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11.
Jijun Qiu Weidong Yu Xiangdong Gao Xiaomin Li 《Journal of Sol-Gel Science and Technology》2007,44(3):235-239
Ordered porous TiO2 films, including TiO2 nanotube arrays, are fabricated by a sol-gel dip-coating approach via ZnO nanorod templates obtained from aqueous solution
approach. The results indicate that the morphologies of ordered porous TiO2 films have been great affected by the sol-gel dip-coating cycle number. Open-ended TiO2 nanotube arrays can be obtained in optimum dip-coating cycle numbers. The TiO2 nanotubes with the inner diameter matching well with the diameters of ZnO nanorods, are well assembled and separate each
other. When the cycle number is less than this optimum value, no intact porous TiO2 film can be obtained. As the cycle number is larger than this optimum value, an ordered porous TiO2 film with many throughout holes is formed. The evolutive mechanism of ordered porous TiO2 films is proposed. 相似文献
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Englert BC Scholz S Leech PJ Srinivasarao M Bunz UH 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(3):995-1000
We describe the synthesis of two cyclobutadiene(cyclopentadienyl)cobalt-containing poly(p-phenylene ethynylene)s (PPEs) and their use as precursors for stable ceramic surface coatings. Organometallic PPEs were shaped into hexagonally ordered assemblies by using the breath-figure method. Such breath figures can be washed away with an appropriate solvent. Upon pyrolysis at 500 degrees C under either nitrogen or air, the bubble arrays persist as ceramics and are insoluble in organic solvents or water. The formed pyrolyzed bubble arrays were analyzed by optical and scanning electron microscopy, as well as energy dispersive X-ray microanalysis (EDX). The composition of the ceramic materials is discussed based on EDX and IR data. 相似文献
15.
《Electroanalysis》2005,17(1):79-84
Fabrication, electrochemical characterization, and applications of low‐site density carbon nanotubes based nanoelectrode arrays (CNTs‐NEAs) are reported in this work. Spin‐coating of an epoxy resin provides a new way to create the electrode passivation layer effectively reducing electrode capacitance and current leakage. Cyclic voltammetry showed the sigmoidal shape curves with low capacitive current and scan‐rate‐independent limiting current. Square‐wave voltammetry showed well‐defined peak shapes in voltammograms of K3Fe(CN)6 and 4‐acetamidophenol (acetaminophen) and the peak currents to be proportioned to their concentrations, demonstrating the feasibility for voltammetric analysis of the CNTs‐NEAs. The CNTs‐NEAs were also used successfully for voltammetric detection of trace concentrations of lead(II) at ppb level at first‐time. The CNTs‐NEAs provide an excellent platform for ultra sensitive electrochemical sensors for chemical and biological sensing. 相似文献
16.
Minhao Jiang Xiangyu Yan Yibo Wang Fang Pu Huiling Liu Yumei Li Chunfeng Yang Jiawei Zhu Xuemeng Liu Jinsong Ren Xiaogang Qu 《Advanced functional materials》2023,33(24):2300091
Hydrogen-bond organic frameworks (HOFs) with excellent structural and luminescent properties have emerged as a promising material for the construction of fluorescence sensors. However, designing a facile, universal and high throughput sensor with multiplex detection capacity still remains challenging. Herein, a one-component sensor array is constructed that mimics natural gustatory system for accurate and high-throughput discrimination and identification of versatile analytes. HOF as a single sensing element greatly simplifies the probe preparation in sensor array and detection procedure. Metal ions, proteins and bacteria as the model targets are rapid and accurately discriminated, presenting the universality of the system. Particularly, the system is successfully used for the classification of antibiotic mechanisms. The study expands the application scope of HOFs and provides a facile and universal system for sensing applications. 相似文献
17.
Kseniia A. Sergeeva Dmitrii V. Pavlov Albert A. Seredin Eugeny V. Mitsai Aleksandr A. Sergeev Evgeny B. Modin Anastasiia V. Sokolova Tsz Chun Lau Kseniia V. Baryshnikova Mihail I. Petrov Stephen V. Kershaw Aleksandr A. Kuchmizhak Kam Sing Wong Andrey L. Rogach 《Advanced functional materials》2023,33(44):2307660
In order to advance the development of quantum emitter-based devices, it is essential to enhance light-matter interactions through coupling between semiconductor quantum dots with high quality factor resonators. Here, efficient tuning of the emission properties of HgTe quantum dots in the infrared spectral region is demonstrated by coupling them to a plasmonic metasurface that supports bound states in the continuum. The plasmonic metasurface, composed of an array of gold nanobumps, is fabricated using single-step direct laser printing, opening up new opportunities for creating exclusive 3D plasmonic nanostructures and advanced photonic devices in the infrared region. A 12-fold enhancement of the photoluminescence in the 900–1700 nm range is observed under optimal coupling conditions. By tuning the geometry of the plasmonic arrays, controllable shaping of the emission spectra is achieved, selectively enhancing specific wavelength ranges across the emission spectrum. The observed enhancement and shaping of the emission are attributed to the Purcell effect, as corroborated by systematic measurements of radiative lifetimes and optical simulations based on the numerical solution of Maxwell's equations. Moreover, coupling of the HgTe photoluminescence to high quality factor modes of the metasurface improves emission directivity, concentrating output within an ≈20° angle. 相似文献
18.
Chao Lin Zheng Jiang Tiejun Zhao Xiaopeng Li Wei Luo Jung-Ho Lee 《Advanced functional materials》2023,33(7):2212827
Catalysis always proceeds in a chaotic fashion. Therefore, identifying the working principles of heterogeneous catalysts is a challenging task. Creating atomic order in heterogeneous catalysts simplifies this task and also offers new opportunities for rationally designing active sites to manipulate catalytic performance. The recent rapid advances in heterogeneous electrocatalysis have led to exciting progress in the construction of atomically ordered materials. Here, the latest progress in electrocatalysts with the periodic atomic arrangement, including intermetallic compounds with long-range order and metal atom-array catalysts with short-range order is summarized. The synthesis principles and the intriguing physical and chemical properties of these electrocatalysts are discussed. Furthermore, the compelling prospects of atomically ordered catalysts in the frontier of catalyst research are outlined. 相似文献
19.
The distributions of two--block--factors arising from i.i.d. sequences are observed to coincide with the distributions of the superdiagonals of jointly exchangeable and dissociated arrays . An inequality for superdiagonal probabilities of the arrays is presented. It provides, together with the observation, a simple proof of the fact that a special one--dependent Markov sequence of Aaronson, Gilat and Keane (1992) is not a two--block factor.
20.
Dimitris Gizopoulos Dimitris Nikolos Antonis Paschalis Constantin Halatsis 《Journal of Electronic Testing》1996,8(3):241-260
In this paper the testability of modified-Booth array multipliers for standard cells based design environments is examined for first time. In such cases the structure of the cells may be unknown, thus Cell Fault Model (CFM) is adopted. Two C-testable designs are proposed. A design for an N
x × Ny bits modified-Booth multiplier, which uses ripple carry addition at the last stage of the multiplication, is first proposed. The design requires the addition of only one extra primary input and 38 test vectors with respect to CFM. A second C-testable design is given using carry lookahead addition at the last stage which is the case of practical implementations of modified-Booth multipliers. Such a C-testable design using carry lookahead addition is for first time proposed in the open literature. This second design requires the addition of 4 extra primary inputs. One-level and two-levels carry lookahead adders, are considered. The C-testable design requires 61 test vectors for the former and 73 test vectors for the latter, respectively. The hardware and delay overheads imposed by both C-testable designs are very small and decrease when the size of the multiplier increases. 相似文献