MCF介孔分子筛负载Co催化环己基过氧化氢分解

以P123为模板剂，1，3，5-三甲苯（TMB）为扩孔剂，正硅酸乙酯（TEOS）为硅源，六水硝酸钴为钴源，在酸性条件下原位合成XCo-MCF （X=4%，8%，10%，20%）介孔分子筛.采用FT-IR、UV-Vis、氮气物理吸附、XRD、XPS、H₂-TPR等手段对XCo-MCF的结构进行表征，并在环己基过氧化氢（CHHP）分解反应中进行了催化性能评价.UV-Vis、XPS和XRD等表征结果表明，XCo-MCF中钴主要以Co₃O₄的形式存在.以CHHP含量为7.2%（重量百分比）的环己烷氧化液为原料，XCo-MCF催化CHHP分解，在80℃反应90 min，CHHP分解转化率均在90%以上，其中8% Co-MCF为催化剂时，CHHP转化率达到95.7%，环己醇和环己酮选择性分别为77.5%和53.4%.经过4次回收重复使用后，催化剂仍能够保持较高的活性，ICP表征表明各催化剂活性组分均存在一定程度的流失，负载量达到20%时，活性组分的流失速率得到明显抑制.     

N,N-dialkoxy-N′-alkylureas

The chlorination of N-alkoxy-N-alkylureas (1) by the action oft-BuOCl proceeds regiospecifically to give stable N-chloro-N-alkoxy-N-alkylureas (2). The alcoholysis of2 leads to N,N-dialkoxy-N-alkylureas (3). The alkaline hydrolysis of3 is a new, convenient method for the preparation of dialkoxyamines.N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 117913 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 10, pp. 2441–2443, October, 1992.     

Electrochemical Behavior of MCF‐7 Cells on Carbon Nanotube Modified Electrode and Application in Evaluating the Effect of 5‐Fluorouracil

The electrochemical behavior of human breast cancer cells (MCF‐7) suspension on multiwalled carbon nanotube (MWCNT) modified graphite electrode was studied by using cyclic voltammetry (CV) and potentiometric stripping analysis (PSA). Compared with bare graphite electrode, the MWCNTs‐modified electrode showed electrocatalytic property to the oxidation of electroactive species in the cell suspension. One oxidative peak at about +0.74 V was observed in the cyclic voltammogram. PSA was proved to be more sensitive than CV for investigation of the electrochemical behavior of cells. And it was found that ultrasonication treatment of the cell suspension can significantly enhance the PSA signal. Factors influencing the PSA signal of cells, including deposition time, deposition potential and stripping current, were investigated in detail and the optimum conditions were obtained. The baseline corrected PSA signal was found to be related to the viability of cells and the technique was used for monitoring the growth of MCF‐7 cells. The effect of anticancer drug 5‐fluorouracil (5‐FU) on the growth of MCF‐7 cells was also investigated by PSA.     

基于多芯光纤错位熔接结构的温度与折射率同时测量传感器

提出了一款由输入单模光纤(SMF)-多芯光纤(MCF) -多模光纤(MMF)-输出SMF错位熔接构成的光纤Mach-Zehnder 干涉仪(MZI)结构,实现了环境温度和折射率的同时测量。实验结果表明,随着环境温度的 变化,传感器透射谱峰值波长线性漂移,灵敏度达 到54.238pm/℃,而透射谱峰值强度随温度变化不敏感;随着环境折 射率的变化,传感器透射谱峰值 强度线性变化,灵敏度达到10.704dB/RIU(RIU为折射率单位),而透 射谱峰值波长随环境折射率变 化不敏感。通过同时监测传感器输出光谱的峰值波长漂移量和峰值强度变化量,能够实现温 度与折 射率的同时测量。在温度与折射率测量时分别利用波长调制法与强度调制法,因此它们同时 测量不 存在交叉感染。本文传感器具有结构简单、制作容易和灵敏度高等优点,在生物、化学和医 学等领域有广泛的应用前景。     

单片硅酸镓镧晶体滤波器的研制

比较了几种压电晶体的物理性质,采用硅酸镓镧(La3Ga5SiO14,LGS)晶体材料设计了一种6极点单片晶体滤波器.该滤波器中心频率为4.8 MHz,3 dB带宽20 kHz,工作温度范围为-55～125℃,体积仅32.2 mm×12.6 mm×8.5 mm.实验证明,LGS晶体温度性能好,机电耦合系数高,适合制作中等带宽的晶体滤波器,该研究填补了国内该领域的空白.