全文获取类型
收费全文 | 13206篇 |
免费 | 2554篇 |
国内免费 | 3067篇 |
专业分类
化学 | 13161篇 |
晶体学 | 175篇 |
力学 | 378篇 |
综合类 | 63篇 |
数学 | 202篇 |
物理学 | 2880篇 |
无线电 | 1968篇 |
出版年
2024年 | 66篇 |
2023年 | 305篇 |
2022年 | 587篇 |
2021年 | 657篇 |
2020年 | 864篇 |
2019年 | 651篇 |
2018年 | 601篇 |
2017年 | 685篇 |
2016年 | 864篇 |
2015年 | 817篇 |
2014年 | 940篇 |
2013年 | 1439篇 |
2012年 | 1078篇 |
2011年 | 1106篇 |
2010年 | 885篇 |
2009年 | 893篇 |
2008年 | 887篇 |
2007年 | 861篇 |
2006年 | 719篇 |
2005年 | 633篇 |
2004年 | 615篇 |
2003年 | 531篇 |
2002年 | 380篇 |
2001年 | 308篇 |
2000年 | 235篇 |
1999年 | 201篇 |
1998年 | 190篇 |
1997年 | 142篇 |
1996年 | 117篇 |
1995年 | 128篇 |
1994年 | 92篇 |
1993年 | 92篇 |
1992年 | 44篇 |
1991年 | 43篇 |
1990年 | 34篇 |
1989年 | 16篇 |
1988年 | 19篇 |
1987年 | 16篇 |
1986年 | 11篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 12篇 |
1982年 | 8篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1972年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 9 毫秒
81.
Tadatomi Nishikubo Atsushi Kameyama Jun Yamashita Masao Tomoi Wakichi Fukuda 《Journal of polymer science. Part A, Polymer chemistry》1993,31(4):939-947
The addition reaction of oxiranes ( 26a—e ) with carbon dioxide (CO2) was performed using insoluble polystyrene beads containing pendant quaternary ammonium or phosphonium salts as catalysts under atmospheric pressure. The reaction of 26a—e with CO2 proceeded smoothly catalyzed by 1–2 mol % of the polymer-supported quaternary onium salts to give the corresponding cyclic carbonates ( 27a—e ) in high yields at 80–90°C. In this reaction system, the catalytic activity of the polymer-supported quaternary onium salts was strongly affected by the following factors: degree of ring substitution (DRS) of the onium salt residues to the polymer, degree of crosslinking (DC) of the polystyrene beads, chain length of the alkylene spacer between the polymer back-bone and the onium salt, hydrophobicity of the alkyl group on the onium salts, and kind of onium salts. That is, the polymer-supported quaternary phosphonium salts with low DRS and DC and with long alkylene spacer chain were found to have higher catalytic activity than low molecualr weight quaternary onium salts. The above polymer-supported catalysts can easily be separated at the end of a reaction by filtration and can be reused for at least seven runs. It was also found that the rate of reaction was proportional to the products of catalyst concentration and oxirane concentration. © 1993 John Wiley & Sons, Inc. 相似文献
82.
Susumu Narita Takeshi Hamakawa Tetsuo Morikawa Tai-ichi Shibuya 《Monatshefte für Chemie / Chemical Monthly》2002,133(7):987-990
Summary. The generalized Pauling bond order was enumerated in the C60 fullerene cage molecule (truncated icosahedral symmetry). This index measures chemical similarity in fullerene derivatives
such as dihydrofullerene (C60H2), anionized monohydrofullerene (C60H−), N-substituted monohydrofullerene (C59NH), the fullerene dimer ((C60)2), and the dianionic fullerene dimer ((C60)2
2−). It is also useful in judging the chemical stability of isomers.
Received October 9, 2001. Accepted November 9, 2001 相似文献
83.
Density of supercritical CO_2-tetrahydrofuran binary mixture and the partial molar volume of the cosolvent 总被引:1,自引:0,他引:1
The densities of supercritical CO2-tetrahydrofuran (cosolvent) binary mixture weremeasured at temperatures in range of 308.15 to 323.15 K and at pressure up to 16.5 MPa.The concentrations of tetrahydrofuran were from 0 to 0.57 mol/L.The partial molar volume of tetrahydrofuran was calculated based on the relationship between the density of the mixture and the concentration of the cosolvent.It is observed that the partial molar volume of the cosolvent is negative and the absolute value decreases with increasing pressure and the concentration of the cosolvent. 相似文献
84.
X. N. Yang 《Journal of solution chemistry》1998,27(3):261-272
A diaphragm cell has been used to measure mutual diffusion coefficients at 25°C for four binary nonelectrolyte mixtures: ethylbenzene + n-hexane, carbon tetrachloride + ethylbenzene, cyclohexane + p-xylene, and 1,2-dichloroethane + cyclohexane. A free-volume predictive approach for binary mutual diffusion coefficients was developed and tested. Only infinite dilution diffusion coefficients, some readily available pure substance data, and UNIFAC group contribution parameters are used in the model. No binary equilibrium thermodynamic information is required. For 73 binary systems with an overall average absolute deviation of 5.2%, it has been shown that the developed method is better than two commonly available reference methods for the prediction of liquid diffusion coefficients. 相似文献
85.
86.
87.
以互通多孔碳(IPC)为载体,水热条件下在碳表面原位反应生成纳米结构的二氧化锰(MnO2),制备互通多孔碳/二氧化锰纳米(IPC/MnO2)复合电极材料. 采用扫描电镜(SEM),透射电镜(TEM),X射线衍射(XRD),热重分析(TGA)对其结构进行表征;采用循环伏安法、恒流充放电和交流阻抗对其电化学性能进行研究. 结果表明:生成的MnO2均匀地负载在碳的表面,形成多层次结构,并且随着温度的升高IPC表面负载的MnO2由纳米颗粒变为纳米片状结构;MnO2纳米片具有典型的K-Birnessite 型晶体结构;复合物中MnO2的含量约为34%(w). 在100 ℃制备的IPC/MnO2复合材料在三电极系统中最高比电容达到了411 F·g-1;随着反应温度的升高,比容量先增长后基本保持不变. 以IPC/MnO2为正极,活性炭(AC)为负极,1 mol·L-1 Na2SO4溶液为电解液组装成IPC/MnO2//AC 混合超级电容器,发现IPC/MnO2电极的电容器其电位窗口从1 V扩展到1.8 V,容量可达86F·g-1,且表现出良好的电容特性和大电流放电性能. 相似文献
88.
缓慢炭化部分氧化对制备煤质活性炭的影响 总被引:5,自引:0,他引:5
研究了炭化升温速度、炭化低温区引入空气部分氧化对活性炭制备过程中炭化阶段、炭化物结构、活性炭性能等的影响。结果表明,炭化时低温部分氧化可提高炭化物得率,使炭化物微晶的d002值升高和Lc值减小;而较慢的炭化升温速度有利于制备优质活性炭。缓慢炭化、部分氧化可以在一定程度上控制炭化路径,使炭化向生成取向性差、难石墨化、各向同性、呒定形炭多的炭化物的方向进行;并讨论了它们控制炭化的作用机理。以此为指导, 相似文献
89.
90.