全文获取类型
收费全文 | 13088篇 |
免费 | 1323篇 |
国内免费 | 350篇 |
专业分类
化学 | 1171篇 |
晶体学 | 12篇 |
力学 | 244篇 |
综合类 | 188篇 |
数学 | 2402篇 |
物理学 | 1734篇 |
无线电 | 9010篇 |
出版年
2024年 | 35篇 |
2023年 | 124篇 |
2022年 | 335篇 |
2021年 | 511篇 |
2020年 | 450篇 |
2019年 | 328篇 |
2018年 | 316篇 |
2017年 | 516篇 |
2016年 | 602篇 |
2015年 | 627篇 |
2014年 | 1058篇 |
2013年 | 1013篇 |
2012年 | 962篇 |
2011年 | 974篇 |
2010年 | 621篇 |
2009年 | 608篇 |
2008年 | 750篇 |
2007年 | 802篇 |
2006年 | 658篇 |
2005年 | 606篇 |
2004年 | 540篇 |
2003年 | 452篇 |
2002年 | 307篇 |
2001年 | 267篇 |
2000年 | 229篇 |
1999年 | 165篇 |
1998年 | 137篇 |
1997年 | 108篇 |
1996年 | 109篇 |
1995年 | 109篇 |
1994年 | 72篇 |
1993年 | 62篇 |
1992年 | 51篇 |
1991年 | 42篇 |
1990年 | 27篇 |
1989年 | 21篇 |
1988年 | 23篇 |
1987年 | 20篇 |
1986年 | 17篇 |
1985年 | 18篇 |
1984年 | 26篇 |
1983年 | 10篇 |
1982年 | 13篇 |
1981年 | 9篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1973年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
101.
We propose a form of random forests that is especially suited for functional covariates. The method is based on partitioning the functions' domain in intervals and using the functions' mean values across those intervals as predictors in regression or classification trees. This approach appears to be more intuitive to applied researchers than usual methods for functional data, while also performing very well in terms of prediction accuracy. The intervals are obtained from randomly drawn, exponentially distributed waiting times. We apply our method to data from Raman spectra on boar meat as well as near‐infrared absorption spectra. The predictive performance of the proposed functional random forests is compared with commonly used parametric and nonparametric functional methods and with a nonfunctional random forest using the single measurements of the curve as covariates. Further, we present a functional variable importance measure, yielding information about the relevance of the different parts of the predictor curves. Our variable importance curve is much smoother and hence easier to interpret than the one obtained from nonfunctional random forests. 相似文献
102.
103.
Modeling Studies of the Formation and Destruction of NO in Pulsed Barrier Discharges in Nitrogen and Air 总被引:1,自引:0,他引:1
This paper presents the results of modeling studies on the formation and destruction of NO in pulsed barrier discharges in nitrogen and air. The goals of this work are to identify the major processes involved in the formation and destruction of NO in air discharges, to distinguish between oxidative and reductive paths for NO destruction, to explore the potential importance of excited state reactions, to evaluate the role of water in such systems, and to identify the final products in the absence of heterogeneous processes. In all cases, the systems were modeled with 100×10–4% (100 ppm) of added NO, with and without 3% added water. The focus in all of this work is chemistry in the post-pulse regime. 相似文献
104.
105.
分析了“化学平衡常数”的教材内容和相关教学设计,针对实际教学中存在的2个问题:简化的数据探究难以让学生体会到科学研究的复杂性;纯粹的知识性教学难以体现科学知识的价值和意义。提出在教学中融合化学史和数据探究,能帮助学生全面深入地理解概念,促进学生进一步认识科学本质和学科价值。 相似文献
106.
107.
Hiroaki Umeda Shiro Koseki Umpei Nagashima Michael W. Schmidt 《Journal of computational chemistry》2001,22(12):1243-1251
The quasi‐degenerate multireference second‐order perturbation theory (MRMP2) routines in the GAMESS suite of program codes have been parallelized using a distributed data interface (DDI). Two typical kinds of molecules were chosen for examination of parallelization speedup using one to eight PCs gathered as a cluster and connected by Fast Ethernet. The first example, in which total energies of several low‐lying electronic states have been obtained for niobium monohydride, give parallelization speedup of 7.15 when eight PCs were used as a cluster. The second example is the ground‐state total energy for a medium sized molecule, 4a,4b,8a,9a‐tetrahydro‐pyridino[1′,2′‐4,3]imidazo‐lidino[1,5‐a]pyridine. When distributed memory is employed, the parallelization speedup improves to 6.84 for the MRMP2 calculations when an eight‐PC cluster is used. These results demonstrate that our efforts to achieve the parallelization of MRMP2 routines have been successful. © 2001 John Wiley & Sons, Inc. J Comput Chem 22: 1243–1251, 2001 相似文献
108.
Ewald Sattler Harald Krautscheid Eberhard Matern Gerhard Fritz Ilona Kovcs 《无机化学与普通化学杂志》2001,627(2):186-193
Formation and Reactions of the CH2Li‐Derivatives of tBu2P–P=P(CH3)tBu2 and (Me3Si)tBuP–P=P(CH3)tBu2 With nBuLi, (Me3Si)tBuP–P=P(CH3)tBu2 ( 1 ) and tBu2P–P=P(CH3)tBu2 ( 2 ) yield (Me3Si)tBuP–P=P(CH2Li)tBu2 ( 3 ) and tBu2P–P=P(CH2Li)tBu2 ( 4 ), wich react with Me3SiCl to give (Me3Si)tBuP–P=P(CH2–SiMe3)tBu2 ( 5 ) and tBu2P–P=P(CH2–SiMe3)tBu2 ( 6 ), respectively. With tBu2P–P(SiMe3)–PtBuCl ( 7 ), compound 3 forms 5 as well as the cyclic products [H2C–P(tBu)2=P–P(tBu)–PtBu] ( 8 ) and [H2C–P(tBu)2=P–P(PtBu2)–P(tBu)] ( 9 ). Also 3 forms 8 with tBuPCl2. The cleavage of the Me3Si–P‐bond in 1 by means of C2Cl6 or N‐bromo‐succinimide yields (Cl)tBuP–P=P(CH3)tBu2 ( 10 ) or (Br)tBuP–P=P(CH3)tBu2 ( 11 ), resp. With LiP(SiMe3)2, 10 forms (Me3Si)2P–P(tBu)–P=P(CH3)tBu2 ( 12 ), and Et2P–P(tBu)–P=P(CH3)tBu2 ( 13 ) with LiPEt2. All compounds are characterized by 31P NMR Data and mass spectra; the ylide 5 and the THF adduct of 4 additionally by X‐ray structure analyses. 相似文献
109.
110.
The present state of the minimum assumption multivariate component resolution theory is outlined. Some new developments are presented: limiting function domains; the analytical expression for the limiting function; efficient algorithms for defining the FIRPOL and INNPOL hyperpolyhedrons. A very low resolution data set is analyzed. 相似文献