High Sensitive Microsensor Based on Organic‐Inorganic Composite for Two‐Dimensional Mapping of H2O2 by SECM

The present work describes the development of a selective, sensitive and stable sensing microsensor for scanning electrochemical microscopy (SECM) to measure H₂O₂ during electrochemical reduction of oxygen. The microsensor is based on graphene and Poly(3,4‐ethylenedioxythiophene) composite as support to iron (III) hexacyanoferrate (II) (PEDOT/graphene/Fe^III₄[Fe^II(CN)₆]₃ microsensor). The electrochemical properties of the PEDOT/graphene/Fe^III₄[Fe^II(CN)₆]₃ microsensor were investigated by cyclic voltammetry (CV) and scanning electrochemical microscopy (SECM). The PEDOT/graphene/Fe^III₄[Fe^II(CN)₆]₃ microsensor showed an excellent electrocatalytic activity toward hydrogen peroxide (H₂O₂) reduction with a diminution of the overpotential of about 500 mV in comparison to the process at a bare gold microelectrode. The microsensor presented excellent performance for two dimensional mapping of H₂O₂ by SECM in 0.1 mol L^?1 phosphate buffer solution (pH 7.0). Under optimized conditions, a linear response range from 1 up to 1000 µmol L^?1 was obtained with a sensitivity of 0.08 nA L µmol^?1 and limit of detection of 0.5 µmol L^?1.     

思维导图在物理化学教学中的应用

通过介绍思维导图的特征以及思维导图软件XMind的主要功能特点,阐述了思维导图应用于物理化学的理论基础。以XMind软件作为绘制工具,以"热力学第二定律"为例,探讨了将思维导图运用于单元总结中,在建构知识体系、把握知识脉络以及训练思维能力方面的有效作用。进一步以本章重要知识点"熵增加原理"为例,尝试思维导图在知识点的理解掌握、拓展应用等方面的具体应用。     

In situ detection of a single carotenoid crystal in a plant cell using Raman microspectroscopy

It is the first report of direct, in situ detection of carotenoids at the subcellular level by using Raman microspectroscopy. Single crystals sequestered in a carrot cell were measured using FT-Raman spectrometer equipped with a microscope and 40× objective. The observed characteristic bands centered at 1518 cm⁻¹ and 1156 cm⁻¹ proved the crystals were composed of carotenoids with β-carotene being predominant. The obtained results show the potential of Raman microspectroscopy for identification and analysis of compounds localized in cytoplasm by taking measurements directly from a single plant cell.     

虚拟网络映射模型和算法研究

虚拟网络映射是网络虚拟化的关键问题之一,其目的是在满足虚拟网络资源需求的前提下,为该虚拟网络分配合适的底层网络节点和链路资源,从而在共享的物理网络基础设施之上构建彼此隔离的多重异构虚拟网络,为网络基础创新研究提供实验环境和平台,为网络新应用提供承载服务。论述了虚拟网络映射模型和映射算法,并提出基于最小割集理论设计VN映射算法。     

移动互联技术助力博物馆社会化服务

移动互联网技术和智能手机发展给博物馆带来了新的契机,同时也给观众带来了新颖独特的体验,利用移动互联网延伸博物馆的社会教育服务功能,科技与文化相结合,将文化送到公众手上,科技助力文化传播可以让文化更亲民,让文化服务更惠民。借助移动互联网技术,利用3G/4G手机、PAD等各类移动终端,运用最新的掌上微游、数字导览、知识图谱、社交互动等方式打造可以随身携带的博物馆。     

AUTOMATICALLY EXTRACTING AND OPTIMIZING FUZZY RULE BASE

A method of automatically extracting and optimizing fuzzy rule base is presented in this paper. Firstly, it applies the method of CCM (cell-to-cell mapping) to analyze the evolving trend and global behavior of a fuzzy dynamical system based on a cell state space, which is characterized by equilibrium, cost and their domain of attractions. Secondly, each rule base is evaluated to determine a performance index based on the information of the system obtained by CCM. Thirdly, CA (Genetic Algorithm) optimizes the coded rule bases according to the performance index generation by generation. The method presented in this paper can be applied to various systems (linear or nonlinear, continuous or discrete) to automatically obtain optimal rule base, for it fuses the advantages of GA and CCM. As an example, a complicated nonlinear system-an inverted pendulum is simulated to demonstrate the validity of the method.     

L-Fuzzy伴随的若干特征定理照

研究 Frame格上的一类等价关系 ,给出 L - Fuzzy伴随的若干性质定理及其等价刻画 ,体现了L- Fuzzy伴随的层次伴随特点 ,最后引入广义 L-值偏序集的概念 ,得到了类似经典伴随的若干特征定理。     

一种新的按位块分段快速排序算法

针对分段快速排序法因分段映射策略不理想而造成算法复杂度显著增加之问题，文章提出了一种由按位块分段、分段映射和局部快速排序所组成的新排序算法——按位块分段快速排序法（以下简称为“按位块分段快速排序”）。算法分析和实验结果都表明：在待排序数据均匀分布或正态分布的情况下，按位块分段快速排序法的时间复杂度可以达到O（N），而附加存储空间开销却仅仅为N＋M（M为分段数目，1≤M≤N），同时排序速度明显优于Quick Sort、分段快速排序、分“档”统计插入排序和Proponion Split Sort等算法。     

The Existence of Infinitely Many Teichmuller Type Extremal Mappings with Special Boundary Correspondence

in the theory of quasiconformal mappings in the plane, tile problem about whetherthere exist infinitely many Teichmuller type extrmal mappings with special boundarycorrespondence is unsolved so far. In this paper an affirmative answer is given.