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741.
742.
Sulfines react with sulfinyl chlorides giving α-chloroalkyl alkanethiosulfonate esters and with thionyl chloride giving α-chloroalkanesulfenyl chlorides, both in good yields. 相似文献
743.
Calcium sulphide phosphors doped with bismuth and thulium are prepared from Indian minerals. The glow curves are recorded in the temperature range of 96–320 °K. The activation energies are determined by analyzing the glow peaks after thermal cleaning, using different methods. The results show that, in these phosphors, the electron traps responsible for thermoluminescence are present prior to irradiation. The infrared absorption spectra are recorded in the range of 4000-250 cm-1. It is concluded that the traps are due to host lattice defects which may arise from S-2 ion vacancies, created during phosphor preparation. 相似文献
744.
A. Czerniakiewicz 《Discrete Mathematics》1977,19(3):201-212
We determine the minimum number of vertices an edge-colored graph must have, if its group of color preserving automorphisms is the cyclic group of order n. 相似文献
745.
针对目前光缆网建设存在的光纤利用率不高、投资不经济的基本问题,通过对目前国内外使用或出现的“微管”、“微缆”、“Fibreflow”导管、“JETnet”等使用技术特点的介绍与研究,提出了微蜂窝型导管和气吹集束型光缆的概念并探索性地论述其解决光缆网建设存在基本问题的若干应用方式、经济性及技术优越性。 相似文献
746.
Nando Prati 《Mathematical Logic Quarterly》1993,39(1):274-278
The theory New Foundations (NF) of Quine was introduced in [14]. This theory is finitely axiomatizable as it has been proved in [9]. A similar result is shown in [8] using a system called K. Particular subsystems of NF, inspired by [8] and [9], have models in ZF. Very little is known about subsystems of NF satisfying typical properties of ZF; for example in [11] it is shown that the existence of some sets which appear naturally in ZF is an axiom independent from NF (see also [12]). Here we discuss a model of subsystems of NF in which there is a set which is a model of ZF. MSC: 03E70. 相似文献
747.
Monty L Herr 《Tetrahedron》1977,33(15):1897-1903
Using the Maximum Overlap Approximation, the hybridization of a series of small ring propellanes is studied in order to arrive at a measure of the strain in these compounds 相似文献
748.
New chiral polymers have been prepared by conversion of cyano groups of polysiloxanes XE-60 and OV-225 into carboxylic groups and subsequent coupling to give the respective S-valine-R-α-phenyl-ethyl amide. In contrast to the corresponding stationary phases with S-α-phenylethyl amide groups, which have been used for the resoultion of trifluoroacetylated hexose derivatives, the new phase show high enantioselectivity for pentose and 6-deoxyhexose derivatives. 相似文献
749.
Robert H. Crabtree Hugh Felkin Tauqir Fillebeen-Khan George E. Morris 《Journal of organometallic chemistry》1979,168(2):183-195
Two isomeric series of dihydrido-diolefin complex cations, cis- and cis-trans- [IrH2(cod)L2]PF6 (cod = 1,5-cyclooctadiene; L = tertiary phosphine)have been observed directly by PMR spectroscopy and in some cases have been isolated as crystalline solids. They are prepared by H2 addition to a diolefin complex (unsaturated route) or by diolefin addition to a hydrido complex (hydride route), respectively. These complexes appear to be important intermediates in the catalytic hydrogenation of (cod) by the catalysts [Ir(cod)L2]PF6. The cis- isomers transfer hydrogen to the coordinated (cod) much more rapidly than the cis, trans isomers; the hydrogen transfer to the olefin seems to require a coplanar M(CC)H system. H2 addition to [Ir(cod)2]+ at ?80° C gives [IrH2(cod)2]+; electron-withdrawing substituents therefore do not deactivate the metal center with respect to oxidative addition. 相似文献
750.