowing the use of the protonated form of this ligand over a wide pH range.     

Isolation, Mapping, DNA Sequence and RFLPs Studies of Random Single-Copy DNA Segments on Human X Chromosome

Using the total human/mouse DNA as the probe, screening has been carried out three times with in situ plaque hybridization to obtain the single-copy DNA sequence from the human X chromosome genomic library. The effective rate of screening is 1. 45%. DNAs from clones containing single-copy inserts have been analyzed by a panel of hybrid cells with or without human X chromosome. Three segments, designated by DXFD52,73,75, are mapped to the X chromosome. DXFD52 has been precisely localized on Xq12-q13 with in situ chromosomal hybridization. DXFD52 has been partially sequenced. The results indicate that DXFD52 is a new isolated single-copy segment on the X chromosome. Great progress in the RFLPs study with DXFD52 has been achieved in the population of Chongqing, Sichuan Province. The results show that the DXFD52 can be used to detect the RFLP with Hind Ⅲ, Bgl Ⅱ, and Hinf Ⅰ. DXFD52 will be a potential "landmark" for the construction of the complete linkage map of human genome and the analysis of genomic s     

基于Zadoff-Chu序列的频控阵稳健波束成形方法

不同于传统相控阵,频控阵（Frequency Diverse Array,FDA）在所有阵元间引入频率偏差,可以生成具有精准指向特性的点状辐射方向图,有效克服传统相控阵方位角相关性导致的接收方向射频信号安全性下降的问题。作为与传统相控阵的本质区别,FDA阵元频偏设置直接影响FDA辐射方向图的形状。为了生成理想的点状方向图,提出了一种Zadoff-Chu FDA（ZC-FDA）稳健波束成形方案,利用Zadoff-Chu序列调整阵元频偏,消除FDA辐射方向图周期性,抑制距离-方位角耦合性。与现有FDA系统相比,ZC-FDA方案在理想点状辐射方向图生成和波束旁瓣水平抑制方面具有明显优势。     

FBMC系统改进序列算法的定时同步技术

为提高滤波器组多载波（Filter Bank Multicarrier,FBMC）系统在低信噪比下的定时同步准确率和抗频偏性能,基于FBMC系统与正交频分复用（Orthogonal Frequency Division Multiple,OFDM）系统的相似性,对OFDM系统定时同步中的Park测度函数进行改进并引入到FBMC系统中。利用共轭对称结构能够提高定时精度和加权处理能够更好地抵抗频偏影响的特点设计同步序列,进行共轭对称和加权处理。仿真结果表明,基于改进序列的Park算法相较共轭对称序列的TR1算法,其信噪比提前3 dB达到了100%定时准确率,实现了低信噪比下的高精度定时同步,且具有更强的抗频偏性能;相较原Park算法,相同信噪比下,改进序列的Park算法的频偏均方差（Mean Square Error,MSE)也小于原Park算法的频偏MSE,抗频偏性能表现更优。     

一种降低FBMC-OQAM系统PAPR的ASSABC-PTS算法

针对滤波器组多载波-偏移正交幅度调制技术(Filter Bank Multicarrier-Offset Quadrature Amplitude Modulation,FBMC-OQAM)存在峰均功率比(Peak-to-Average Power Ratio,PAPR)过高的问题,以及传统部分传输序列(Partial Transfer Sequence,PTS)算法对PAPR抑制效果不明显,提出了一种新的基于自适应搜索策略的人工蜂群部分传输序列算法(Adaptive Search Strategy Based Artifical Bee Colony PTS,ASSABC-PTS)。首先,根据FBMC-OQAM系统特性,利用传统PTS算法对系统进行初步优化,以降低FBMC-OQAM系统的PAPR;然后,针对PTS算法中存在的计算复杂度问题,引入人工蜂群(Artificial Bee Colony,ABC)算法进行优化;最后,在ABC算法中引入自适应搜索策略提升算法的局部寻优能力,加快ABC算法的收敛速度和搜索精度。仿真实验表明,ASSABC-PTS在有效降低系统算法复杂度的同时,也极大降低了FBMC-OQAM系统的峰均功率比。     

组合跳变随机平移宽间隔混沌跳频序列设计

为进一步提高宽间隔跳频序列的性能,基于混沌跳频序列,针对随机平移替代法存在的“窄点”平移与序列平衡性的矛盾问题,提出了一种新的组合跳变随机平移法。该方法在随机平移替代法的基础上取消“窄点”修正,引入组合跳变序列控制频点宽间隔映射。为兼顾组合跳变随机平移法产生序列的平衡性、汉明自相关性和宽间隔特性,构造了跳频序列的复合目标优化函数,引入粒子群算法计算得到最优的序列控制参数。仿真结果表明,组合跳变随机平移法可构造更多的序列,且产生的宽间隔混沌跳频序列具有更好的平衡性、汉明相关性和复杂度,采用粒子群优化获取的控制参数可以实现序列性能的均衡最优。     

A strong limit theorem for generalized Cantor-like random sequences

ＡＳＴＲＯＮＧＬＩＭＩＴＴＨＥＯＲＥＭＦＯＲＧＥＮＥＲＡＬＩＺＥＤＣＡＮＴＯＲ－ＬＩＫＥ　ＲＡＮＤＯＭ　ＳＥＱＵＥＮＣＥＳＬＩＵＷＥＮ（刘文）（ＤｅｐａｒｔｍｅｎｔｏｆＭａｔｈｅｍａｔｉｃｓａｎｄＰｈｙｓｉｃｓ,ＨｅｂｅｉＵｎｉｖｅｒｓｉｔｙｏｆＴｅ...     

Stories about groups and sequences

The main theme of this article is that counting orbits of an infinite permutation group on finite subsets or tuples is very closely related to combinatorial enumeration; this point of view ties together various disparate stories. Among these are reconstruction problems, the relation between connected and arbitrary graphs, the enumeration of N-free posets, and some of the combinatorics of Stirling numbers.Dedicated to Hanfried Lenz on the occasion of his 80th birthday.