Living anionic polymerization of N‐methoxymethyl‐N‐isopropylacrylamide: Synthesis of well‐defined poly(N‐isopropylacrylamide) having various stereoregularity

Anionic polymerization of N‐methoxymethyl‐N‐isopropylacrylamide ( 1 ) was carried out with 1,1‐diphenyl‐3‐methylpentyllithium and diphenylmethyllithium, ‐potassium, and ‐cesium in THF at ?78 °C for 2 h in the presence of Et₂Zn. The poly( 1 )s were quantitatively obtained and possessed the predicted molecular weights based on the feed molar ratios between monomer to initiators and narrow molecular weight distributions (M_w/M_n = 1.1). The living character of propagating carbanion of poly( 1 ) either at 0 or ?78 °C was confirmed by the quantitative efficiency of the sequential block copolymerization using N,N‐diethylacrylamide as a second monomer. The methoxymethyl group of the resulting poly( 1 ) was completely removed to give a well‐defined poly(N‐isopropylacrylamide), poly(NIPAM), via the acidic hydrolysis. The racemo diad contents in the poly(NIPAM)s could be widely changed from 15 to 83% by choosing the initiator systems for 1 . The poly(NIPAM)s obtained with Li⁺/Et₂Zn initiator system possessed syndiotactic‐rich configurations (r = 75–83%), while either atactic (r = 50%) or isotactic poly(NIPAM) (r = 15–22%) was generated with K⁺/Et₂Zn or Li⁺/LiCl initiator system, respectively. Atactic and syndiotactic poly(NIPAM)s (42 < r < 83%) were water‐soluble, whereas isotactic‐rich one (r < 31%) was insoluble in water. The cloud points of the aqueous solution of poly(NIPAM)s increased from 32 to 37 °C with the r‐contents. These indicated the significant effect of stereoregularity of the poly(NIPAM) on the water‐solubility and the cloud point in water © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4832–4845, 2006     

On universal spaces and absorbing sets related to a transfinite extension of covering dimension

R. Pol has shown that for every countable ordinal number α there exists a universal space for separable metrizable spaces X with trindX?α. W. Olszewski has shown that for every countable limit ordinal number λ there is no universal space for separable metrizable space with trIndX?λ. T. Radul and M. Zarichnyi have proved that for every countable limit ordinal number there is no universal space for separable metrizable spaces with dimWX?α where dimW is a transfinite extension of covering dimension introduced by P. Borst. We prove the same result for another transfinite extension dimC of the covering dimension.As an application, we show that there is no absorbing sets (in the sense of Bestvina and Mogilski) for the classes of spaces X with dimCX?α belonging to some absolute Borel class.     

On hermitian polynomial optimization

We compare three levels of algebraic certificates for evaluating the maximum modulus of a complex analytic polynomial, on a compact semi-algebraic set. They are obtained as translations of some recently discovered inequalities in operator theory. Although they can be stated in purely algebraic terms, the only known proofs for these decompositions have a transcendental character. Received: 27 June 2005     

Dimensional reduction for Helmholtz's equation on a bounded domain

Summary. The dimensional reduction method for solving boundary value problems of Helmholtz's equation in domain by replacing them with systems of equations in dimensional space are investigated. It is proved that the existence and uniqueness for the exact solution and the dimensionally reduced solution of the boundary value problem if the input data on the faces are in some class of functions. In addition, the difference between and in is estimated as and are fixed. Finally, some numerical experiments in a domain are given in order to compare theretical results. Received April 2, 1996 / Revised version received July 30, 1990     

Fully discrete Galerkin approximations of parabolic boundary-value problems with nonsmooth boundary data

Summary In this paper we study the convergence properties of a fully discrete Galerkin approximation with a backwark Euler time discretization scheme. An approach based on semigroup theory is used to deal with the nonsmooth Dirichlet boundary data which cannot be handled by standard techniques. This approach gives rise to optimal rates of convergence inL _p[O,T;L ₂()] norms for boundary conditions inL _p[O,T;L ₂()], 1p.     

Asymptotic expansions andL ∞-error estimates for mixed finite element methods for second order elliptic problems

Summary Asymptotic expansions for mixed finite element approximations of the second order elliptic problem are derived and Richardson extrapolation can be applied to increase the accuracy of the approximations. A new procedure, which is called the error corrected method, is presented as a further application of the asymptotic error expansion for the first order BDM approximation of the scalar field. The key point in deriving the asymptotic expansions for the error is an establishment ofL ¹-error estimates for mixed finite element approximations for the regularized Green's functions. As another application of theL ¹-error estimates for the regularized Green's functions, we shall present maximum norm error estimates for mixed finite element methods for second order elliptic problems.     

Spectral methods with sparse matrices

Summary Spectral methods employ global polynomials for approximation. Hence they give very accurate approximations for smooth solutions. Unfortunately, for Dirichlet problems the matrices involved are dense and have condition numbers growing asO(N ⁴) for polynomials of degree N in each variable. We propose a new spectral method for the Helmholtz equation with a symmetric and sparse matrix whose condition number grows only asO(N ²). Certain algebraic spectral multigrid methods can be efficiently used for solving the resulting system. Numerical results are presented which show that we have probably found the most effective solver for spectral systems.     

Uniformly convergent difference schemes for singularly perturbed parabolic diffusion-convection problems without turning points

We consider first the initial-boundary value problem for the parabolic equation