二水草酸锌脱水的热分解动力学研究

提出一种多升温速率-等温法确定机理函数g(α)的新方法;并用迭代的等转化率法求出较为可靠的活化能Ea;在Ea和g(α)的基础上计算出指前因子A.用该法对二水草酸锌（ZnC2O4•2H2O）脱水反应的热分解动力学三因子进行了求算,得出Ea为87.22 kJ•mol－1, A为4.2120×108～7.2328×108 s－1;以及随机成核和随后生长型机理函数Am（Avrami-Erofeer）,其积分形式g(α)=[－ln(1－α)] 1/m和微分形式f(α)=m(1－α)•[－ln(1－α)](1－1/m),调节因子m=1.85～2.00.     

The Electrochemical Behavior of α‐Ketoglutarate at the Hanging Mercury Drop Electrode in Acidic Aqueous Solution and Its Practical Application in Environmental and Biological Samples

The voltammetric behavior of α‐ketoglutarate (α‐KG) at the hanging mercury drop electrode (HMDE) has been investigated in acetate buffer solution. Under the optimum experimental conditions (pH 4.5, 0.2 M NaAc‐HAc buffer solution), a sensitive reductive wave of α‐KG was obtained by linear scan voltammetry (LSV) and the peak potential was ?1.18 V (vs. SCE), which was an irreversible adsorption wave. The kinetic parameters of the electrode process were α=0.3 and k_s=0.72 1/s. There was a linear relationship between peak current i_{p, α‐KG} and α‐KG concentration in the range of 2×10^?6–8×10^?4 M α‐KG. The detection limit was 8×10^?7 M and the relative standard deviation was 2.0% (C_α‐KG=8×10^?4 M, n=10). Applications of the reductive wave of α‐KG for practical analysis were addressed as follows: (1) It can be used for the quantitative analysis of α‐KG in biological samples and the results agree well with those obtained from the established ultraviolet spectrophotometric method. (2) Utilizing the complexing effect between α‐KG and aluminum, a linear relationship holds between the decrease of peak current of α‐KG Δi_p and the added Al concentration Cequation/tex2gif-inf-5.gif in the range of 5.0×10^?6–2.5×10^?4 M. The detection limit was 2.2×10^?6 M and the relative standard deviation was 3.1% (Cequation/tex2gif-inf-6.gif=4×10^?5 M, n=10). It was successfully applied to the detection of aluminum in water and synthetic biological samples with satisfactory results, which were consistent with those of ICP‐AES. (3) It was also applied to study the effect of Al^III on the glutamate dehydrogenase (GDH) activity in the catalytically reaction of α‐KG+NH +NADH?L ‐glutamate+NAD⁺+H₂O by differential pulse polarography (DPP) technique. By monitoring DPP reductive currents of NAD⁺ and α‐KG, an elementary important result was found that Al could greatly affect the activity of GDH. This study could be attributed to intrinsic understanding of the aluminum's toxicity in enzyme reaction processes.     

Features of a Scan and Clock Resource chip for providing access to board-level test functions

The architecture and some of the specific features of a Scan and Clock Resource (SCR) chip are described. This chip is currently being used in a high-end workstation product to provide access to the testability features of the individual chips and/or printed circuit boards. Using a board-level controller to gain access to the testability features of system components and interfacing the controller to a diagnostics processor (or external tester) is emerging as a common strategy for designing testable digital systems. Based upon experience gained from such an application, controller features that are deemed useful are discussed.This paper is an enhanced version of the author's earlier paper titled Towards a Standard Approach for Controlling Board-Level Test Functions, presented at the IEEE International Test Conference, ITC'90, Washington D.C., September 1990.     

Boundary scan test,test methodology,and fault modeling

The test technique called boundary scan test (BST) offers new opportunities in testing but confronts users with new problems too. The implementation of BST in a chip has become an IEEE standard and users on board level are the next group to begin thinking about using the new possibilities. This article addresses some of the questions about changes in board-level testing and fault diagnosis. The fault model itself is also affected by using BST. Trivial items are extended with more sophisticated details in order to complete the fault model. Finally, BST appears to be a test technique that offers a high degree of detectability on board level, but for diagnosis, some additional effort has to be made.     

The nearest neighbor random walk on subspaces of a vector space and rate of convergence

LetX be the collection ofk-dimensional subspaces of ann-dimensional vector spaceV _n overGF(q). A metric may be defined onX by letting

Initial data truncation for multivariate output of discrete-event simulations using the Kalman filter

Data truncation is a commonly accepted method of dealing with initialization bias in discrete-event simulation. An algorithm for determining the appropriate initial-data truncation point for multivariate output is proposed. The technique entails averaging across independent replications and estimating a steady-state output model in a state-space framework. A Bayesian technique called Multiple Model Adaptive Estimation (MMAE) is applied to compute a time varying estimate of the output's steady-state mean vector. This MMAE implementation features the use, in paralle, of a bank of Kalman filters. Each filter is constructed under a different assumption concerning the output's steady-state mean vector. One of the filters assumes that the steady-state mean vector is accurately reflected by an estimate, called the assumed steady-state mean vector, taken from the last half of the simulation data. As the filters process the output through the effective transient, this particular filter becomes more likely (in a Bayesian sense) to be the best filter to represent the data and the MMAE mean estimator is influenced increasingly towards the assumed steady-state mean vector. The estimated truncation point is selected when a norm of the MMAE mean vector estimate is within a small tolerance of the assumed steady-state mean vector. A Monte Carlo analysis using data from simulations of open and closed queueing models is used to evaluate the technique. The evaluation criteria include the ability to construct accurate and reliable confidence regions for the mean response vector based on the truncated sequences.     

基于自注意力机制和CycleGAN的高分三号ScanSAR图像的扇贝效应抑制

高分三号卫星是我国首颗分辨率达到1 m的C波段 多极化合成孔径雷达(synthetic aperture radar,SAR) 卫星,其中扫描 式合成孔径雷达(scan synthetic aperture radar,ScanSAR)模式是高分三号卫星重要的工 作模式之一,由于该模式的工作机制导致生成的图像可能发生扇贝效应,一般呈现为明暗相 间的条纹。本文针对高分三号卫星ScanSAR模式下存在的扇贝效应,提出自注意力机制与循 环一致对抗网络(cycle-consistent adversarial networks,CycleGAN)结合的模型对Scan S AR图像进行处理,从而抑制扇贝效应产生的条纹现象。本文所示方法与传统扇贝效应抑制方 法和深度学习相关算法进行比较,并通过亮度均值、平均梯度等指标进行分析。实验结果表 明,本文方法可以对高分三号ScanSAR图像存在的扇贝效应进行较好的处理,有效抑制图像 的条纹现象,使得图像质量得到提升,具有较大的实用意义。     

一种变压器巴伦馈电的超短波紧耦合阵列天线

紧耦合阵列天线(Tightly Coupled Array, TCA)具有超宽带、低剖面、宽角扫描等特点,近年来受到国内外学者的广泛关注。然而,在甚高频(VHF)、特高频(UHF)频段TCA 由于馈电网络设计困难等原因现有的研究报道很少。为了填补这一空白,本文设计并测试了一款变压器巴伦馈电的TCA,利用变压器巴伦解决了单元平衡馈电困难问题,同时采用短路枝节抑制E面共模谐振,采用频率选择表面(FSS)匹配层改善宽角扫描阻抗匹配。实测结果表明,该天线在110~520 MHz 频带内、±40°扫描角范围内电压驻波比<2.5,和仿真结果吻合。     

High-Efficiency Organic Solar Cells Enabled by Chalcogen Containing Branched Chain Engineering: Balancing Short-Circuit Current and Open-Circuit Voltage,Enhancing Fill Factor

The elaborate balance between the open-circuit voltage (V_OC) and the short-circuit current density (J_SC) is critical to ensure efficient organic solar cells (OSCs). Herein, the chalcogen containing branched chain engineering is employed to address this dilemma. Three novel nonfullerene acceptors (NFAs), named BTP-2O , BTP-O-S , and BTP-2S , featuring different peripheral chalcogen containing branched chains are synthesized. Compared with symmetric BTP-2O and BTP-2S grafting two alkoxy or alkylthio branched chains, the asymmetric BTP-O-S grafting one alkoxy and one alkylthio branched chains shows mediate absorption range, applicable miscibility, and favorable crystallinity. Benefiting from the enhanced π–π stacking and charge transport, an optimal power conversion efficiency (PCE) of 17.3% is obtained for the PM6: BTP-O-S -based devices, with a good balance between V_OC (0.912 V) and J_SC (24.5 mA cm⁻²), and a high fill factor (FF) of 0.775, which is much higher than those of BTP-2O (16.1%) and BTP-2S -based (16.4%) devices. Such a result represents one of the highest efficiencies among the binary OSCs with V_OC surpassing 0.9 V. Moreover, the BTP-O-S -based devices fabricated by using green solvent yield a satisfactory PCE of 17.1%. This work highlights the synergistic effect of alkoxy and alkylthio branched chains for high-performance OSCs by alleviating voltage loss and enhancing FF.     

一种3D眼镜虚拟试戴系统的实现

针对人脸图像试戴3D眼镜过程中存在的镜腿遮挡人脸问题,文中提出一种基于人脸图像的3D眼镜虚拟试戴技术。利用构建的人脸形状的三维模型,使其在虚拟试戴中对镜腿起到消隐作用,解决镜腿的遮挡问题。文中对输入的人脸图像进行关键点检测,结合Graham扫描法求得人脸形状的凸多边形,利用平移扫描构建人脸形状的三维模型。此外,文中根据定位人脸图像上的关键点以及姿态估计后对三维眼镜模型的变换,将眼镜模型佩戴到人脸图像上。实验结果表明,该方法对于多视角的人脸图像实现了虚拟试戴效果,解决了多种视角下人脸图像试戴过程中镜腿的遮挡问题,虚拟试戴中镜腿遮挡平均准确率为94.5%,遮挡精度较高。