A Decision Aided CDMA Receiver with Partially Adaptive Decorrelating Multi-User Interference Cancellation

A CDMA receiver with enhanced multiple access interference (MAI) suppressionis proposed for a pilot symbols assisted system over multipath channels. Thedesign of the receiver involves the following procedure. First, blind adaptivecorrelators are constructed at different fingers based on the scheme ofgeneralized sidelobe canceller (GSC) to collect the multipath signals andsuppress MAI. A low-complexity partially adaptive (PA) realization of the GSCcorrelators is proposed which incorporates multi-user information for reducedrank processing. By a judiciously designed decorrelating procedure, a new GSCstructure is obtained in which the MAI are decorrelated and suppressedindividually. The next step is then a simple coherent combining of thecorrelator outputs with pilot aided channel estimation. Finally, furtherperformance enhancement is achieved by an iterative scheme in which the signalis reconstructed and subtracted from the GSC correlators input data, leadingto faster convergence of the receiver. The proposed low-complexity PA CDMAmulti-user receiver is shown to be robust to multipath fading and channelerrors, and achieve nearly the same performance of the ideal maximum SINR andMMSE receivers by using a small number of pilot symbols.     

The effect of hBN on the flame retardancy and thermal stability of P-N flame retardant PA6

A novel thermally conductive Polyamide 6 (PA6) with good fire resistance was prepared by introducing a phosphorous-nitrogen flame retardant (FR) and platelet-shaped hexagonal boron nitride (hBN) into the matrix. With high thermal conductivity and good flame retardancy, the material is suitable for applications in electronic and electrical devices. The limiting oxygen index (LOI) changes for various loadings content of FR. However this formulation still does not show an ideal fire resistance, due to the appearance of melt dripping behavior during the UL 94 test. With the extra introduction of 3 vol% and 5 vol% hBN, the melt dripping behavior during the burning process completely disappeared. The hBN also increased the thermal conductivity. Furthermore PA6 compounded with FR and hBN showed a better thermal stability than neat PA6. The morphology of the char residues was investigated by scanning electron microscopy (SEM). The flaky hBN acted as the framework in the char structure and the rigid hBN could effectively break the bubble-shaped char on the surface of the residues which resulted in the enhancement of the strength and compactness of the char.     

基于GaAs HBT工艺的高增益宽带Doherty功率放大器设计

在传统Doherty功率放大器的基础上,采用砷化镓(GaAs)异质结双极晶体管(HBT)工艺,设计了一款可应用于5G通信N79频段(4.4~5 GHz)的高回退效率MMIC Doherty功率放大器(DPA)。通过在Doherty电路中采用共射-共基结构,并在共射-共基结构中加入共基极接地电容,大幅提升了DPA的增益和输出功率。使用集总元件参与匹配,减小了芯片的面积。仿真结果表明,在目标频段内,增益大于28 dB,饱和输出功率约为38 dBm,饱和附加效率(PAE)为63%,7 dB回退处的效率达到43%。     

嵌入式平面麦克风阵列TDOA校正方法

针对嵌入式安装麦克风阵列因壳体遮挡部分阵元而导致的实际波达时间差（TDOA）偏离直达波理论模型问题,基于实际声探测系统最常用的对称凸多边形平面阵型构造线性几何约束并结合秩2代数约束,提出了一种校正实测TDOA矩阵的凸优化闭式解,只要阵列结构中存在至少一对等长平行线,就能获得现有TDOA校正方法所没有的壳体遮挡衍射效应抑制能力,同时还能抑制随机误差和异常值的不利影响,实现复杂度低,更适用于日益普及的小型实时全向声探测系统应用.仿真结果验证了该方法的有效性.     

Surface segregation of silicon impurities in organic materials

The present revolution in novel organic materials is driven by the synthesis of new materials exhibiting specific functional properties. Traces of silicon compounds are often present in these materials and, although the bulk concentrations of these impurities may be low, segregation can seriously modify the surface composition. Surfaces and interfaces play an important role in many applications, and the intrinsic properties of the materials are thus often obscured by the presence of segregated impurities. By studying silicon impurity segregation in poly‐dialkoxy phenylenevinylene (PPV), polycarbonate and dendrimer macromolecules, we demonstrate how low‐energy ion scattering may be used to determine the surface impurity fraction and to observe which groups at the surface are shielded by the segregated species. We demonstrate that the performance of PPV‐ based light‐emitting diodes is significantly reduced for submonolayer coverages of siloxanes. We find that the kinetics of the segregation process depend strongly on the materials and the sample preparation conditions. We find that the presence of solvents is needed to enable segregation at room temperature. Heating does enable siloxane impurity segregation in polycarbonate in the solid phase, whereas for polydimethylsiloxane in PPV films we find that segregation in the solid phase does not occur up to 200 °C. The siloxane molecules are found to segregate to preferential sites at the surface, shielding the polar groups. Finally, we demonstrate that purification of the surface is often possible through simple procedures that provide an easy way to study the intrinsic properties of the materials. Copyright © 2004 John Wiley & Sons, Ltd.     

The crystal structure of a tricarbonyliron-substituted cyclobutadiene complex: Tricarbonyl[1,2,2a,12a-η-5,10-dimethyldibenzo[a,c]cyclobuta[f]cyclooctene-3,12-dione] iron

The crystal structure of tricarbonyl[1,2,2a,12a-η-5,10-dimethyldibenzo[a,c] cyclobuta[f] cyclooctene-3,12-dione] iron, C₂₀O₂H₁₄Fe(CO)₃, has been determined by the single crystal X-ray diffraction technique using data collected with a fully automated diffractometer. The unit cell is monoclinic, space group P2₁/c with a = 12.025(2), b = 23.204(3), c = 14.614(2) Å, β = 102.16(2)°, and contains eight molecules (two per asymmetric unit). The structure was elucidated to study the coordination of the iron atom and to correlate the conformation of the eight-membered ring with an NMR study. The final structure was obtained by Patterson-superposition and Fourier techniques and refined by full-matrix least-squares to a crystallographic residual of 0.070. In both independent molecules the iron atom is 1.77 Å from the cyclobutadiene ring to which it is coordinated. The eight-membered ring is flattened from a boat conformation and the six-membered rings are twisted from coplanarity by an angle of 74°. The twist is such that if one ring points above the eight-membered ring, the other ring will point below it with concomitant pointing in the opposite sense by neighboring carbonyl groups. Such a structure has conformational chirality. It is postulated that the stability of each enantiometer is due to the particularly high energy of the transition state through which each would pass to achieve inter-conversion.     

Photo-acoustic measurements of gas and aerosol absorption with diode lasers

The results of designing multipurpose high-sensitive photo-acoustic (PA) detectors and their application to high-resolution diode laser spectroscopy of molecular gases, gas analysis, and aerosol absorption measurements are summarized in this paper. The hardware and software of the diode laser spectrometer with a Helmholtz resonant PA detector providing an absorption sensitivity limit of better than 10(-7)Wm(-1)Hz(-1/2) are described. A procedure is proposed for an experiment involving the measurements of the rotational structure of hot vibrational bands of molecules. The results of the application of the nonresonant PA cell with temporal resolution of signals to measurements of weak nonresonant absorption of gases and soot aerosols are presented, and the possibility of creating a broad-band PA laser diode aerosol-meter is discussed.     

FT-IR photoacoustic spectra of the surface of Ru3(CO)12/Al2O3 system

The FT-IR photoacoustic spectra of Ru₃(CO)₁₂/Al₂O₃ (acidic and basic alumina) system have been measured for different ageing times. The behaviors of oxidation states of Ru on the surface of basic or acidic alumina and their difference are discussed on the ground of CO stretching bands of their spectra.     

Interpreting divergences and Madelung-type sums via extrapolations of sequence generating polynomials: Method of intersection and area rule

Based on explorations in estimating certain Madelung constants, we put forward here two separate strategies to understand the meaning of two distinct classes of divergent non-power-series expansions. One class refers to alternating series representations, the other to monotonic ones. They chiefly rest on precise and approximate polynomial extrapolations, depending on situations. In case of sawtooth sequences, e.g., the partial-sums obtainable from Dirichlet eta or beta function at negative integer arguments, exact sequence-generating polynomials are found. Extrapolations yield a graphical meaning to anti-limit here, along with the exact answer. For staircase sequences, like the ones obtained from partial-sums of series representations for lambda and zeta functions, again at negative integer arguments, anti-limits do not exist. But, correct sequence-generating polynomials are obtained. There, our recipe relies on estimation of specific, finite areas embedded by such polynomials. The schemes put forward here are direct, independent and conceptually appealing. A subsequent extension of the latter strategy to alternating series also lends extra credence. Two new interpretations of summability are gained. Pilot calculations on several types of lattice sums reveal the worth of our endeavor with approximate extrapolations as well.     

Preparation of sustained-release chlorpyrifos particles via the emulsification coacervation method and their sustained-release performance

MMA-HEMA-MAA ternary random copolymer (PA) and CaCl₂ was used as carrier and precipitant, respectively, and emulsification coacervation was adopted to prepare sustained-release chlorpyrifos particles. The particle size, morphology, structure, and the sustained-released performance of the samples were characterized. Results showed that porous and random sustained-release chlorpyrifos particles piled up into small spherical particles. Hydrogen-bonding interactions between PA and chlorpyrifos molecules were observed, and chlorpyrifos was dispersed among the PA molecules as both crystal and noncrystal forms. Raising chlorpyrifos concentrations resulted in larger proportions of chlorpyrifos distributed in the crystalline state. Chlorpyrifos was loaded into the PA crosslinked network structure and the heat resistance of the pesticide was improved significantly. The sustained-release process of chlorpyrifos was controlled by Fick diffusion mechanism, and the release mechansim of the drug consisted with the Korsmeyer-Peppas kinetic equation.