基于MR弱覆盖提升TD-LTE终端驻留比的方法

LTE驻留比作为LTE网络优化的重要参数，移动在多网并存的情况下，令更多的用户体验到更快更好的网络是运营商的奋斗目标。本文通过调整弱覆盖参数的方法来提高LTE驻留比及MR覆盖率，从而让更多的用户驻留在4G上，实验证明该方法对LTE驻留比的提升有一定作用。     

一种大容性负载的压电陶瓷驱动电源设计

压电陶瓷作为微定位系统的动能器件,可达到纳米级的位移精度。针对位移驱动型压电陶瓷的大容性负载特点,基于PA92设计了一种高精度、大电流的动态驱动电源。通过电容超前反馈、隔离电阻结合反馈及相位补偿等方式提高了电源的稳定性。分析结果表明,该电源能有效应用于纳米级定位系统中,在大容性负载时具有良好的动态性能,输出电压精度可达0.5 mV。     

一种符合多种协议要求的UHF RFID阅读器发射机

采用0.18 μm SiGe BiCMOS工艺,设计了一种符合多种协议要求的UHF RFID阅读器发射机。该电路包含电平移位电路(DCS)、I/Q正交上混频器、全集成功率放大器。通过DCS控制混频器跨导管的偏置,实现SSB-ASK、PR-ASK和DSB-ASK三种调制,并在不同基带信号强度下实现30%~100%可变调制深度的DSB-ASK调制。仿真结果表明,在转换增益为－4 dB时,上混频器的输出1 dB压缩点(OP1dB)为7.11 dBm,工作在AB类的功率放大器的OP1dB为26.64 dBm,发射机输入DSB-ASK信号的trai为25 μs。输出频谱满足三种协议要求。     

Studies on the migration in PA6‐OMMT nanocomposites: effect of annealing on migration as evidenced by ARXPS (angle resolved X‐ray photoelectron spectroscopy)

The present paper deals with experiments in which the angle resolved X‐ray photoelectron spectroscopy (ARXPS) technique was applied to investigate the phenomenon of migration in polyamide 6 with organically modified montmorillonite (PA6‐OMMT) nanocomposites. This is the first time ARXPS was used, to gain a more detailed insight into the migration process. Curve‐fitting analyses are reported which enable the differentiation between a manual mixture of PA6 with OMMT at room temperature from a nanocomposite structure. The ARXPS technique was applied to annealed samples at 250, 275, and 285°C, for 2 hr, and with three take of angles, α, of 90, 60, and 30°. The depth of the layer investigated is 9 nm in case the sample surface is well defined. By tilting the take‐off angle of the beam‐out electrons one can determine the intensity of the signals at various distances from the surface within the investigated layer. The concentration gradient of the Si signals is observed. The rate of migration is found to be more rapid in the layer closest to the surface. The intensity of the Si signals in the investigated layer is found to be 1.8 to 9.1 times that of the same composite sample at room temperature. This ratio determines the extent of migration. At temperatures higher than 250°C and times of annealing greater than 30 min a decrease in the extent of migration is observed. This decrease is explained by the gradual decomposition of the surfactant and the consequent removal of the polymeric matrix molecules from the migrating exfoliated units, culminating in denuded alumino‐silicate layers. These layers aggregate to noncolloidal microcomposite particles which do not migrate. The concentration of the exfoliated units decreases with consequent decrease in migration. A gradient of decreasing concentration of Si2p signals was observed after various times of annealing, where the gradient becomes more uniform with increase in time. Copyright © 2008 John Wiley & Sons, Ltd.     

Cisplatin‐Prodrug‐Constructed Liposomes as a Versatile Theranostic Nanoplatform for Bimodal Imaging Guided Combination Cancer Therapy

Up to date, a large variety of liposomal nanodrugs have been explored for cancer nanomedicine, showing encouraging results in both preclinical animal experiments and clinical treatment of cancer patients. Herein, a phospholipid conjugated with a cisplatin prodrug is used as the major structure component of liposomes together with other commercial lipids via self‐assembling. By doping with 1,1′‐dioctadecyl‐3,3,3′,3′‐tetramethylindotricarbocyanine iodide (DiR), a lipophilic dye with strong near infrared (NIR) absorbance and fluorescence, the obtained DiR‐Pt(IV)‐liposome is found to be an effective probe for in vivo NIR fluorescence and photoacoustic bimodal imaging. Attributing to its intrinsically doped cis‐Pt(IV) prodrug, efficient photothermal conversion ability, and excellent tumor homing ability, DiR‐Pt(IV)‐liposome confers greatly enhanced therapeutic outcomes in the combined photothermal‐chemotherapy. Moreover, Pt(IV)‐liposome is also demonstrated to be an efficient carrier for both small hydrophilic molecules and proteins, which are encapsulated inside the water‐cavity of liposomes, further demonstrating the versatile functions of this nanoplatform. This study develops a unique type of liposomal nanomedicine with a prodrug conjugated phospholipid as the major structure component. Such Pt(IV)‐liposome is featured with advantages including precisely defined/easily tunable drug compositions, stealth‐like pharmacokinetics, efficient tumor passive uptake, and the capabilities to simultaneously load with various types of imaging or therapeutic agents.     

丙炔醇聚合股对铁在酸性溶液中的缓蚀作用

应用电化学交流阻抗谱技术研究了Ｆｅ／Ｈ_２ＳＯ_４与Ｆｅ／Ｈ_２ＳＯ_４＋Ｈ_２Ｓ体系中丙炔醇（ＰＡ）聚合膜的形成及其缓蚀作用,同时利用ＳＥＭ、ＡＦＭ及ＥＤＸ对ＰＡ聚合不同时期铁表面腐蚀形貌进行观测与成分分析．结果表明,Ｆｅ／Ｈ_２ＳＯ_４与 Ｆｅ／Ｈ_２ＳＯ_４＋ Ｈ_２Ｓ体系中 ＰＡ可逐渐聚合成膜,从而有效抑制基体的腐蚀,使电极表面较为平整,微米尺度下呈现规则的块状结构;但Ｆｅ／Ｈ_２ＳＯ_４体系中宏观上ＰＡ并未形成连续的保护膜,导致电极表面局部发生腐蚀;而Ｆｅ／Ｈ_２ＳＯ_４＋Ｈ_２Ｓ体系中,Ｈ_２Ｓ、ＨＳ－在电极表面的吸附减缓了ＰＡ聚合成膜,但长时间腐蚀后,由于硫化物的生成覆盖在ＰＡ聚合膜上,使其具有长期缓蚀效能．     

尼龙1010／6及尼龙1010／66动态力学分析

通过动态力学参数温度谱,研究了尼龙１０１０／６、尼龙１０１０／６６两个共聚物系列的动态力学参数与组成的关系。研究表明尼龙１０１０／６、尼龙１０１０／６６在测试温度范围内出现三个明显的松驰转变：α、β、γ,其中各共聚物的β、γ松驰温度相差不大,而α松驰温度随组成改变有明显改变。一般均聚物的α松驰温度较高,共聚物的α松驰温度均低于均聚物,二个系列以尼龙１０１０／６（２９．８／７０．２）、尼龙１０１０／     

PP/PA共混高聚物在冲击载荷下的热粘弹性力学响应

采用Instron1342液压伺服试验机和改进的SHPB技术对2种不同相容剂和重量比的4种PP／PA共混高聚物进行了应变率在10^-4～10^3s^-1宽广范围,温度为25℃、40℃、60℃、80℃下的一维应力力学性能试验．结果表明这类共混高聚物的力学响应对温度和应变率都是敏感的．在准静态时,以PP-g-MAH作相容剂的PP／PA三元体系的应力幅值要高于用TPE-g作界面相容剂的PP／PA三元体系,而在承受冲击载荷下,TPE—g作相容剂的PP／PA三元体系比PP-g-MAH作相容剂的三元体系更有韧性,而在相容剂相同的条件下,随着相容剂质量比重的增加,使得尼龙粒子分布的更加均匀,虽然降低了一定的强度,但提高了韧性,以113材料为例,由其从10^-4～10^3s^-1宽广应变率范围内,20～80℃下的试验数据为依据,以“朱-王-唐”非线性粘弹性本构方程来描述这类PP／PA共混高聚物的力学响应,并拟合得到了其热粘弹性本构参数,理论预言与实验结果在应变小于7％时吻合良好．     

Polymer blends of polyamide-6 (PA6) and poly(phenylene ether) (PPE) compatibilized by a multifunctional epoxy coupler

A tetrafunctional epoxy monomer, N,N,N′-N′-tetraglycidyl-4,4′-diaminodiphenyl methane (TGDDM), has demonstrated to be a highly efficient reactive compatibilizer in compatibilizing the immiscible and incompatible polymer blends of polyamide-6 (PA6) and poly(2,6-dimethyl-1,4-phenylene ether) (PPE). This epoxy coupler can react with both PA6 and PPE to form various PA6-co-TGDDM-co-PPE mixed copolymers. These interfacially formed PA6-co-TGDDM-co-PPE copolymers tend to anchor along the interface to reduce the interfacial tension and result in finer phase domains and enhanced interfacial adhesion. A simple one-step melt blending has demonstrated to be more efficient in producing a better compatibilized PA6/PPE blend than a two-step sequential blending. The mechanical property improvement of the compatibilized blend over the uncompatibilized counterpart is very drastic, by considering the addition of a very small amount, a few fractions of 1%, of this epoxy coupling agent. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 1805–1819, 1998