H2S-sensing properties of SnO2 produced by ball milling and different chemical reactions

In this work, the mechanochemical synthesis of a moderately agglomerated tin oxide (SnO₂) powders and the subsequent preparation of semiconductor gas sensors as prototypes, were studied. Tin (II) chloride (SnCl₂) powder was milled with calcium hydroxide (Ca(OH)₂) and potassium carbonate, (K₂CO₃) powder, respectively, in a ball mill at room temperature and in an air atmosphere. Heat treatment of milled mixtures at 400 °C resulted in the formation of a tetragonal phase, confirmed by X-ray diffraction (XRD). During milling in the presence of water, a high number of hydroxide (OH) groups are formed at the surface. When SnCl₂ was milled with K₂CO₃, no water was produced and the Fourier-transform infrared spectrum (FT-IR) of the powder has no surface hydroxyl deformations. On exposure to hydrogen sulfide (H₂S) gas, the particles, prepared from anhydrous powder, have higher sensitivity than these, prepared from hydrated powder. The SnO₂ thick film, prepared from anhydrous powder may be successfully applied to a H₂S gas sensor.     

Novel anti-inflammatory and wound healing controlled released LDH-Curcumin nanocomposite via intramuscular implantation,in-vivo study

One of the most common problems in wounds is delayed healing and complications such as infection. Therefore, the need for novel materials accelerates the healing of wounds especially abdominal wounds after surgery besides high efficiency and safety is mandatory. The rate of wound healing, anti-inflammatory and biocompatibility of Zn-Al LDH (Zn-Al layer double hydroxide) alone and loaded with Curcumin (Zn-Al LDH/Curcumin) was screened via in-vivo assays through intramuscular implantation in rat abdominal wall with intact peritoneum cavity. The implanted drugs were formed through Curcumin loaded into LDH of Zn-Al with drug release of 56.78 ± 1.51% within 24 h. The synthesized nanocomposite was characterized by (TGA/DTA) thermal analysis, (XRD) X-ray diffraction, (FESEM) Field emission scanning electron microscopy, (HRTEM) high resolution transmission electron microscope, energy dispersive X-ray (EDX) and low-temperature N₂ adsorption, pore volume and average pore size distribution. The integrity of blood circulation, inflammatory signs, wound healing rate, capacity of tissue integration, antigenicity and composite biocompatibility, auto fluorescence ability of collagen bundles and the tensile strength of the muscle were assessed histopathologically after 7 and 30 days’ post-implantation. Excellent wound healing ability was achieved with shortest length between the wound gap edges and higher tensile strength of the muscle. Besides emit florescence very well followed by good healing and tensile muscles strength in Curcumin while very low strength with scar formation in Zn-Al LDH/Curcumin in both acute and chronic wound. No signs of inflammation in Curcumin & Zn-Al LDH. No vessels obstruction or bleeding observed in both Zn-Al LDH and Curcumin more than Zn-Al LDH/Curcumin and control which examined through candling. Good healing & infiltrated immune cells in same groups through histopathological examination. This work supports the anti-inflammatory, wound healing and biocompatibility of both LDH and Curcumin with living matter, increasing their biomedical applications in this era with safety and increasing efficacy with prolonged drug release.     

Synthesis,characterization, and application of griseofulvin surface molecularly imprinted polymers as the selective solid phase extraction sorbent in rat plasma samples

In present study, an investigation was carried out to develop and validate an analytical method for the selective extraction and determination of griseofulvin (GSF) from plasma samples. For this purpose, a rational approach was made to synthesize and characterize the surface molecularly imprinted polymers (SMIPs). The SMIPs were utilized as solid phase extraction (SPE) sorbents. The SMIPs were prepared by using GSF as template molecule on the surface of modified silica particles through a non-covalent technique. The particles demonstrated high adsorption capacity (119.1 µg/mL), fast adsorption equilibrium time (30 min) and good recognition selectivity for the template drug. The scanning electron microscopy and infrared spectroscopy were used to explain the structural and morphological characteristics of the SMIPs and surface non-imprinted polymers. The SPE method was combined with HPLC for plasma analysis. The method validation results demonstrated that the established method possessed good linearity for GSF ranging from 0.1 to 50 µg/mL (R² = 0.997). The limit of detection for this method was 0.02 µg/mL for rat plasma samples. The recoveries of GSF from spiked plasma samples were (90.7–97.7%) and relative standard deviations were (0.9–4.5%). Moreover, the SMIPs as selective SPE sorbent can be reused more than 8 times which is a clear advantage over commercial SPE sorbents. Finally, the usefulness of the proposed strategy was assessed by extraction and detection of GSF in real rat plasma samples.     

双极场逆Radon变换的数值模拟

对双极场（DPF）的逆Radon变换进行了数值模拟。采用加法代数重建迭代算法（ART）对含有正负值的DPF进行重建，迭代了500次。结果发现，迭代一直收敛，重建场与原场相似，包括峰的位置、方向和形状，但各个峰的高度都较原场相应的峰矮，重建区域的边界出现了明显的波动现象。与相应单极场（SPF）的重建误差作比较，结果发现，DPF的3种模拟误差都大于SPF相应的误差，其中均方误差（MSE）大10^-4数量级，绝对平均误差（AVE）、峰值相对误差（PE）分别大10^-3、10^-2数量级，说明同样条件下DPF的重建精度比SPF的小。     

GPS电子地图坐标转换算法研究

GPS车载导航系统现在已经运用得十分广泛,然而GPS采用的是WGS-84坐标系,目前我国的各类地图均采用54北京坐标或是80西安坐标,两者的差距可达0～120m.要使用各类电子导航装置就需要把WGS-84坐标转换到54北京坐标系下,并和电子地图中的像素点对应起来.本文主要介绍一种坐标转换算法,并且通过实测检验,证实算法效果良好.     

基于小波变换的在役管线漏磁信号的去噪

采用漏磁法对在役管线进行无损检测时,所采集的信号中含有大量的噪声需要去除。文中介绍了小波变换的基本理论及检测信号和噪声信号在小波变换下的特性,说明了去除漏磁信号噪声的原理。在仿真试验中采用二阶双正交样条小波为小波函数,选用软硬阈值折中法和自适应阈值处理小波系数,结果表明将小波变换应用于在役管线漏磁检测中,能很好地去除噪声,提取出有用信号。     

数学形态学与hough变换在医学图像中的应用

利用数学形态学对含有胎儿头部轮廓的医学图像进行预处理,提取近似圆形的胎儿大脑轮廓的骨架.利用hough变换自动逼近,获得最逼近胎儿大脑轮廓的圆周,此圆周的直径可以近似双顶径.     

基于Labview的光学空间滤波远程虚拟实验

提出了一种利用Labview实现光学空间滤波模拟的新方法,并对经典的阿贝-波特实验设计了仿真程序.该程序可根据用户设置的参量生成二维网格光栅作为整个物理过程的输入物,允许用户选择多种不同的滤波方式,如低通、高通、方向滤波等,并可依次操纵成像的各个步骤.程序可脱离编程环境独立运行,具有跨平台、界面友好、易于操作等优点,并可架设基于浏览器的远程虚拟实验.     

气溶胶前向散射大气能见度测量系统传递系数的标定及校准方法

分析了气溶胶的前向角散射特性,利用标准的大气透射仪标定前向散射大气能见度测量系统的传递系数。当系统结构发生变化时,传递系数也随之改变,为保证系统测量的准确性和简化系统传递系数的标定过程,提出了一种利用标准漫透射板校准系统传递系数的方法。该方法使用了两块具有相同透射系数的漫透射板,使气溶胶粒子团在前向半球上产生漫散射,此时探测器的测量值即为包含了仪器常数的定值。当系统结构改变时,这个测量值相对于原测量值的变化率作为比例系数代入系统传递系数的计算,实现校准。     

基于联合变换相关器的像移测量仿真分析

对基于联合变换相关器的像移测量数学原理进行了说明,介绍了面阵CCD的安装位置以及输入图像的获取方法,分析了低信噪比输入图像、相对转动位移对测量精度的影响。应用MATLAB对输入图像进行傅里叶变换得到联合功率谱,对二值化处理的功率谱进行傅里叶变换得到相关输出,用质量中心算法计算出像移量。分析得出,输入图像信噪比大于5dB,测量均方误差小于0.05像素;输入图像相对转动位移在0.1°的范围内,转动位移对测量精度和峰噪比的影响可以忽略不计。综合分析表明像移测量均方误差小于0.05像素。