含喹噁啉环的化合物改性聚己内酰胺

合成了14种由三种含喹(哑心)啉环的芳香化合物改性的聚己内酰胺(MC尼龙),并对其形态、抗冲击强度、吸水性及熔融行为等进行了表征。聚苯基单醚喹(哑心)啉(PPQ)单模型化合物对MC尼龙结晶部分几乎没有影响。少量(0.005—5.0％)吩嗪的引入使MC尼龙的颜色、形态及性能等发生巨大变化,改性体系被认为是氢键相互作用,PPQ双模型化合物的改性作用介于二者之间。     

Quantitative surface analysis by Auger and x-ray photoelectron spectroscopy

Recent developments in quantitative surface analysis by Auger (AES) and x-ray photoelectron (XPS) spectroscopies are reviewed and problems relating to a more accurate quantitative interpretation of AES/XPS experimental data are discussed. Special attention is paid to consideration of elementary physical processes involved and influence of multiple scattering effects on signal line intensities. In particular, the major features of core-shell ionization by electron impact, Auger transitions and photoionization are considered qualitatively and rigorous approaches used to calculate the respective transition probabilities are analysed. It is shown that, in amorphous and polycrystalline targets, incoherent scattering of primary and signal Auger and photoelectrons can be described by solving analytically a kinetic equation with appropriate boundary conditions. The analytical results for the angular and energy distribution, the mean escape depth, and the escape probability as a function of depth of origin of signal electrons as well as that for the backscattering factor in AES are in good agreement with the corresponding Mote Carlo simulation data. Methods for inelastic background subtraction, surface composition determination and depth-profile reconstructions by angle-resolved AES/XPS are discussed. Examples of novel techniques based on x-ray induced photoemission are considered.     

MONTE CARLO SIMULATION OF TRIBLOCK COPOLYMER/HOMOPOLYMER BLEND FILMS

1. INTRODUCTION The extensive applications of block copolymer have been studied in detail due to their special molecular architecture and characteristic [1,2]. Recently, many studies including theoretical analysis and experimental techniques have addressed the polymer blend system of diblock copolymer/homopolymer [3~9]. An early investigation presented a quantitative analysis of homopolymer distributions in well-ordered copolymer microdomains through mixing polystyrene (PS) or poly methyl…     

基于80C196MC的单极性SPWM的实现

研究了利用80C196MC单片机的波形发生器和一定的外围电路产生单极性SPWM(正弦脉宽调制)信号的方法。利用IR2130驱动器作为栅极驱动器,驱动用IGBT(绝缘栅双极晶体管)组成的单相H桥。对比了单极性SPWM相对于双极性SPWM的优点,阐述了其实现的基本原理,给出了具体的主电路和控制电路及程序实现的流程,分析了IR2130应用中的具体问题,最后给出了一种简单的减小过零点失真的方法。     

带有USB的DTU设计

为了实现采用GPRS(通用分组无线电业务)网进行远距离数据传输,采用Cygnal公司的带有USB(通用串行总线)接口的8051F320单片机和西门子公司的GPRS模块MC35研发出一款带有USB接口的DTU(数据终端单元),该款带有USB接口的DTU实现了远距离数据处理和手法数据的功能。文中提供了硬件和软件部分(底层固件和PC机前台软件)的设计方案。     

Efficient structural modification of electron-withdrawing substituents on Pt(II) complexes for red emitters: A theoretical study

In this study, the electronic structures and optical properties of a cyclometalated Pt(II) complex (M1) and a series of derivatives (M1–F, M1–CF₃, and M1–CN) with electron-withdrawing substituents (–F, –CF₃, and –CN) at the carbazole moiety were theoretically investigated by density functional theory and time-dependent density functional theory. The calculation results reveal that these Pt complexes display deep red phosphorescence emission above Λ = 640 nm. When the ³MLCT/π → π* to triplet metal-centered ³MC/d–d state decay mechanism is taken into consideration, the nonradiative decay rate constant (k_nr) decreased in the order M1 > M1–CF₃ > M1–F > M1–CN. The <T₁|H_SOC|S_m> and kr values of M1-F are similar with those of M1, however the Knr rate ofM1-F is larger than that of M1. M1–F is expected to have improved quantum yields. Moreover, through the analyses of the HOMO/LUMO level and triplet energy, it is found that the introduction of –F and –CN substituents in M1 results in efficient energy transfer from the host material 4,4′-N,N′-dicarbazole-biphenyl to these complexes. In view of the electroluminescent applications in organic light-emitting diodes, M1–F can serve as efficient deep-red guest materials with improved electron injection and transport ability.     

模拟乘法器MC1496的应用研究

模拟乘法器是一种完成两个模拟信号相乘的电子器件。本文基于电路设计与仿真软件Multisim进行模拟乘法器MC1496的应用研究,具体实现普通调幅（AM）、双边带调幅（DSB）、同步检波器、混频器的电路设计与仿真。     

基于MC9S12XET256MAL的汽车车身控制模块系统电路设计

本设计是以Freescale导体的MC9S12XET256MAL设计车载车身控制单元,主要实现功能包含车窗控制,车灯控制,背光控制,RKE,雨刮,清洗电机,防盗报警,中控门锁,行车喇叭,安全指示灯,CAN总线,LIN总线。增强汽车的安全、舒适和方便性。用户可以对外部按键操作实现相应功能,同时采集相关传感器自动实现相关功能,例如雨刮,防盗报警。利用总线将显示系统、驾驶员信息系统、导航系统、计算机网络系统、状态监测与故障诊断系统等连接。     

基于压缩传感和加权主色的镜头边界检测算法

针对现有算法存在计算量大、对摄像机和物体运动 敏感等缺点,提出一种基于压缩传感(CS)和加权主色(WMC)的镜头边界检测(SBD)算法(CSWMC )。首先通过直方图特征得到粗略的镜头 边界集合;然后利用CS将该集合中的帧及其前后帧的高维特征投影到低维空间,采用调节余 弦相似度得到基 于夹角的第一判定指标;继而定义一种新的图像主色权值和基于该权值的类Bhattacharyya 相似度,得到基于颜色 相似度的第二判定指标;以两种判定指标的乘积作为最终判定指标,并设计一种朴素但有效 的策略进行SBD。 实验结果表明,与常用方法相比,所提算法具有更高的查全率和精确率,能够更加有效进行 SBD。     

DS-CDMA的一种时频二维联合解扩方法

多径环境中传统的DS-CDMA信号接收,一般采用RAKE接收技术.本文提出一种不使用RAKE接收机的DS-CDMA接收算法:基于时频二维扩频的思想,考虑DS-CDMA发射机发射的一个扩频符号对应时间内的信号,在接收机中先将接收到的信号做一个比扩频增益N小的DFT变换,联合对多个DFT变换后的信号进行扩频解扩处理,从而恢复出发射的原始信息比特.本文对比了DS-CDMA传统的RAKE接收算法、基于时频二维扩频的DS-CDMA接收算法(2DSS)、以及Wang等提出的具有信道选择的频域解扩算法的复杂度,并就性能进行了计算机仿真验证.结果表明,在根均方时延较小信道中的性能优于传统RAKE接收算法和具有信道选择的频域解扩算法的性能.