ABS的MAH/St多单体熔融接枝及其对PA6/ABS共混体系相形态和力学性能的影响

通过多单体熔融接枝的方法制备出了具有较高接枝率的ABS接枝物 (ABS g (MAH co St) ) ,并对其接枝机理进行了初步探讨 .研究表明 ,MAH、St接枝ABS时 ,反应主要发生在ABS中聚丁二烯的双键部位 .同时 ,当MAH与St的用量比约为 1:1时接枝率达到最高 .ABS g (MAH co St)作为尼龙 6 (PA6 ) ABS共混体系相容剂起到了良好的增容效果 .实验证明 ,相容剂使用前后 ,共混物的相区尺寸由几十 μm减小到 1μm以下 ,且分布更加均匀 ;共混物的拉伸强度和冲击强度等力学性能也同时得到均衡改善 .     

SMA、OMMT对PA6/ABS共混物聚集态结构及性能影响的研究

采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)等手段研究了苯乙烯-马来酸酐共聚物(SMA)、有机蒙脱土(OMMT)对尼龙6(PA6)/丙烯腈-丁二烯-苯乙烯(ABS)共混物体系聚集态结构及性能的影响.结果表明,SMA与OMMT的加入均可提高PA6/ABS共混物体系的强度及模量,但加入OMMT后共混物的韧性有所下降,而PA6/ABS/SMA共混物的韧性随SMA含量的增加呈上升趋势.SMA、OMMT对PA6/ABS共混体系都有细化ABS分散相的作用,随SMA加入量的增加,ABS分散相尺寸逐渐减小,分布趋于均匀;当OMMT加入量在4 phr以内时,对ABS分散相粒径影响不大,超过4 phr后,随着OMMT含量的增加,ABS分散相的尺寸逐渐减小.XRD与TEM的分析结果表明,对PA6/OMMT(100/5)共混物,OMMT主要以剥离形态分布,同时也存在少量OMMT聚集体;PA6/ABS/OMMT共混物中OMMT则基本以剥离形态选择分布在PA6基体相中.     

跳频发射机自动电平控制的实现方法

针对传统自动电平控制（ALC）在跳频发射机控制过程中存在功 率过冲、建立时间长的技术弊端,提出了一种改进的ALC电路的实现方法,即跳频时钟禁发法 。工程实践证明, 所提方法 是解决该瓶颈的有效方法,已成功应用于某跳频通信电台中。     

Joint power allocation and subcarrier pairing in OFDM-based cooperative relaying system

This paper proposes rate-maximized (MR) joint subcarrier pairing (SP) and power allocation (PA) (MR-SP&PA),a novel scheme for maximizing the weighted sum rate of the orthogonal-frequency-division multiplexing (OFDM) relaying system with a decode-and-forward (DF) relay.MR-SP&PA is based on the joint optimization of both SP and power allocation with total power constraint,and formulated as a mixed integer programming problem in the paper.The programming problem is then transformed to a convex optimization problem by using continuous relaxation,and solved in the Lagrangian dual domain.Simulation results show that MR-SP&PA can maximize the weighted sum rate under total power constraint and outperform equal power allocation (EPA) and proportion power allocation (PCG).     

岭南小镇文化中心扩声系统的设计

介绍了岭南小镇文化中心扩声系统的项目概况,详细说明了声场设计过程和设备配置,指出了扩声系统设计之前,特别要重视建声设计的必要性.若建声未处理好,电声就很被动.该扩声工程设计是在紧盯建声处理合理的前提下来完成电声设计步骤的,该项目验收后,使用效果很好,因此值得工程技术人员借鉴.     

Phase Structure of Polyamide 6/Poly(styrene-co-acrylonitrile) and Poly(styrene-b-(ethylene-co-butylene)-b-styrene) or Poly(maleated Styrene/Ethylene-co-Butylene/Styrene) Ternary Blends

Two sets of ternary blends; polyamide 6/poly(styrene-co-acrylonitrile)/poly(styrene-b-(ethylene-co-butylene)-b-styrene) (PA6/SAN/SEBS) and polyamide 6/poly(styrene-co-acrylonitrile)/poly(maleated styrene/ethylene-co-butylene/styrene) (PA6/SAN/SEBS-g-MA), based on 70 wt% of matrix and 30 wt% of the dispersed phases at various concentrations of the minor components, were prepared via melt blending. Morphologies of the ternary systems were studied using scanning electron microscopy (SEM) and compared with the predictions of the spreading coefficient (SC), minimum relative interfacial energy (RIE), and dynamic interfacial energy (DIE) phenomenological models. The effects of different reported surface tensions of the used polymers and different protocols of the core-shell ratio calculation on the prediction of the models were investigated. The core-shell structure for PA6/SAN/SEBS system and two separate minor phases for PA6/SAN/SEBS-g-MA were observed at all of the compositions. The results indicated that the most important parameter for the accurate prediction of the models is the accurate calculation of the interfacial tension of the used polymers, in both the static and dynamic conditions.     

Comparative study of kinetics isomerization of substituted polyacetylene (Cl,F and I): Ab initio and DFT calculations

Ab initio and DFT methods were used to investigate the interconversions of substituted polyacetylene conformers C₁₀H₆X₆ (X=F, Cl and I) in the vapour phase. The rates of this geometrical isomerization have been calculated and the Arrhenius parameters evaluated. In the case of unsubstituted polyacetylene as the reference, the B3LYP Arrhenius parameters obtained are A₁=2.99 × 10¹⁷ s^–1 and E_a=17.30 kcal mol^–1. The values of the equilibrium constant for the reaction have also been determined at various temperatures between 300 and 500 K and the value of the energies change calculated. The results also suggest that the straightforward kinetics characterizing the majority of substituted polyacetylene isomerizations above 300 K. The isomerization energies are positive and the barrier heights ΔE_barrier are expected to be sensitive for the magnitude of halogens effects. According to geometries features the Cis → Trans isomerization in the gas phase occurs by a rotational mechanism.     

一种简单RF预失真电路的研究

文章介绍一种基于肖特基二极管的预失真器及其工作原理。预失真器主要由一个肖特基二极管和直流偏置电阻组成,利用二极管的非线性,产生与功放相反的幅度失真与相位失真。通过调节二极管的偏压来调整预失真器的工作状态,使功率放大器在不同输出功率下得到最好的线性度改善。设计实际电路经实验发现,对于应用在C波段的某功率放大器,在不同的输出功率下IMD3的改善不同。在功率放大器1dB增益压缩点处IMD3改善了5dB,而在其他功率点处IMD3最大甚至可以改善20dB。     

Separation and Quantitation of Urinary Phthalates by HPLC

Abstract

A method was developed for the separation and quantitation of plasticizers and their metabolites from human urine using HPLC, Urine was diluted with an equal volume of water and extracted at pH 2.0 with diethyl ether, The extract was dried, the solvent vacuum stripped, and the residue dissolved in methanol for injection into the chromatograph. A C₁₈ reverse phase column containing 10 μ particles was used for the analysis. Ionic suppression, 0.5% acetic acid in water, at pH 3.0 was used to resolve the acidic components. A step gradient of acetonitri1e:water (containing acetic acid) was used to elute the polar metabolites as well as the non-polar plasticizers. Mass spectrometry was used t o identify the compounds in the HPLC fractions. From the HPLC fractions of the urine extract collected, phthalic acid, MEHP, DEHP and normal urinary constituents (e.g., hippuric and benzoic acid derivatives) were identified     

一种应用于WiMAX协议的全集成3.5GHzCMOS功率驱动放大器

A fully integrated CMOS differential power amplifier driver(PAD) is proposed for WiMAX applications. In order to fulfill the differential application requirements,a transmission line transformer is used as the output matching network.A differential inductance constitutes an inter-stage matching network.Meanwhile,an on chip balun realizes input matching as well as single-end to differential conversion.The PAD is fabricated in a 0.13μm RFCMOS process.The chip size is 1.1×1.1 mm~2 with all of the matching network integrated on chip. The saturated power is around 10 dBm and power gain is about 12 dB.